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Conversion of waste plastic into ordered mesoporous carbon for electrochemical applications

Published online by Cambridge University Press:  18 February 2019

Kehan Liang ,
Lei Liu ,
Wei Wang ,
Yifeng Yu ,
Yuying Wang ,
Lili Zhang ,
Chang Ma  and
Aibing Chen Open the ORCID record for Aibing Chen [Opens in a new window]
Kehan Liang
Affiliation:
College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China
Lei Liu
Affiliation:
College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China
Wei Wang
Affiliation:
College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China
Yifeng Yu
Affiliation:
College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China
Yuying Wang
Affiliation:
College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China
Lili Zhang
Affiliation:
College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China
Chang Ma
Affiliation:
College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China
Aibing Chen*
Affiliation:
College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

The excessive use of plastic, especially polystyrene (PS), has caused serious environmental pollution. The efficient utilization of plastics and the conversion of plastics into value-added carbon materials are the concerns of researchers. Herein, we propose novel “pyrolysis–deposition” method to convert one popular plastic substance, PS, into ordered mesoporous carbons (OMCs). During the synthesis process, PS is pyrolyzed into small organic gases under high temperature, which is then adsorbed through capillary adsorption into the mesoporous of SBA-15 in the presence of catalyst. The obtained OMCs have high specific surface area, uniform pore size, and ordered pore structure. The OMCs exhibit specific capacitance of 118 F/g at a current density of 0.2 A/g and electrochemical stability of 87.2% at a current density of 2 A/g after 5000 cycles. The pyrolysis–deposition strategy provides a new idea to convert waste plastics into high-performance carbon materials for electrochemical applications.

Keywords

energy storagenanostructurepyrolysis
Type
Article
Information
Journal of Materials Research , Volume 34 , Issue 6 , 28 March 2019 , pp. 941 - 949
Copyright
Copyright © Materials Research Society 2019 

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