Hostname: page-component-848d4c4894-2xdlg Total loading time: 0 Render date: 2024-06-28T21:30:46.310Z Has data issue: false hasContentIssue false
  • English
  • Français

Characteristics of CeO2/ZrO2-HA composite coating on ZK60 magnesium alloy

Published online by Cambridge University Press:  13 February 2017

Ying Xiong Open the ORCID record for Ying Xiong [Opens in a new window] ,
Xiaxia Hu  and
Renguo Song
Ying Xiong*
Affiliation:
Key Laboratory of Special Purpose Equipment and Advanced Manufacture Technology, Ministry of Education, College of Mechanical Engineering, Zhejiang University of Technology, Hangzhou 310032, Zhejiang, China
Xiaxia Hu
Affiliation:
Key Laboratory of Special Purpose Equipment and Advanced Manufacture Technology, Ministry of Education, College of Mechanical Engineering, Zhejiang University of Technology, Hangzhou 310032, Zhejiang, China
Renguo Song
Affiliation:
School of Materials Science and Engineering, Changzhou University, Changzhou 213164, China; and Jiangsu Key Laboratory of Materials Surface Science and Technology, Changzhou University, Changzhou 213164, Jiangsu, China
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

A CeO2/ZrO2-hydroxyapatite (HA) composite bio-ceramic coating was prepared on ZK60 magnesium (Mg) alloy by using micro-arc oxidation (MAO) and electrophoretic deposition (EPD). MAO coating was done as the basal layer was grown in alkaline electrolyte with the addition of nanoparticles (CeO2 and ZrO2) to improve the mechanical properties of coating. A HA coating as the covering layer was deposited on the surface of MAO coating for improving the biological properties of the coating. The phase compositions and morphology of coatings were monitored with X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. Adhesion and wear resistance of coatings were evaluated using a scratch test and a pin-on-disc sliding wear test. The corrosion resistance of coatings was evaluated in a simulated body fluid (SBF) using electrochemical tests at 36.5 ± 0.5 °C. The experimental results showed that the CeO2/ZrO2-HA composite coating on Mg alloy effectively improved its mechanical properties and corrosion resistance. Combining MAO and EPD is a promising modification technology for degradable Mg alloys as biomaterials.

Keywords

magnesium alloymicro-arc oxidationelectrophoresis depositioncomposite coatingformation mechanism
Type
Articles
Information
Journal of Materials Research , Volume 32 , Issue 6 , 28 March 2017 , pp. 1073 - 1082
Check for updates
Copyright
Copyright © Materials Research Society 2017 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

