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Synthesis, electrochemical, and microstructural study of precursor-derived LiMn2O4 powders

Published online by Cambridge University Press:  31 January 2011

Yumi H. Ikuhara ,
Yuji Iwamoto ,
Koichi Kikuta  and
Shin-ichi Hirano
Yumi H. Ikuhara*
Affiliation:
Fine Ceramics Research Association, Synergy Ceramics Laboratory, 2-4-1, Mutsuno, Atsuta-ku, Nagoya, 456-8587, Japan
Yuji Iwamoto
Affiliation:
Fine Ceramics Research Association, Synergy Ceramics Laboratory, 2-4-1, Mutsuno, Atsuta-ku, Nagoya, 456-8587, Japan
Koichi Kikuta
Affiliation:
Graduate School of Engineering, Nagoya University, 1, Furo-cho, Chikusa-ku, Nagoya, 464-8603, Japan
Shin-ichi Hirano
Affiliation:
Graduate School of Engineering, Nagoya University, 1, Furo-cho, Chikusa-ku, Nagoya, 464-8603, Japan
*
a) Address all correspondence to this author. Present address: Japan Fine Ceramics Center, Research and Development Laboratory, 2-4-1 Mutsuno, Atsuta-ku, Nagoya, 456-8587, Japan.
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Abstract

Stable and homogeneous alkoxide precursor solutions of lithium ethoxyethoxide and manganese ethoxyethoxide in 2-ethoxyethanol were synthesized by ligand exchange reaction of lithium isopropoxide and manganese 2-ethoxide, respectively, with 2-ethoxyethanol. [Li–Mn–O] precursor solution was prepared by mixing these modified alkoxide precursor solutions. LiMn2O4 powders were successfully synthesized by pyrolysis of the [Li–Mn–O] precursor powder in O2 temperature as low as 200 °C. The nanocrystalline LiMn2O4 powders 20–50 mm in diameter after heat treatment up to 700 °C consisted of the ordered (111) plane and performed with good cyclability as the cathode materials for Li secondary batteries.

Type
Articles
Information
Journal of Materials Research , Volume 14 , Issue 7 , July 1999 , pp. 3102 - 3110
Copyright
Copyright © Materials Research Society 1999

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References

REFERENCES

1.Thackeray, M.M., Johnson, P.J., de Picciotto, L.A., Bruce, P.G., and Goodenough, J.B., Mater. Res. Bull. 19, 179 (1984).CrossRefGoogle Scholar
2.Bach, S., Pereira-Ramos, J.P., Baffier, N., and Messina, R., Electrochim. Acta 37, 1301 (1992).CrossRefGoogle Scholar
3.Rossouw, M.H., de Kock, A., de Picciotto, L.A., Thackeray, M.M., David, W.I.F, and Ibberson, R.M., Mater. Res. Bull. 25, 173 (1990).CrossRefGoogle Scholar
4.Ohzuku, T., Kitagawa, M., and Taketsugu, H., J. Electrochem. Soc. 137, 769 (1990).CrossRefGoogle Scholar
5.Huang, H. and Bruce, P.G., J. Electrochem. Soc. 141, 185 (1994).CrossRefGoogle Scholar
6.Tarascon, J.M., McKinnon, W.R., Coowar, F., Bowmer, T.N., Amatucci, G., and Guyomard, D., J. Electrochem. Soc. 141, 1421 (1994).CrossRefGoogle Scholar
7.Gummow, R.J., de Kock, A., and Thackeray, M.M., Solid State Ionics 69, 59 (1994).CrossRefGoogle Scholar
8.Masquelier, C., Tabuchi, M., Ado, K., Kanno, R., Kobayashi, Y., Maki, Y., Nakamura, O., Goodenough, J.B., J. Solid State Chem. 123, 256 (1996).CrossRefGoogle Scholar
9.Guyomard, D. and Tarascon, J.M., J. Electrochem. Soc. 139, 937 (1992).CrossRefGoogle Scholar
10.Reimers, J.N. and Dahn, J.R., J. Electrochem. Soc. 139, 2091 (1992).CrossRefGoogle Scholar
11.Gummow, R.J., Liles, D.C., Thackeray, M.M., and David, W.I.F, Mater. Res. Bull. 28, 1177 (1993).CrossRefGoogle Scholar
12.Thomas, M.G.S.R, David, W.I.F, Goodenough, J.B., and Gloves, P., Mater. Res. Bull. 20, 1137 (1985).CrossRefGoogle Scholar
13.Dahn, J.R., von Sacken, U., Michael, C.A., Solid State Ionics 44, 87 (1990).CrossRefGoogle Scholar
14.Hirano, A., Kanno, R., Kawamoto, Y., Takeda, Y., Yamaura, K., Takano, M., Ohyama, K., Ohashi, M., Yamaguchi, Y., Solid State Ionics 78, 123 (1995).CrossRefGoogle Scholar
15.Jiang, Z. and Abraham, K.M., J. Electrochem. Soc. 143, 1591 (1996).CrossRefGoogle Scholar
16.Endres, P., Fuchs, B., Kemmler-Sack, S., Brandt, K., FaustBecker, G., Praas, H-W., Solid State Ionics, 89, 221 (1996).CrossRefGoogle Scholar
17.Tsumura, T., Shimizu, A., and Inagaki, M., Solid State Ionics 90, 197 (1996).CrossRefGoogle Scholar
18.Bach, S., Henry, M., Baffier, N., and Livage, J., J. Solid State Chem. 88, 325 (1990).CrossRefGoogle Scholar
19.Barboux, P., Tarascon, J.M., and Shokoohi, F.K., J. Solid State Chem. 94, 185 (1991).CrossRefGoogle Scholar
20.Tsumura, T., Shimizu, A., and Inagaki, M., J. Mater. Chem. 3, 995 (1993).CrossRefGoogle Scholar
21.Liu, W., Farringtonaa, G.C., Chaput, F. and Dunn, B., J. Electrochem. Soc. 143, 879 (1996).CrossRefGoogle Scholar
22.Hall, W.H., Proc. Phys. Soc. 62, 714 (1949).Google Scholar