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Carbon–silica alloy material as silicon carbide precursor prepared from phenol resin and ethyl silicate

Published online by Cambridge University Press:  31 January 2011

Masaki Narisawa ,
Kentaro Yamane ,
Yoshio Okabe ,
Kiyohito Okamura  and
Yasuo Kurachi
Masaki Narisawa
Affiliation:
Department of Metallurgy and Materials Science, College of Engineering, Osaka Prefecture University, 1–1 Gakuen-cho, Sakai 599–8531, Japan
Kentaro Yamane
Affiliation:
Department of Metallurgy and Materials Science, College of Engineering, Osaka Prefecture University, 1–1 Gakuen-cho, Sakai 599–8531, Japan
Yoshio Okabe
Affiliation:
Department of Metallurgy and Materials Science, College of Engineering, Osaka Prefecture University, 1–1 Gakuen-cho, Sakai 599–8531, Japan
Kiyohito Okamura
Affiliation:
Department of Metallurgy and Materials Science, College of Engineering, Osaka Prefecture University, 1–1 Gakuen-cho, Sakai 599–8531, Japan
Yasuo Kurachi
Affiliation:
Konica Corporation, No. 1, Sakura-machi, Hino-shi, Tokyo 191–0063, Japan
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Extract

Three kinds of inorganic–organic hybrid gel sheets were prepared from the liquid mixtures of ethyl silicate and water–soluble phenol resin. The prepared transparent gel sheets were fired at various temperatures. The density of the fired sheets jumped up at 773–1023 K with disappearance of organic groups. The sheets kept the prepared shape after the 1273 K firing, and their density increased with the silica content. After the firing at 1873 K, the sheets with high carbon content (C/SiO2: 5.60, 3.52) were converted into the sheets composed of silicon carbide aggregate with excess carbon, while the sheet with low carbon content (C/SiO2: 1.43) was converted into the fragile powders.

Type
Articles
Information
Journal of Materials Research , Volume 14 , Issue 12 , December 1999 , pp. 4587 - 4593
Copyright
Copyright © Materials Research Society 1999

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