Hostname: page-component-78c5997874-j824f Total loading time: 0 Render date: 2024-11-05T05:09:52.877Z Has data issue: false hasContentIssue false
  • English
  • Français

Blue emission of Ce3+ in lanthanide silicon oxynitride phosphors

Published online by Cambridge University Press:  31 January 2011

Benjamin Dierre ,
Rong-Jun Xie ,
Naoto Hirosaki  and
T. Sekiguchi
Benjamin Dierre
Affiliation:
Advanced Electronic Materials Center, National Institute for Materials Science (NIMS), Tsukuba 305-0044, Japan
Rong-Jun Xie*
Affiliation:
Nano Ceramics Center, National Institute for Materials Science, Tsukuba, Ibaraki 305-0044, Japan
Naoto Hirosaki
Affiliation:
Nano Ceramics Center, National Institute for Materials Science, Tsukuba, Ibaraki 305-0044, Japan
T. Sekiguchi
Affiliation:
Advanced Electronic Materials Center, National Institute for Materials Science (NIMS), Tsukuba 305-0044, Japan
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

Ce3+-activated lanthanide silicon oxynitride (La5Si3O12N, La4SiO7N2, LaSiO2N, and La3Si8O4N11) phosphors were prepared by firing the mixture of La2O3, Si3N4, SiO2, and CeO2 at 1500–1600 °C under a 0.5 MPa nitrogen atmosphere. Diffuse reflection spectrum, photoluminescence spectra, and temperature-dependent luminescence of these phosphors are presented in this work. A blue emission of Ce3+ in all lanthanide silicon oxynitrides was observed under ultraviolet irradiation, which is strongest in La3Si8O4N11:Ce3+. The concentration quenching and thermal quenching of the samples were discussed.

Keywords

LuminescenceNitrideOptical properties
Type
Articles
Information
Journal of Materials Research , Volume 22 , Issue 7 , July 2007 , pp. 1933 - 1941
Copyright
Copyright © Materials Research Society 2007

