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Combustion synthesis of α–Si3N4 whiskers

Published online by Cambridge University Press:  31 January 2011

Yong-Ge Cao
Affiliation:
Laboratory of Special Ceramics and P/M, University of Science and Technology Beijing, Beijing 100083, People's Republic of China
Chang-Chun Ge
Affiliation:
Laboratory of Special Ceramics and P/M, University of Science and Technology Beijing, Beijing 100083, People's Republic of China
Zhang-Jian Zhou
Affiliation:
Laboratory of Special Ceramics and P/M, University of Science and Technology Beijing, Beijing 100083, People's Republic of China
Jiang-Tao Li
Affiliation:
Laboratory of Special Ceramics and P/M, University of Science and Technology Beijing, Beijing 100083, People's Republic of China
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Abstract

α–Si3N4 whiskers were fabricated first through combustion synthesis (CS) technology. The as-synthesized crystals with [001] as the elongated axis contain a large amount of linear defects including (a + b)-type, (a + b + c)-type, and c-type of dislocations. The growth of α–Si3N4 whiskers is mainly controlled by vapor-condensation (VC) mechanism. Special additive plays an important role in promoting the growth of α–Si3N4 whiskers and suppressing the phase transformation of α–Si3N4 to β–Si3N4.

Type
Articles
Copyright
Copyright © Materials Research Society 1999

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References

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