Hostname: page-component-586b7cd67f-tf8b9 Total loading time: 0 Render date: 2024-11-26T10:11:00.515Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis of functional ceramic materials from aqueous solutions

Published online by Cambridge University Press:  31 January 2011

Takeshi Yao
Takeshi Yao
Affiliation:
Department of Fundamental Energy Science, Graduate School of Energy Science, Kyoto University, Yoshida, Sakyo-ku, Kyoto-shi 606-01, Japan
Get access

Abstract

Methods for synthesizing ceramic materials from aqueous solutions at ordinary temperature and pressure are advantageous because of the applicability to making films with wide areas and/or complicated shapes with no requirement of vacuum or high temperature, and because of lower cost. Powder of ZrO2 or LnMeO3 (Ln = La, Nd; Me = Cr, Mn, Fe, Co) perovskite was dissolved in hydrofluoric acid and a solution of fluoro-complex ions was obtained. Boric acid was added to the solution, the fluoride ions were consumed by the formation of BF4-, and then the fluoro-complex ions were hydrolyzed to ZrO2 or LnMeO3 in order to increase the amount of fluoride ions. A number of synthesized particles of ZrO2 or LnMeO3 were observed on the substrates in scanning electron microscope images.

Type
Articles
Information
Journal of Materials Research , Volume 13 , Issue 5 , May 1998 , pp. 1091 - 1098
Copyright
Copyright © Materials Research Society 1998

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Can, Z. Y., Narita, H., Mizusaki, J., and Tagawa, H., Solid State Ionics 79, 344 (1995).CrossRefGoogle Scholar
2.Periaswami, G., Vana Varamban, S., Rajan Babu, S., and Mathews, C. K., Solid State Ionics 26, 311 (1988).CrossRefGoogle Scholar
3.Miller, T. M. and Grassian, V. H., J. Am. Chem. Soc. 117, 10,969 (1995).CrossRefGoogle Scholar
4.Meadowcroft, D. B., Nature (London) 226, 847 (1970).CrossRefGoogle Scholar
5.Tseung, A. C. C. and Bevan, H. L., J. Electroanal. Chem. 45, 429 (1973).CrossRefGoogle Scholar
6.Manoharan, R. and Shukla, A. K., Electrochimica Acta 30, 205 (1985).CrossRefGoogle Scholar
7.Teraoka, Y., Zhang, H. M., Furukawa, S., and Yamazoe, N., Chem. Lett. 1985, 1743 (1985).CrossRefGoogle Scholar
8.Teraoka, Y., Nobunaga, T., and Yamazoe, N., Chem. Lett. 1988, 503 (1988).CrossRefGoogle Scholar
9.Dönitz, W., Dietrich, G., Erdle, E., and Streicher, R., Int. J. Hydrogen Energy 13, 283 (1988).CrossRefGoogle Scholar
10.Fuel Cell Systems, edited by Blomen, L. J. M. J. and Mugerwa, M. N. (Plenum Press, New York, 1993), p. 58.CrossRefGoogle Scholar
11.Kokubo, T., Kushitani, H., Sakka, S., Kitsugi, T., and Yamamuro, T., J. Biomed. Mater. Res. 24, 721 (1990).CrossRefGoogle Scholar
12.Yao, T., Inui, T., and Ariyoshi, A., J. Am. Ceram. Soc. 79, 3329 (1996).CrossRefGoogle Scholar
13.Mesmer, R. E., Palen, K. M., and Baes, C. F. Jr, Inorg. Chem. 12, 89 (1973).CrossRefGoogle Scholar
14.Yao, T., Ariyoshi, A., and Inui, T., J. Am. Ceram. Soc. 80, 2441 (1997).CrossRefGoogle Scholar
15. JCPDS No. 44–333.Google Scholar
16. JCPDS No. 32–484.Google Scholar
17. JCPDS No. 37–1493.Google Scholar
18. JCPDS No. 25–1060.Google Scholar
19. JCPDS No. 25–565.Google Scholar