Hostname: page-component-586b7cd67f-rdxmf Total loading time: 0 Render date: 2024-11-26T03:55:41.788Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis of Cr–Si intermetallic compounds by field-activated combustion synthesis

Published online by Cambridge University Press:  31 January 2011

F. Maglia ,
U. Anselmi-Tamburini ,
N. Bertolino ,
C. Milanese  and
Z. A. Munir
F. Maglia
Affiliation:
Department of Physical Chemistry and C.S.T.E./CNR, University of Pavia, V. le Taramelli, 16, 27100 Pavia, Italy
U. Anselmi-Tamburini
Affiliation:
Department of Physical Chemistry and C.S.T.E./CNR, University of Pavia, V. le Taramelli, 16, 27100 Pavia, Italy
N. Bertolino
Affiliation:
Department of Physical Chemistry and C.S.T.E./CNR, University of Pavia, V. le Taramelli, 16, 27100 Pavia, Italy
C. Milanese
Affiliation:
Department of Physical Chemistry and C.S.T.E./CNR, University of Pavia, V. le Taramelli, 16, 27100 Pavia, Italy
Z. A. Munir
Affiliation:
Department of Chemical Engineering and Materials Science, University of California, Davis, CA 95616–5294
Get access

Abstract

The use of an electric field to activate the combustion synthesis of chromium silicides was investigated. Despite their relatively low adiabatic temperatures, all four silicides were synthesized by field-activated combustion synthesis. However, although self-propagating synthesis reactions were initiated, the products were not pure but contained other silicides and reactant phases. The purity of the samples increased with increasing field strength, and under the highest field, the products contained the desired silicide as the major phase with minor amounts of other stoichiometries. Observation of microstructural evolution in quenched reactions revealed the key role played by the liquid phases in the propagation of the combustion front. The phase Cr5Si3 was the first product of the interaction between the reactants when either solid–solid or solid–liquid processes were involved. These results were confirmed by isothermal solid–solid and solid–liquid diffusion couple experiments.

Type
Articles
Information
Journal of Materials Research , Volume 15 , Issue 5 , May 2000 , pp. 1098 - 1109
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Sarkisyan, A.R., Dolukhanyan, S.K., Borovinskaya, I.P., and Merzhanov, A.G., Comb. Explos. Shock Waves 14, 49 (1978).CrossRefGoogle Scholar
2.Sarkisyan, A.R., Dolukhanyan, S.K., and Borovinskaya, I.P., Poroshk. Metall. (Kiev) 6, 14 (1978).Google Scholar
3.Sarkisyan, A.R., Dolukhanyan, S.K., and Borovinskaya, I.P., Comb. Explos. Shock Waves 15, 95 (1979).CrossRefGoogle Scholar
4.Zhang, S. and Munir, Z.A., J. Mater. Sci. 26, 3685 (1991).CrossRefGoogle Scholar
5.Deevi, S., Mater. Sci. Eng. A149, 241 (1992).CrossRefGoogle Scholar
6.Bhaduri, S.B., Radhakrishnan, R., and Qian, Z.B., Scripta Metall. Mater. 29, 1089 (1993).CrossRefGoogle Scholar
7.Subrahmanyam, J. and Mohan Rao, R., Mater. Sci. Eng. A183, 205 (1994).CrossRefGoogle Scholar
8.Bertolino, N., Anselmi-Tamburini, U., Maglia, F., Spinolo, G., and Munir, Z.A., J. Alloys Compd. 288, 238 (1999).CrossRefGoogle Scholar
9.Halverson, D.C., Lum, B.Y., and Munir, Z.A., in High Temperature Materials Chemistry IV, edited by Munir, Z.A., Cubicciotti, D., and Tagawa, H. (Electrochemical Society Proceedings 88–5, Pennington, NJ, 1988), p 613.Google Scholar
10.Feng, A. and Munir, Z.A., J. Appl. Phys. 76, 1927 (1994).CrossRefGoogle Scholar
11.Feng, A. and Munir, Z.A., Metall. Mater. Trans. 26B, 581 (1995).CrossRefGoogle Scholar
12.Feng, A. and Munir, Z.A., Metall. Mater. Trans. 26B, 587 (1995).CrossRefGoogle Scholar
13.Gedevanishvili, S. and Munir, Z.A., J. Mater. Res. 10, 2642 (1995).CrossRefGoogle Scholar
14.Gedevanishvili, S. and Munir, Z.A., Mater. Sci. Eng. A211, 1 (1996).CrossRefGoogle Scholar
15.Shon, I.J., Munir, Z.A., Yamazaki, K., and Shoda, K., J. Am. Ceram. Soc. 79, 1875 (1996).CrossRefGoogle Scholar
16.Feng, A. and Munir, Z.A., J. Am. Ceram. Soc. 80, 1222 (1997).CrossRefGoogle Scholar
17.Gedevanishvili, S. and Munir, Z.A., Mater. Sci. Eng. A242, 1 (1998).CrossRefGoogle Scholar
18.Schlesinger, M.E., Chem. Rev. 90, 607 (1990).CrossRefGoogle Scholar
19.Grami, M.E. and Munir, Z.A., J. Mater. Res. 9, 431 (1994).CrossRefGoogle Scholar
20.Rogachev, A.S., Shugaev, V.A., Khomenko, I.O., Varma, A., and Kachelmyer, C.R., Combust. Sci. Technol. 109, 53 (1995).CrossRefGoogle Scholar
21.Munir, Z.A., in Novel Techniques in Synthesis and Processing of Advanced Materials, edited by Singh, J. and Copely, S.M. (TMS, Warrendale, PA, 1994), p 53.Google Scholar
22.Xue, H. and Munir, Z.A., J. Eur. Ceram. Soc. 17, 1787 (1997).CrossRefGoogle Scholar
23.Bertolino, N., Maglia, F., Milanese, C., and Anselmi-Tamburini, U. (unpublished).Google Scholar
24.Maglia, F., Anselmi-Tamburini, U., and Spinolo, G. (unpublished).Google Scholar