Hostname: page-component-586b7cd67f-l7hp2 Total loading time: 0 Render date: 2024-11-29T15:58:45.836Z Has data issue: false hasContentIssue false

Syntheses and corrosion behaviors of Fe-based amorphous soft magnetic alloys with high-saturation magnetization near 1.7 T

Published online by Cambridge University Press:  13 February 2015

Ye Han
Affiliation:
School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China
Fanli Kong
Affiliation:
International Institute of Green Materials, Josai International University, Togane 283-8555, Japan
Chuntao Chang
Affiliation:
Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Sciences, Ningbo 315201, China
Shengli Zhu
Affiliation:
School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China
Akihisa Inoue*
Affiliation:
School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China; International Institute of Green Materials, Josai International University, Togane 283-8555, Japan; and Department of Physics, King Abdulaziz University, Jeddah 22254, Saudi Arabia
El-Sayed Shalaan
Affiliation:
Department of Physics, King Abdulaziz University, Jeddah 22254, Saudi Arabia
Fahad Al-Marzouki
Affiliation:
Department of Physics, King Abdulaziz University, Jeddah 22254, Saudi Arabia
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

Some Fe-rich amorphous alloys of Fe–B–P–Si and Fe–B–P–Si–C systems were found to exhibit simultaneously good soft magnetic properties with high-saturation magnetization values near 1.7 T, which are higher than those for previously reported Fe-based amorphous and glassy alloys, in addition to rather good amorphous ribbon formability, good bending ductility, and rather high corrosion resistance. The corrosion resistance increased with increasing P content, accompanying by the increase in thermal stability of the amorphous phase. The decrease in the outer surface velocity of the wheel, which results in the increase of ribbon thickness, also causes an improvement of surface smoothness of the melt-spun amorphous alloy ribbons. The syntheses of new high-saturation Fe-based soft magnetic amorphous alloys without any other transition metals hold promise for future extension of Fe-based soft magnetic amorphous materials.

Type
Articles
Copyright
Copyright © Materials Research Society 2015 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Long, Z.L., Shao, Y., Xie, G.Q., Zhang, P., Shen, B.L., and Inoue, A.: Enhanced soft-magnetic and corrosion properties of Fe-based bulk glassy alloys with improved plasticity through the addition of Cr. J. Alloys Compd. 462, 5259 (2008).CrossRefGoogle Scholar
Makino, A., Kubota, T., Makabe, M., Chang, C.T., and Inoue, A.: FeSiBP metallic glasses with high glass-forming ability and excellent magnetic properties. Mater. Sci. Eng., B 148, 166170 (2008).CrossRefGoogle Scholar
Matsumoto, H., Urata, A., Yamada, Y., and Inoue, A.: Novel FePBNbCr glassy alloys “SENNTIX” with good soft-magnetic properties for high efficiency commercial inductor cores. J. Alloys Compd. 509, S193S196 (2011).CrossRefGoogle Scholar
Lavorato, C., Fiore, G., Tiberto, P., Baricco, M., Sirkin, H., and Moya, J.A.: Structural and magnetic properties of Fe76P5(Si0.3B0.5C0.2)19 amorphous alloy. J. Alloys Compd. 536, S319S323 (2012).CrossRefGoogle Scholar
Ryan, D.H., Coey, J.M.D., and Strom-Olsen, J.O.: Magnetic properties of iron-rich Fe-Hf glasses. J. Magn. Magn. Mater. 67, 148154 (1987).CrossRefGoogle Scholar
Mishra, D., Gurram, M., Reddy, A., Perumal, A., Saravanan, P., and Srinivasan, A.: Enhanced soft magnetic properties and magnetocaloric effect in B substituted amorphous Fe–Zr alloy ribbons. Mater. Sci. Eng., B 175, 253260 (2010).CrossRefGoogle Scholar
Matsumoto, H., Urata, A., Yamada, Y., and Inoue, A.: Novel Fe(97-x-y)PxByNb2Cr1 glassy alloys with high magnetization and low loss characteristics for inductor core materials. IEEE Trans. Magn. 46, 373376 (2010).CrossRefGoogle Scholar
Inoue, A., Yoshii, I., Kimura, H., Okumura, K., and Kurosaki, J.: Enhanced shot peening effect for steels by using Fe-based glassy alloy shots. Mater. Trans. 44, 23912395 (2003).CrossRefGoogle Scholar
Botta, W.J., Berger, J.E., Kiminami, C.S., Roche, V., Nogueira, R.P., and Bolfarini, C.: Corrosion resistance of Fe-based amorphous alloys. J. Alloys Compd. 586, S105S110 (2014).CrossRefGoogle Scholar
May, J.E., Souza, C.A.C., Morelli, C.L., Mariano, N.A., and Kuri, S.E.: Magnetic and corrosion properties comparison of FeSi-based, FeZr-based and FeCo-based alloys. J. Alloys Compd. 390, 106111 (2005).CrossRefGoogle Scholar
Chang, C.T., Qin, C.L., Makino, A., and Inoue, A.: Enhancement of glass-forming ability of FeSiBP bulk glassy alloys with good soft-magnetic properties and high corrosion resistance. J. Alloys Compd. 533, 6770 (2012).CrossRefGoogle Scholar
Chang, C.T., Kubota, T., Makino, A., and Inoue, A.: Synthesis of ferromagnetic Fe-based bulk glassy alloys in the Fe–Si–B–P–C system. J. Alloys Compd. 473, 368372 (2009).CrossRefGoogle Scholar
ASM International Handbook Committee: Handbook of ASM, vol. 3, Alloy Phase Diagrams (ASM International Press, U.S., 1990), pp. 2.81, 2.200, 2.203.Google Scholar
Makino, A., Chang, C.T., Kubota, T., and Inoue, A.: Soft magnetic Fe–Si–B–P–C bulk metallic glasses without any glass-forming metal elements. J. Alloys Compd. 483, 616619 (2009).CrossRefGoogle Scholar
Asami, K., Kimura, H.M., Hashimoto, K., and Masumoto, T.: Compositions of amorphous Ni-Fe-P alloy surfaces. J. Non-Cryst. Solids 64, 135147 (1984).CrossRefGoogle Scholar
Hagiwara, M., Inoue, A., and Matsumoto, T.: Production of amorphous Co-Si-B and Co-M-Si-B (M = Group IV-VIII transition metals) wires by a method employing melt spinning into rotating water and some properties of the wires. Mater. Sci. Eng. 54, 197207 (1982).CrossRefGoogle Scholar
Inoue, A., Shen, B.L., and Chang, C.T.: Fe- and Co-based bulk glassy alloys with ultrahigh strength of over 4000 MPa. Intermetallics 14, 936944 (2006).CrossRefGoogle Scholar
De Boer, F.R., Boom, R., Mattens, W.C.M., Miedema, A.R., and Niessen, A.K.: Cohesion in Metals (North-Holland, Amsterdam, Netherlands, 1989), pp. 217403.Google Scholar
Inoue, A.: Non-Equilibrium Processing of Materials (Pergamon Press, U.K., 1999), pp. 375414.CrossRefGoogle Scholar
Szewieczek, D., Baron, A., and Nawrat, G.: Electrochemical behavior of Fe78Si9B13 alloy in sulphate and chloride solution. J. Mater. Pro. Tech. 175, 411415 (2006).CrossRefGoogle Scholar
Pang, S.J., Zhang, T., Asami, K., and Inoue, A.: Electrochemical behavior of Fe78Si9B13 alloy in sulphate and chloride solution. Acta Mater. 50, 489497 (2002).CrossRefGoogle Scholar