Hostname: page-component-78c5997874-94fs2 Total loading time: 0 Render date: 2024-11-18T01:23:13.437Z Has data issue: false hasContentIssue false
  • English
  • Français

Anomalous solid state reaction between SiC and Pt

Published online by Cambridge University Press:  31 January 2011

T.C. Chou
T.C. Chou
Affiliation:
Research and Development, Engelhard Corporation, Edison, New Jersey 08818
Get access

Abstract

Periodic structures are generated by solid state reaction between platinum (Pt) and silicon carbide (SiC). At temperatures above 900°C, periodic structures consisting of alternating layers of platinum silicides and carbon are produced in the diffusion zone. The composition profile across the diffusion zone and the chemistry of the periodic structures are investigated by scanning electron microscopy (SEM), scanning Auger microscopy (SAM), x-ray diffraction (XRD), and laser Raman microprobe. The formation of the platinum silicides causes an interfacial melting between Pt and SiC. X-ray diffraction indicates that Pt3Si is formed at 900°C, while Pt2Si is formed at 1000 °C. Laser Raman spectroscopy indicates that carbon is in either an amorphous state or a highly ordered graphitic state, depending upon its location from the reaction interface. The mechanism of formation of the periodic structure is discussed in terms of the solubility of carbon in platinum silicide during the solidification process.

Type
Articles
Information
Journal of Materials Research , Volume 5 , Issue 3 , March 1990 , pp. 601 - 608
Copyright
Copyright © Materials Research Society 1990

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1Warren, R. and Anderson, C., Composites (Guildford, U.K.) 15, 101 (1984).CrossRefGoogle Scholar
2Anderson, C. and Warren, R., in Proc. of the 9th Int. Symp. on Reactivity of Solids, edited by Dyrek, K., Haber, J., and Nowatny, J. (Elsevier, Amsterdam, The Netherlands, 1982), p. 820.Google Scholar
3Yamada, T., Sekiguchi, H., Okamoto, H., Azuma, S., and Kitamura, A., in Proc. of the 2nd Int. Symp. on Ceramic Materials and Components for Engines, edited by Bunk, W. and Hausner, H. (Verlag Deutsche Veramische Gesellschaft, Lubeck-Travemunde, Federal Republic of Germany, 1986), p. 441.Google Scholar
4Schiepers, R. C. J., van Loo, F. J. J., and With, G. D., J. Am. Ceram. Soc. 71, C-284 (1988).CrossRefGoogle Scholar
5Hansen, P. M., in Constitution of Binary Alloys (McGraw-Hill, New York, 1958), p. 1140.Google Scholar
6Topor, L. and Kleppa, O. J., Z. Metallkd. 77, 65 (1986).Google Scholar
7Walker, G. A., Wnuk, R. C., and Words, J. E., J. Vac. Sci. Technol. 7, 543 (1970).CrossRefGoogle Scholar
8Kawamura, T., Shinoda, D., and Muta, H., Appl. Phys. Lett. 11, 101 (1967).CrossRefGoogle Scholar
9Ottaviani, G., J. Vac. Sci. Technol. 16, 1112 (1979).CrossRefGoogle Scholar
10Drobek, J., Sun, R. C., and Tisone, T. C., Phys. Stat. Sol. (a) 8, 243 (1971).CrossRefGoogle Scholar
11Majni, G., Nava, F., Ottaviani, G., Danna, E., Leggieri, G., Luches, A., and Celotti, G., J. Appl. Phys. 52, 4055 (1981).CrossRefGoogle Scholar
12Liesegang, R. E., Naturwissenschaften 11, 353 (1896).Google Scholar
13Van Rooijen, V. A., Van Royen, E.W., Vrijen, J., and Radelaar, S., Acta Metall. 23, 987 (1975)CrossRefGoogle Scholar
14Klueh, R. L. and Mullins, W. W., Acta Metall. 17, 59 (1969).CrossRefGoogle Scholar
15Shen, Y. S., Zdanuk, E. J., and Krock, R. H., Metall. Trans. 2, 2839 (1971).CrossRefGoogle Scholar
16Patnaik, P. C., Ph.D. Thesis, McMaster University (1984).Google Scholar
17Osinski, K., Vriend, A. W., Bastin, G. F., and van Loo, F. J. J., Z. Metallkd. 73, 258 (1982).Google Scholar