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1Hoppe, H.A., Lutz, H., Morys, P., Schnick, W. Seilmeier, A.: Luminescence in Eu2+-doped Ba2Si5N8: Fluorescence, thermoluminescence, and upconversion. J. Phys. Chem. Solids 61, 2000 2000CrossRefGoogle Scholar
2van Krevel, J.W.H., Hintzen, H.T., Metselaar, R. Meijerink, A.: Long wavelength Ce3+ emission in Y–Si–O–N materials. J. Alloys Compd. 268, 272 1998CrossRefGoogle Scholar
3van Krevel, J.W.H., van Rutten, J.W.T., Mandal, H., Hintzen, H.T. Metselaar, R.: Luminescence properties of terbium-, cerium-, or europium-doped α-SiAlON materials. J. Solid State Chem. 165, 19 2002CrossRefGoogle Scholar
4Xie, R-J., Mitomo, M., Uheda, K., Xu, F.F. Akimune, Y.: Preparation and luminescence spectra of calcium- and rare-earth (R = Eu, Tb, and Pr)-codoped α-SiAlON ceramics. J. Am. Ceram. Soc. 85, 1229 2002CrossRefGoogle Scholar
5Xie, R-J., Hirosaki, N., Sakuma, K., Yamamoto, Y. Mitomo, M.: Eu2+-doped Ca-α-SiAlON: A yellow phosphor for white light-emitting diodes. Appl. Phys. Lett. 84, 5404 2004CrossRefGoogle Scholar
6Xie, R-J., Hirosaki, N., Mitomo, M., Yamamoto, Y., Suehiro, T. Sakuma, K.: Optical properties of Eu2+ in α-SiAlON. J. Phys. Chem. B108, 12027 2004CrossRefGoogle Scholar
7Xie, R-J., Hirosaki, N., Mitomo, M., Uheda, K., Suehiro, T., Xu, Y., Yamamoto, Y. Sekiguchi, T.: Strong green emission from α-SiAlON activated by divalent ytterbium under blue light irradiation. J. Phys. Chem. B109, 9490 2005CrossRefGoogle Scholar
8Xie, R-J., Hirosaki, N., Mitomo, M., Yamamoto, Y., Suehiro, T. Ohashi, N.: Photoluminescence of cerium-doped α-SiAlON materials. J. Am. Ceram. Soc. 87, 1368 2005CrossRefGoogle Scholar
9Xie, R-J., Hirosaki, N., Mitomo, M., Suehiro, T., Xu, X. Tanaka, H.: Photoluminescence of rare-earth-doped Ca-α-SiAlON phosphors: Composition and concentration dependence. J. Am. Ceram. Soc. 88, 2883 2005CrossRefGoogle Scholar
10Li, Y.Q., Delsing, A.C.A., de With, G. Hintzen, H.T.: Luminescence properties of Eu2+-activated alkaline-earth silicon-oxynitride MSi2O2−δN2+2/3δ (M = Ca, Sr, Ba): A promising class of novel LED conversion phosphors. Chem. Mater. 17, 3242 2005CrossRefGoogle Scholar
11Li, Y.Q., de With, G. Hintzen, H.T.: Luminescence properties of Ce3+-activated alkaline earth silicon nitride M2Si5N8 (M = Ca, Sr, Ba) materials. J. Lumin. 116, 107 2006CrossRefGoogle Scholar
12Li, Y.Q., Fang, C.M., de With, G. Hintzen, H.T.: Preparation, structure and luminescence properties of Eu2+ and Ce3+-doped SrYSi4N7. J. Solid State Chem. 177, 4687 2006CrossRefGoogle Scholar
13Suehiro, T., Hirosaki, N., Xie, R-J. Mitomo, M.: Powder synthesis of Ca-α-SiAlON as a host material for phosphors. Chem. Mater. 17, 308 2005CrossRefGoogle Scholar
14Hirosaki, N., Xie, R-J., Kimoto, K., Sekiguchi, T., Yamamoto, Y., Suehiro, T. Mitomo, M.: Characterization and properties of green-emitting β-SiAlON:Eu2+ powder phosphors for white light-emitting diodes. Appl. Phys. Lett. 86, 211905 2005CrossRefGoogle Scholar
15Xie, R-J., Hirosaki, N., Suehiro, T., Xu, F-F. Mitomo, M.: A simple, efficient synthetic route to Sr2Si5N8:Eu2+-based red phosphors for white light-emitting diodes. Chem. Mater. 18, 5578 2006CrossRefGoogle Scholar
16Uheda, K., Hirosaki, N., Yamamoto, Y., Naito, A., Nakajima, T. Yamamoto, H.: Luminescence properties of a red phosphors, CaAlSiN3:Eu2+, for white light-emitting diodes. Electrochem. Solid State Lett. 9, H22 2006CrossRefGoogle Scholar
