Hostname: page-component-78c5997874-m6dg7 Total loading time: 0 Render date: 2024-11-05T12:58:42.921Z Has data issue: false hasContentIssue false

Tunable luminescence from Sm3+, Ce3+ codoped Al2O3–La2O3–SiO2 glasses for white light emission

Published online by Cambridge University Press:  31 January 2011

Jianrong Qiu*
Affiliation:
State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027, China
*
a) Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

Sm3+, Ce3+ codoped Al2O3–La2O3–SiO2 glasses were prepared and their luminescence properties were characterized. Blue-cyan to orange-red tunable luminescence was observed from these glasses with different excitation wavelengths ranging from 385 to 410 nm. White light emission with internal luminescence efficiency 42% has been observed using commercially available purple light-emitting-diode excitation. The energy transfer between Ce3+ and Sm3+ has also been investigated from fluorescence decay curves and spectral properties.

Type
Articles
Copyright
Copyright © Materials Research Society 2009

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Nakamura, S., Mukai, T., and Senoh, M.: Candela-class high-brightness InGaN/AlGaN double-heterostructure blue-light-emitting diodes. Appl. Phys. Lett. 64, 1687 (1994).CrossRefGoogle Scholar
2.Rohwer, L.S. and Srivastava, A.M.: Development of phosphors for LEDS. Electrochem. Soc. Interface 12, 36 (2003).CrossRefGoogle Scholar
3.Light Emitting Diodes (LEDs) for General Illumination Update 2002, edited by J.Y. Taso (Optoelectronics Industry Development Association, Washington, DC, 2002).Google Scholar
4.Schlotter, P., Baur, J., Hielscher, Ch., Kunzer, M., Obloh, H., Schmidt, R., and Schneider, J.: Fabrication and characterization of GaN:InGaN:AlGaN double heterostructure LEDs and their application in luminescence conversion LEDs. Mater. Sci. Eng., B 59, 390 (1999).CrossRefGoogle Scholar
5.Nakamura, S. and Fasol, G.: The Blue Laser Diodes (GaN Based Light Emitters and Lasers, Springer, Berlin, 1997), p. 216.CrossRefGoogle Scholar
6.Mueller-Mach, R., Mueller, G.O., Krames, M.R., and Trottier, T.: High-power phosphor-converted light-emitting diodes based on III-Nitrides. IEEE J. Sel. Top. Quantum Electron. 8, 339 (2002).CrossRefGoogle Scholar
7.Kobashi, K. and Taguchi, T.: Imaging camera system of OYGBR-phosphor-based white LED lighting. Proc. SPIE 5739, 25 (2005).CrossRefGoogle Scholar
8.Abramov, I.: Retinal mechanism of color vision, in Handbook of Sensory Physiology, Vol. 7, edited by Fourtes, M.G.F. (Springer-Verlag, New York, 1972), pp. 567607.Google Scholar
9.Le Toquin, R. and Cheetham, A.K.: Red-emitting cerium-based phosphor materials for solid-state lighting applications. Chem. Phys. Lett. 423, 352 (2006).CrossRefGoogle Scholar
10.Shimizu, Y. and Bandou, K.: Development of white LED light source. Rare Earth 40, 150 (2002).Google Scholar
11.Fujita, S., Yoshihara, S., Sakamoto, A., Yamamoto, S., and Tanabe, S.: YAG glass-ceramic phosphor for white LED (I): Background and development. Proc. SPIE 5941, 59411 (2005).Google Scholar
12.Lin, G., Zhu, B., Zhou, S., Yang, H., and Qiu, J.: Tunable luminescence of CaO–Al2O3–GeO2 glasses. Opt. Express 15(25), 16980 (2007).CrossRefGoogle ScholarPubMed
13.Yang, H., Lakshminarayana, G., Zhou, S., Teng, Y., and Qiu, J.: Cyan-white-red luminescence from europium doped Al2O3–La2O3–SiO2 glasses. Opt. Express 16(9), 6731 (2008).CrossRefGoogle ScholarPubMed
14.Blasse, G. and Grabmaier, B.C.: Luminescent Materials (Springer-Verlag, Berlin, 1994).CrossRefGoogle Scholar
15.Morrison, C.A. and Leavitt, R.P.: Spectroscopic properties of triply ionized lanthanides in transparent host crystals, in Handbook on the Physics and Chemistry of Rare Earths, Vol. 5, edited by Gschneidner, K.A. Jr and Eyring, L. (North-Holland, Amsterdam, 1982), p. 491.Google Scholar