Hostname: page-component-745bb68f8f-cphqk Total loading time: 0 Render date: 2025-01-25T17:51:34.080Z Has data issue: false hasContentIssue false
  • English
  • Français

Cryosol method: A novel powder processing technique based on ion-exchange phenomena

Published online by Cambridge University Press:  31 January 2011

A. A. Vertegel ,
S. V. Kalinin ,
N. N. Oleynikov ,
Yu. G. Metlin  and
Yu. D. Tretyakov
A. A. Vertegel
Affiliation:
Inorganic Chemistry Division, Department of Chemistry, Moscow State University, 119899, Moscow, Russia
S. V. Kalinin
Affiliation:
Inorganic Chemistry Division, Department of Chemistry, Moscow State University, 119899, Moscow, Russia
N. N. Oleynikov
Affiliation:
Inorganic Chemistry Division, Department of Chemistry, Moscow State University, 119899, Moscow, Russia
Yu. G. Metlin
Affiliation:
Inorganic Chemistry Division, Department of Chemistry, Moscow State University, 119899, Moscow, Russia
Yu. D. Tretyakov
Affiliation:
Inorganic Chemistry Division, Department of Chemistry, Moscow State University, 119899, Moscow, Russia
Get access

Abstract

A novel technique has been suggested for synthesis of highly dispersed oxide powders. The method is based on the treatment of aqueous solution of a multivalent metal nitrate (or chloride) by anion-exchange resin in the OH− form. The presented technique yields a stable colloid solution of the corresponding hydroxide with concentration up to 1 M. The subsequent freeze-drying and thermal dehydration results in very fine powder of metal oxide. The individual and multicomponent oxides obtained by the cryosol method were shown to possess unusual properties due to their high dispersity and chemical homogeneity.

Type
Articles
Information
Journal of Materials Research , Volume 13 , Issue 4 , April 1998 , pp. 901 - 904
Copyright
Copyright © Materials Research Society 1998

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Johnson, D. W., Am. Ceram. Soc. Bull. 64, 1597 (1985).Google Scholar
2.Sakka, S., Am. Ceram. Soc. Bull. 64, 1463 (1985).Google Scholar
3.Brinker, C. J., Keefer, K. D., Shaefer, D. W., Assink, R. A., Kay, B. D., and Ashley, C. S., J. Non-Cryst. Solids 70, 301 (1984).CrossRefGoogle Scholar
4.Whitehead, T. H.Chem. Rev. 21, 113 (1937).CrossRefGoogle Scholar
5.Pokras, L., J. Chem. Educ. 33, 223 (1956).CrossRefGoogle Scholar
6.Scott, E. S. and Andrieth, L. F., J. Chem. Educ. 31, 168 (1954).CrossRefGoogle Scholar
7.Spiro, Th. G., Allerton, S. E., Renner, J., Bils, R., and Saltman, P., J. Am. Chem. Soc. 88, 2721 (1966).CrossRefGoogle Scholar
8.Akitt, J. W., Greenwood, N. N., Khandelwal, B. L., and Lester, G. D., J. Chem. Soc. Dalton. Trans., 604 (1972).CrossRefGoogle Scholar
9.Vertegel, A. A., Lukashin, A. V., Zhirov, A. I., and Oleynikov, N. N., Inorg. Mater. 31, 495 (1995).Google Scholar
10.Edenborough, B. W., Malin, A. S., and Robins, R. G., J. Nucl. Mater. 48, 210 (1973).CrossRefGoogle Scholar
11.Livage, J., Henry, M., and Sanchez, C., Prog. Solid St. Chem. 18, 259 (1988).CrossRefGoogle Scholar
12.Lifshits, I. M. and Slezov, V. V., JETP 35, 479 (1958).Google Scholar
13.Krivoruchko, O. P., Buyanov, R. A., and Zolotovskii, B. P., Bull. Siberian Branch of the USSR Academy of Sciences 4, 26 (1980).Google Scholar
14.Toropov, V. E., Phase Diagrams of Oxide Systems. Reference Book (Nauka, Leningrad, Russia, 1985), Iss. 1, Part 1, p. 155.Google Scholar