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Corrosion of nickel and nickel–phosphorous-coated AISI 430 in dry (Ar–3%H2) and humid hydrogen (Ar–3%H2–3%H2O) atmosphere

Published online by Cambridge University Press:  01 September 2020

Mark K. King Jr.
Affiliation:
Materials Science and Engineering, University of Alabama at Birmingham, Birmingham, Alabama35294, USA
Manoj K. Mahapatra*
Affiliation:
Materials Science and Engineering, University of Alabama at Birmingham, Birmingham, Alabama35294, USA
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

The corrosion behavior of uncoated, nickel (Ni) and nickel–phosphorous (Ni–P)-coated AISI 430 alloy was investigated in Ar–3%H2 and Ar–3%H2–3%H2O atmosphere at 800 °C for 100 h. Microstructure, chemical composition, and reaction products were analyzed by scanning electron microscopy, energy-dispersive spectroscopy, and X-ray diffraction techniques. The corrosion extent of Ni–P-coated AISI 430 is higher than Ni-coated AISI 430. Oxidation promotes corrosion in the uncoated and coated alloy. The oxidation rate of Ni-coated alloy is the lowest in Ar–3%H2 but Ni–P-coated alloy in Ar–3%H2–3%H2O for initial 20 h. The oxidation rate of the Ni–P-coated sample is ~14 times higher in 20–100 h in Ar–3%H2–3%H2O. External growth of Cr2O3 is observed for Ni-coated alloy in Ar–3%H2 and for Ni–P-coated alloy in both the atmospheres. Inward growth of Cr2O3 by AISI 430 alloy consumption attributes to the lowest oxidation rate and the corrosion extent of Ni-coated sample in Ar–3%H2–3%H2O.

Type
Invited Feature Paper
Copyright
Copyright © Materials Research Society 2020

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Footnotes

b)

These authors contributed equally to this work.

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