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Chemical synthesis and characterization of polyaniline-molybdenum trisulfide composite

Published online by Cambridge University Press:  31 January 2011

Florence Fusalba  and
Daniel Bélanger
Florence Fusalba
Affiliation:
Département de Chimie, Université du Québec à Montréal, Case Postale 8888, succursale Centre-Ville, Montréal, Québec, Canada H3C 3P8
Daniel Bélanger*
Affiliation:
Département de Chimie, Université du Québec à Montréal, Case Postale 8888, succursale Centre-Ville, Montréal, Québec, Canada H3C 3P8
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

A novel polyaniline-molybdenum trisulfide composite has been prepared by chemical polymerization from an acidic (1 M HCl) aqueous solution containing aniline and ammonium tetrathiomolybdate. The presence of molybdenum trisulfide in the polyaniline matrix induces morphological change to the polymer as evidenced by scanning electron micrographs. X-ray diffraction and differential scanning calorimetry indicate that polyaniline-molybdenum trisulfide is slightly less crystalline than polyaniline-HCl. X-ray photoelectron spectroscopy (XPS) and elemental analysis have been used to confirm the presence of molybdenum trisulfide in the polymer matrix. The XPS data also confirm that molybdenum trisulfide and tetrathiomolybdate anions are present with polyaniline to form a new inorganic-organic composite.

Type
Articles
Information
Journal of Materials Research , Volume 14 , Issue 5 , May 1999 , pp. 1805 - 1813
Copyright
Copyright © Materials Research Society 1999

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