Hostname: page-component-848d4c4894-xm8r8 Total loading time: 0 Render date: 2024-07-04T18:59:55.710Z Has data issue: false hasContentIssue false
  • English
  • Français

Amorphization of the TiV system by mechanical alloying and mechanical grinding in a hydrogen and nitrogen atmosphere

Published online by Cambridge University Press:  03 March 2011

K. Aoki ,
A. Memezawa  and
T. Masumoto
K. Aoki
Affiliation:
Institute for Materials Research, Tohoku University, Sendai 980, Japan
A. Memezawa
Affiliation:
Graduate School, Tohoku University, Sendai 980, Japan
T. Masumoto
Affiliation:
Institute for Materials Research, Tohoku University, Sendai 980, Japan
Get access

Abstract

A TiV system, which does not amorphize in an inert gas atmosphere, has been mechanically alloyed (MA) and mechanically ground (MG) using a planetary ball mill in a hydrogen and nitrogen atmosphere. The products were characterized by x-ray diffractometry, transmission electron microscopy, differential scanning calorimetry, and chemical analysis as a function of milling time and the gas pressure. Amorphization occurs by MA and MG in a hydrogen atmosphere and by MG in a nitrogen atmosphere. Amorphization by MA proceeds by the reaction between TiH2 and pure V in a hydrogen atmosphere, while it proceeds by MG by hydrogen and nitrogen absorption into the metastable β-TiV alloy and subsequent milling. The difference in the phase formation by MA and MG of the TiV system is discussed based on the gas absorption rate and the solubility of gases.

Type
Articles
Information
Journal of Materials Research , Volume 9 , Issue 1 , January 1994 , pp. 39 - 46
Copyright
Copyright © Materials Research Society 1994

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1Koch, C. C., Cavin, O. B., McKamey, C. G., and Scarbrough, J. O., Appl. Phys. Lett. 43, 1017 (1983).CrossRefGoogle Scholar
2Weeber, A. W. and Bakker, H., Physica B 153, 93 (1988).Google Scholar
3Gaffet, E., Malhouroux, N., and Abdellaoui, M., J. Alloy Comp. 194, 339 (1993).CrossRefGoogle Scholar
4Aoki, K., Memezawa, A., and Masumoto, T., J. Mater. Res. 8, 307 (1993).Google Scholar
5Aoki, K., Memezawa, A., and Masumoto, T., Appl. Phys. Lett. 61, 1037 (1992).CrossRefGoogle Scholar
6Memezawa, A., Aoki, K., and Masumoto, T., Scr. Metall. Mater. 28, 361 (1993).CrossRefGoogle Scholar
7Hellstern, E. and Schultz, L., Mater. Sci. Eng. 93, 213 (1987).CrossRefGoogle Scholar
8Kissinger, H. E., Anal. Chem. 29, 1702 (1957).CrossRefGoogle Scholar