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Some observations of microstructural changes in alumina induced by Ti inhomogeneities

Published online by Cambridge University Press:  31 January 2011

V. Jayaram
Affiliation:
Materials Department, College of Engineering, University of California, Santa Barbara, Califorina 93106
B. J. Dalgleish
Affiliation:
Materials Department, College of Engineering, University of California, Santa Barbara, Califorina 93106
A. G. Evans
Affiliation:
Materials Department, College of Engineering, University of California, Santa Barbara, Califorina 93106
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Abstract

Analysis of Ti-containing heterogeneities in a hot-pressed Al2O3 has revealed changes in microstructure caused by oxidation that provide some insight regarding the effects of Ti on local grain growth. The most consistent hypothesis is that Ti4+ in solution compensates the Mg2+ ion taken into solution from the MgO additive, probably by forming dipoles, and negates the effect of Mg2+ on grain boundary drag.

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Articles
Copyright
Copyright © Materials Research Society 1988

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References

REFERENCES

1Dalgleish, B. J.Johnson, S. M. and Evans, A. G.J. Am. Ceram. Soc. 67 (11), 741 (1984).Google Scholar
2Kroger, R. A.J. Am. Ceram. Soc. 67 (6), 390 (1984).CrossRefGoogle Scholar
3Winkler, E. R.Sarver, J. F. and Cutler, I. B.J. Am. Ceram. Soc. 49 (12), 634 (1966).CrossRefGoogle Scholar
4McKee, W. D. Jr. and Aleshin, E.J. Am. Ceram. Soc. 46 (1), 54 (1963).CrossRefGoogle Scholar
5Bagley, R. D.Cutler, I. B. and Johnson, D. L.J. Am. Ceram. Soc. 53 (3), 136 (1970).CrossRefGoogle Scholar
6Brook, R. J.J. Am. Ceram. Soc. 55 (2), 114 (1972).CrossRefGoogle Scholar
7Morgan, P. E. D. and Koutsoutis, M. S.J. Am. Ceram. Soc. 68(6), pC156 (1985).Google Scholar
8Roy, S. K. and Coble, R. L.J. Am. Ceram. Soc. 51(1), 1 (1968).Google Scholar
9Chokshi, A. H. and Porter, J. R.J. Am. Ceram. Soc. 70(3), 197 (1987).Google Scholar
10Linde, R. K. and DeCarli, P. S.J. Chem. Phys. 50, 319 (1969).CrossRefGoogle Scholar
11Jayaram, V.Philos. Mag. A 57(3), 525 (1988).Google Scholar
12Krivanek, O. L.Harmer, M. and Geiss, R.9th International Congress on Electron Microscopy, Toronto, Canada (1978), Vol. 1, pp. 414415.Google Scholar
13Clarke, D. R.Ultramicroscopy 4(1), 33 (1979).Google Scholar
14Phillips, D. S.Heuer, A. H. and Mitchell, T. E.Philos. Mag. A 42(3), 385 (1980).CrossRefGoogle Scholar
15Brook, R. J.Tuan, W. H. and Xue, L. A. Advances In Ceramics (in press).Google Scholar