Contributing Editor: Jürgen Eckert

References

REFERENCES

Staiger, M.P., Pietak, A.M., Huadmai, J., and Dias, G.: Magnesium and its alloys as orthopedic biomaterials: A review. Biomaterials 27, 1728–1734 (2006).CrossRefGoogle ScholarPubMed
Revell, P.A., Damien, E., Zhang, X.S., Evans, P., and Howlett, C.R.: The effect of magnesium ions on bone bonding to hydroxyapatite coating on titanium alloy implants. Bioceramics 16(254–256), 447–450 (2004).Google Scholar
Zeng, R., Dietzel, W., Witte, F., Hort, N., and Blawert, C.: Progress and challenge for magnesium alloys as biomaterials. Adv. Biomater. 10, B3–B14 (2008).Google Scholar
Witte, F., Kaese, V., Haferkamp, H., and Switzer, E.: In vivo corrosion of four magnesium alloys and the associated bone response. Biomaterials 26, 3557–3563 (2005).Google Scholar
Yerokhin, A.L., Nie, X., Leyland, A., Matthews, A., and Dowey, S.J.: Plasma electrolysis for surface engineering. Surf. Coat. Technol. 122, 73–93 (1999).CrossRefGoogle Scholar
Gupta, P., Tenhundfeld, G., Daigle, E.O., and Ryabkov, D.: Electrolytic plasma technology: Science and engineering—An overview. Surf. Coat. Technol. 201, 8746–8760 (2007).Google Scholar
Rama Krishna, L., Somajaju, K.R.C., and Sundararajan, G.: The tribological performance of ultra-hard ceramic composite coatings obtained though microarc oxidation. Surf. Coat. Technol. 163–164, 484–490 (2003).Google Scholar
Liang, J., Guo, B.G., Tian, J., Liu, H.W., Zhou, J.F., and Xu, T.: Effect of potassium fluoride in electrolytic solution on the structure and properties of microarc oxidation coatings on magnesium alloy. Appl. Surf. Sci. 252, 345–351 (2005).Google Scholar
Yerokhin, A.L., Nie, X., Leyland, A., and Matthews, A.: Characterisation of oxide films produced by plasma electrolytic oxidation of a Ti–6Al–4V alloy. Surf. Coat. Technol. 130, 195–206 (2000).Google Scholar
Zhao, L.C., Cui, C.X., Wang, Q.Z., and Bu, S.J.: Growth characteristics and corrosion resistance of micro-arc oxidation coating on pure magnesium for biomedical applications. Corros. Sci. 52, 2228–2234 (2010).CrossRefGoogle Scholar
Liu, G.Y., Hu, J., Ding, Z.K., and Wang, C.: Bioactive calcium phosphate coating formed on micro-arc oxidized magnesium by chemical deposition. Appl. Surf. Sci. 257, 2051–2057 (2011).Google Scholar
Xin, Y.C., Liu, C.L., Zhang, X.M., Tang, G.Y., Tian, X.B., and Chu, P.K.: Corrosion behavior of biomedical AZ91 magnesium alloy in simulated body fluids. J. Mater. Res. 22, 2004–2011 (2007).Google Scholar
Mu, W.Y. and Han, Y.: Characterization and properties of the MgF2/ZrO2 composite coatings on magnesium prepared by micro-arc oxidation. Surf. Coat. Technol. 202, 4278–4284 (2008).CrossRefGoogle Scholar
Cai, J.S., Cao, F.H., Chang, L.R., Zheng, J.J., Zhang, J.Q., and Cao, C.N.: The preparation and corrosion behaviors of MAO coating on AZ91D with rare earth conversion precursor film. Appl. Surf. Sci. 257, 3804–3811 (2011).Google Scholar
Mandelli, A., Bestetti, M., Da Forno, A., Lecis, N., Trasatti, S.P., and Trueba, M.: A composite coating for corrosion protection of AM60B magnesium alloy. Surf. Coat. Technol. 205, 4459–4465 (2011).CrossRefGoogle Scholar
Liang, J., Srinivasan, P.B., Blawert, C., and Dietzel, W.: Comparison of electrochemical corrosion behaviour of MgO and ZrO2 coatings on AM50 magnesium alloy formed by plasma electrolytic oxidation. Corros. Sci. 51, 2483–2492 (2009).CrossRefGoogle Scholar
Arrabal, R., Matykina, E., Viejo, F., Skeldon, P., Thompson, G.E., and Merino, M.C.: AC plasma electrolytic oxidation of magnesium with zirconia nanoparticles. Appl. Surf. Sci. 254, 6937–6942 (2008).Google Scholar
Liu, F., Shan, D.Y., Song, Y.W., Han, E.H., and Ke, W.: Corrosion behavior of the composite ceramic coating containing zirconium oxides on AM30 magnesium alloy by plasma electrolytic oxidation. Corros. Sci. 53, 3845–3852 (2011).Google Scholar
Lee, K.M., Shin, K.R., Namgung, S., Yoo, B., and Shin, D.H.: Electrochemical response of ZrO2-incorporated oxide layer on AZ91 Mg alloy processed by plasma electrolytic oxidation. Surf. Coat. Technol. 205, 3779–3784 (2011).Google Scholar
