Hostname: page-component-cd9895bd7-7cvxr Total loading time: 0 Render date: 2024-12-23T13:16:24.270Z Has data issue: false hasContentIssue false

Ball-milling of Fe–Zn intermetallics

Published online by Cambridge University Press:  31 January 2011

Z. T. Liu
Affiliation:
Department of Materials Science and Engineering, University of Cincinnati, Cincinnati, Ohio 45221–0012
O. N. C. Uwakweh*
Affiliation:
Department of Materials Science and Engineering, University of Cincinnati, Cincinnati, Ohio 45221–0012
*
(a)Author to whom correspondence should to be directed.
Get access

Abstract

The ball-milling of pure Fe and Zn elemental powders corresponding to the Г-(Fe3Zn10), Г1-(Fe5Zn21), δ-(FeZn7), and ζ-(FeZn13) compositions yields metastable crystalline phases. This is demonstrated by the peaks observed in the DSC measurements of the different phases. These crystalline phases evolve differently with distinct or characteristic stages with heat treatments. Cold-welding and powder agglomeration are extensive, while the milled materials are completely homogeneous.

Type
Articles
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.William, F. S., Structure and Properties of Engineering Alloys (McGraw-Hill, Inc., New York, 1993), p. 561.Google Scholar
2.Gu, M., Simmons, G. W., and Marder, A.R., Metal. Trans. 21A, 273277 (1990).Google Scholar
3.Laverde, D., Zubillage, J. C., Gil-Sevillano, J., and Villanueva, E., Corros. Sci. 37 (1), 7995 (1995).Google Scholar
4.Lynch, R. F., J. Metals, 3941 (1987).Google Scholar
5.Mackowiak, J. and Short, N. R., Int. Metals Rev. 119 (1979).Google Scholar
6.Johansson, A., Ljung, J. and Westman, S., Acta Chem. Scan. 22, 27432753 (1968).CrossRefGoogle Scholar
7.Grant, R. G. and Cook, D. C., Hyperfine Interactions 94, 23092315 (1994).Google Scholar
8.Dunlop, J. B., Williams, J.M., and Longworth, G., J. Phys. F: Met. Phys. 8 (10), 21152123 (1978).Google Scholar
9.Bastin, G. F., van Loo, F. J. J., and Rieck, G. D., Z. Metallk. 65, 655660 (1974).Google Scholar
10.Cook, D. C. and Grant, R. G., Progress Report No. 1, Identification of the Iron-Zinc Phases in Galvanneal Steel Coatings by Mössbauer Spectroscopy and x-ray Diffraction, June, 5659 (1993).Google Scholar
11.Maurice, D. R. and Courtney, T. H., Metall. Trans. 21A (2), 283303 (1990).Google Scholar
12.McCormick, P. G., Wharton, V. N., and Schaffer, G. B., Physical Chemistry of Powder Metals Production / Processing, St. Marys, PA Oct. 16–18 (1989), pp. 1934.Google Scholar
13.Koch, C. C., Cavin, O. B., McKamey, C. G., and Scarbrough, J.O., Appl. Phys. Lett. 43, 1071 (1983).Google Scholar
14.Kubaschewski, O., Iron Binary Phase Diagrams (Springer-Verlag, Berlin, 1982), pp. 172175.Google Scholar
15.Harris, A. M., Schaffer, G. B., and Page, N. W., Proc. 2nd Int. Conf. Struc. Appl. Mech. Alloying, Vancouver, British Columbia, Canada, Sept. 20–22 (1993), pp. 1519.Google Scholar
16.Pakala, M., Liu, Z. T., and Uwakweh, O. N. C., J. Mater. Synth. Proc. (1996, in press).Google Scholar
17.Liu, Z. T., Boisson, M., and Uwakweh, O. N. C., Metall. Trans. A (1996, in press).Google Scholar
18.Schultz, L., Supermagnets, Hard Magnetic Materials, edited by Long, G. J. and Grandjean, F. (Kluwer Academic Publ., The Netherlands, 1991), pp. 573583.CrossRefGoogle Scholar
19.Brandon, J. K., Brizard, R. Y., Chieh, P. C., McMillan, R. K., and Pearson, W. B., Acta Crystallogr. B 30, 14121417 (1974).Google Scholar
20.The Handbook of Binary Phase Diagrams, General Electric (on the self-diffusion of Zn).Google Scholar
21.Cook, D. C. and Grant, R. G., Progress Report No. 1 Characterization of the Fe–Zn Intermetallic Phases, June, 40–41 (1993).Google Scholar
22.Bastin, G. F., van Loo, F.J.J., and Rieck, G. D., Z. Metallk., Bd. 67, 694698 (1976).Google Scholar
23.Brown, P. J., Acta. Crystallogr. 15, 608612 (1962).Google Scholar
24.Gellings, P. J., de Bree, E. W., and Gierman, G., Z. Metallk., Bd. 70, 315317 (1979).Google Scholar
25.Hellstern, E., Feght, H. J., Fu, Z., and Johnson, W. L.: J. Appl. Phys. 65, 305 (1989).CrossRefGoogle Scholar
26.Shingu, P. H., Huang, B., Nishitani, S. R., and Nasu, S., Suppl. Trans. Jpn. Inst. Metals 29, 3 (1988).Google Scholar
27.Luton, M. J., Jayanath, C. S., Disco, M. M., Matras, S., and Vallone, J., in Multicomponent Ultrafine Micro-structures, edited by McCandlish, L. E., Polk, D. E., Siegel, R. W., and Kear, B. H. (Mater. Res. Soc. Symp. Proc. 132, Pittsburgh, PA, 1989), p. 79.Google Scholar
28.Hellstern, E., Fecht, H. J., Garland, C., and Johnson, W. L., in Multicomponent Ultrafine Micro-structures, edited by Mc-Candlish, L. E., Polk, D. E., Siegel, R. W., and Kear, B. H. (Mater. Res. Soc. Symp. Proc. 132, Pittsburgh, PA, 1989), p. 137.Google Scholar