Hostname: page-component-586b7cd67f-t8hqh Total loading time: 0 Render date: 2024-11-23T10:31:20.207Z Has data issue: false hasContentIssue false
  • English
  • Français

Structural study of room temperature synthesized nickel thiophosphate a–NiPS3

Published online by Cambridge University Press:  31 January 2011

P. Fragnaud ,
E. Prouzet  and
R. Brec
P. Fragnaud
Affiliation:
Laboratoire de Chimie des Solides, IMN, CNRS UMR 110, 2 rue de la Houssinière, 44072, Nantes Cédex 03, France
E. Prouzet
Affiliation:
Laboratoire de Chimie des Solides, IMN, CNRS UMR 110, 2 rue de la Houssinière, 44072, Nantes Cédex 03, France
R. Brec
Affiliation:
Laboratoire de Chimie des Solides, IMN, CNRS UMR 110, 2 rue de la Houssinière, 44072, Nantes Cédex 03, France
Get access

Abstract

A structural study using x-ray diffraction and simulation calculations was performed on a–NiPS3, the highly disordered phase of the nickel thiophosphate, synthesized through a soft chemistry process. The structure of the wet gel is shown to be entirely amorphous; its x-ray pattern exhibits diffusion peaks according to the disordered anionic network. For the powdered samples, measurements of the width of the diffraction lines show that there are small crystallized c–NiPS3-type crystallites with a volume V equal to (25 × 25 × 40) Å3 (i.e., 4a × 3b × 6c in terms of volume cell). The simulation calculations of the x-ray diagrams have indicated that the stacking of these crystallites is quite imperfect: the suggested crystallite structures must contain rotated or shifted layers.

Type
Articles
Information
Journal of Materials Research , Volume 7 , Issue 7 , July 1992 , pp. 1839 - 1846
Copyright
Copyright © Materials Research Society 1992

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1.Brec, R., Solid State Ionics 22, 3 (1986).CrossRefGoogle Scholar
2.Prouzet, E., Thesis, Nantes (1988).Google Scholar
3.Prouzet, E., Ouvrard, G., Brec, R., and Seguineau, P., Solid State Ionics 31, 79 (1988).CrossRefGoogle Scholar
4.Prouzet, E., Ouvrard, G., Brec, R., Benazeth, S., and Dexpert, H., J. Chim. Phys. 86, no. 7/8, 1684 (1989).CrossRefGoogle Scholar
5.Espinat, D., Godart, E., and Thevenot, F., Analusis 15, no. 7, 337 (1987).Google Scholar
6.Fragnaud, P., Prouzet, E., Brec, R., and Mansot, J. L., to be published.Google Scholar
7.Guinier, A., Theorie et technique de la radiocristallographie, edited by Dunot, (1964).Google Scholar
8.Prouzet, E., Ouvrard, G., and Brec, R., J. of Power Sources 26, 319 (1989).CrossRefGoogle Scholar