17Sakuma, K., Omichi, K., Kimura, N., Ohashi, M., Tanaka, D., Hirosaki, N., Yamamoto, Y., Xie, R-J. Suehiro, T.: Warm-white light-emitting diode with yellowish orange SiAlON ceramic phosphor. Opt. Lett. 29, 2001 2004CrossRefGoogle ScholarPubMed
18Xie, R-J., Hirosaki, N., Mitomo, M., Takahashi, K. Sakuma, K.: Highly efficient white-light-emitting diodes fabricated with short-wavelength yellow oxynitride phosphors. Appl. Phys. Lett. 88, 101104 2006CrossRefGoogle Scholar
19Xie, R-J., Hirosaki, N., Mitomo, M., Sakuma, K. Kimura, N.: Wavelength-tunable and thermally stable Li-α-sialon:Eu2+ oxynitride phosphors for white light-emitting diodes. Appl. Phys. Lett. 89, 241103 2006CrossRefGoogle Scholar
20Mueller-Mach, R., Mueller, G., Krames, M.R., Hoppe, H.A., Stadler, F., Schick, W., Juestel, T. Schmidt, P.: Highly efficient all-nitride phosphor-converted white light emitting diode. Phys. Status Solidi A 202, 1727 2005CrossRefGoogle Scholar
21Sakuma, K., Hirosaki, N., Kimura, N., Ohashi, M., Yamamoto, Y., Xie, R.-J., Suehiro, T., Asano, K. Tanaka, D.: White light-emitting diode lamps using oxynitride and nitride phosphor materials. IEICE Trans. Electron. E88–C, 2057 2005CrossRefGoogle Scholar
22Blasse, G. Grabmaier, B.C.: Luminescent Materials Springer– Verlag, Berlin, Germany 1994 108–93CrossRefGoogle Scholar
23Li, Y.Q., de With, G. Hintzen, H.T.: Luminescence of a new class of UV-blue-emitting phosphors MSi2O2−δN2+2/3δ: Ce3+ (M=Ca, Sr, Ba). J. Mater. Chem. 15, 4492 2005CrossRefGoogle Scholar
24Le Toquin, R. Cheetham, A.K.: Red-emitting cerium-based phosphor materials for solid-state lighting applications. Chem. Phys. Lett. 423, 352 2006CrossRefGoogle Scholar
25Titeux, S., Gervais, M., Verdier, P. Laurent, Y.: Synthesis and x-ray diffraction study of substituted La10(Si6O22N2)O2 silicon apatites. Mater. Sci. Forum 325–326, 17 2000CrossRefGoogle Scholar
26Takahashi, J., Yamane, H., Hirosaki, N., Yamamoto, Y., Suehiro, T., Kamiyama, T. Shimada, M.: Crystal structure of La4Si2O7N2 analyzed by the Rietveld method using the time-of flight neutron powder diffraction data. Chem. Mater. 15, 1099 2003CrossRefGoogle Scholar
27Harris, R.K., Leach, M.J. Thompson, D.P.: Nitrogen-15 and oxygen-17 NMR spectroscopy of silicates and nitrogen ceramics. Chem. Mater. 4, 260 1992CrossRefGoogle Scholar
28Grins, J., Shen, Z., Esmaeilzadeh, S. Berastegui, P.: The structure of the Ce and La N-phases RE3Si8−xAlxN11−xO4+x (x ≈ 1.75 for RE = Ce, x≈ 1.5 for RE = La), determined by single-crystal x-ray and time-of-flight neutron powder diffraction, respectively. J. Mater. Chem. 11, 2358 2001CrossRefGoogle Scholar
29Qiu, J., Miura, K., Sugimoto, N. Hirao, K.: Preparation and fluorescence properties of fluoroaluminate glasses containing Eu2+ ions. J. Non-Cryst. Solids 213–214, 266 1997CrossRefGoogle Scholar
30Dexter, D.L.: A theory of sensitized luminescence in solids. J. Chem. Phys. 21, 836 1953CrossRefGoogle Scholar
31Blasse, G., Wanmalcer, W.L., Vrygt, J.W. ter Bril, A.: Fluorescence of Eu2+-activated silicates. Phil. Res. Rep. 23, 189 1968Google Scholar
32Happek, U., Basun, S.A., Choi, J., Krebs, J.K. Raukas, M.: Electron transfer processes in rare earth doped insulators. J. Alloys Compd. 303–304, 198 2000CrossRefGoogle Scholar
33Najafov, H., Kato, A., Toyota, H., Iwai, K., Bayramov, A. Iida, S.: Effect of Ce Co-Doping on CaGa2S4:Eu Phosphor: II. Thermoluminescence. Jpn. J. Appl. Phys. 41, 2058 2002CrossRefGoogle Scholar
34Dorenbos, P.: Thermal quenching of Eu2+ 5d→ 4f luminescence in inorganic compounds. J. Phys.: Condens. Matter 17, 8103 2005Google Scholar