Liu, P., Pan, X., Yang, W.H., Cai, K.Y., and Che, Y.S.: Al2O3–ZrO2 ceramic coatings fabricated on WE43 magnesium alloy by cathodic plasma electrolytic deposition. Mater. Lett. 70, 16–18 (2012).Google Scholar
Luo, H.H., Cai, Q.Z., Wei, B.K., Yu, B., He, J., and Li, D.J.: Study on the microstructure and corrosion resistance of ZrO2-containing ceramic coatings formed on magnesium alloy by plasma electrolytic oxidation. J. Alloys Compd. 474, 551–556 (2009).Google Scholar
Samanipour, F., Bayati, M.R., Zargar, H.R., Golestani-Fard, F., Troczynski, T., and Taheri, M.: Electrophoretic enhanced micro arc oxidation of ZrO2–HAp–TiO2 nanostructured porous layers. J. Alloys Compd. 509, 9351–9355 (2011).CrossRefGoogle Scholar
Lim, T.S., Ryu, H.S., and Hong, S.H.: Electrochemical corrosion properties of CeO2-containing coatings on AZ31 magnesium alloys prepared by plasma electrolytic oxidation. Corros. Sci. 62, 104–111 (2012).Google Scholar
Burg, K.J.L., Porter, S., and Kellam, J.F.: Biomaterial developments for bone tissue engineering. Biomaterials 21, 2347–2359 (2000).CrossRefGoogle ScholarPubMed
Narayanan, R., Seshadri, S.K., Kwon, T.Y., and Kim, K.H.: Electrochemical nano-grained calcium phosphate coatings on Ti–6Al–4V for biomaterial applications. Scr. Mater. 56, 229–232 (2007).Google Scholar
Kumar, R.R. and Wang, M.: Functionally graded bioactive coatings of hydroxyapatite/titanium oxide composite system. Mater. Lett. 55, 133–137 (2002).Google Scholar
De With, G., Van Dijck, H.J.A., Hattu, N., and Prijs, K.: Preparation, microstructure and mechanical properties of dense polycrystalline hydroxy apatite. J. Mater. Sci. 16, 1592–1598 (1981).Google Scholar
Sreekanth, D. and Rameshbabu, N.: Development and characterization of MgO/hydroxyapatite composite coating on AZ31 magnesium alloy by plasma electrolytic oxidation coupled with electrophoretic deposition. Mater. Lett. 68, 439–442 (2012).Google Scholar
Kim, D.Y., Kim, M., Kim, H.E., Koh, Y.H., Kim, H.W., and Jang, J.H.: Formation of hydroxyapatite within porous TiO2 layer by micro-arc oxidation coupled with electrophoretic deposition. Acta Biomater. 5, 2196–2205 (2009).Google Scholar
Nie, X., Leyland, A., and Matthews, A.: Deposition of layered bioceramic hydroxyapatite/TiO2 coatings on titanium alloys using a hybrid technique of micro-arc oxidation and electrophoresis. Surf. Coat. Technol. 125, 407–414 (2000).Google Scholar
ASTM G31–72, Standard Practice for Laboratory Immersion Corrosion Testing of Metals, 1999.Google Scholar
ISO10993.15, Biological Evaluation of Medical Devices—Part 15: Identification and Quantification of Degradation Products from Metals and Alloys, The people’s Republic of China State Administration of Quality Supervision Inspectionand quarantine, 2000.Google Scholar
Guo, H.F. and An, M.Z.: Growth of ceramic coatings on AZ91D magnesium alloys by micro-arc oxidation in aluminate–fluoride solutions and evaluation of corrosion resistance. Appl. Surf. Sci. 246, 229–238 (2005).Google Scholar
Liang, J., Wang, P., Hu, L.T., and Hao, J.C.: Tribological properties of duplex MAO/DLC coatings on magnesium alloy using combined microarc oxidation and filtered cathodic arc deposition. Mater. Sci. Eng., A 454–455, 164–169 (2007).Google Scholar
Vangolu, Y., Alsaran, A., and Yildirim, O.S.: Wear properties of micro arc oxidized and hydrothermally treated Ti6Al4V alloy in simulated body fluid. Wear 271, 2322–2327 (2011).CrossRefGoogle Scholar
Duan, H.P., Yan, C.W., and Wang, F.H.: Effect of electrolyte additives on performance of plasma electrolytic oxidation films formed on magnesium alloy AZ91D. Electrochim. Acta 52, 3785–3793 (2007).Google Scholar
Guo, H.F., An, M.Z., Xu, S., and Huo, H.B.: Formation of oxygen bubbles and its influence on current efficiency in micro-arc oxidation process of AZ91D magnesium alloy. Thin Solid Films 485, 53–58 (2005).Google Scholar
Zhang, R.F. and Zhang, S.F.: Formation of micro-arc oxidation coatings on AZ91HP magnesium alloys. Corros. Sci. 51, 2820–2825 (2009).CrossRefGoogle Scholar
Xue, W.B., Deng, Z.W., Lai, Y.C., Chen, R.Y., and Am, J.: Analysis of phase distribution for ceramic coatings formed by microarc oxidation on aluminum alloy. J. Am. Ceram. Soc. 81, 1365–1368 (1998).Google Scholar