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Revealing the mechanical properties of potassium dihydrogen phosphate crystals by nanoindentation

Published online by Cambridge University Press:  21 March 2016

Y. Zhang*
Affiliation:
School of Mechatronics Engineering, Harbin Institute of Technology, People's Republic of China; Ministry of Education Key Laboratory of Micro-systems and Micro-structures Manufacturing, Harbin Institute of Technology, People's Republic of China; and Laboratory for Precision and Nano Processing Technologies, The University of New South Wales, New South Wales 2052, Australia
L.C. Zhang*
Affiliation:
Laboratory for Precision and Nano Processing Technologies, The University of New South Wales, New South Wales 2052, Australia
M. Liu
Affiliation:
Laboratory for Precision and Nano Processing Technologies, The University of New South Wales, New South Wales 2052, Australia
F.H. Zhang*
Affiliation:
School of Mechatronics Engineering, Harbin Institute of Technology, People's Republic of China
K. Mylvaganam
Affiliation:
Laboratory for Precision and Nano Processing Technologies, The University of New South Wales, New South Wales 2052, Australia
W.D. Liu
Affiliation:
Laboratory for Precision and Nano Processing Technologies, The University of New South Wales, New South Wales 2052, Australia
*
a) Address all correspondence to this author. e-mail: [email protected]
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Abstract

Potassium dihydrogen phosphate (KDP) is an important nonlinear optical crystal material for light frequency converters and Pockels photoelectric switches in laser systems. However, KDP is apt to fracture, is deliquescent, and can suffer from microstructural changes under a temperature variation. As such, KDP has been one of the most difficult-to-handle materials, but its properties have not been well understood. This paper aims to explore the mechanical properties of KDP crystals in detail with the aid of the nanoindentation technique using a Berkovich diamond indenter. It was found that the mechanical properties of KDP can be easily altered by machining-induced subsurface damage. It was also discovered that a KDP crystal is a visco-elasto-plastic material during micro/nanoscale deformation, although it is very brittle macroscopically.

Type
Articles
Copyright
Copyright © Materials Research Society 2016 

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References

REFERENCES

Lines, M.E. and Glass, A.M.: Principles and Applications of Ferroelectrics and Related Materials (Clarendon press, Oxford, 2001).CrossRefGoogle Scholar
Blinc, R. and Zeks, B.: Soft Modes in Ferroelectrics and Anti-Ferroelectrics (North-Holland Pub. Co., Amsterdam, 1974).Google Scholar
Yoreo, J.J.D., Burnham, A.K., and Whitman, P.K.: Developing KH2PO4 and KD2PO4 crystals for the world's most power laser. Int. Mater. Rev. 47, 113152 (2002).CrossRefGoogle Scholar
Fedder, R.A.H., Geraghty, P., and Locke, S.N.: NIF pockels cell and frequency conversion crystals. In Lasers and Applications in Science and Engineering, Lane, Monya A. and Wuest, Craig R., eds. (International Society for Optics and Photonics: Bellingham, 2004); pp. 121126.Google Scholar
Salo, V.I., VAtroschenko, L., Garnov, S.V., and Khodeyeva, N.V.: Structure, impurity composition and laser damage threshold of the subsurface layers in KDP and KD*P single crystals. Proc. SPIE 2714, 197201 (1996).Google Scholar
Feit, M.D. and Rubenchik, A.M.: Influence of subsurface cracks on laser-induced surface damage. In XXXV Annual Symposium on Optical Materials for High Power Lasers: Boulder Damage Symposium, International Society for Optics and Photonics: 2004; pp. 264272.Google Scholar
House, R., Bettis, J.R., and Guenther, A.H.: Subsurface structure and laser damage threshold. IEEE J. Quantum Electron. 13, 363364 (1977).CrossRefGoogle Scholar
Peng, J., Zhang, L.C., and Lu, X.C.: Elastic-plastic deformation of KDP crystals under nanoindentation. Mater. Sci. Forum 773–774, 705711 (2014).Google Scholar
Endert, H. and Melle, W.: Influence of dislocations in KDP crystals on laser damage threshold. Cryst. Res. Technol. 16, 815819 (1981).Google Scholar
Anbukumar, S., Vasudevan, S., and Ramasamy, P.: Hardness anisotropy of ADP crystals. Indian J. Phys. 61A, 397405 (1987).Google Scholar
Fang, T. and Lambropoulos, J.C.: Microhardness and indentation facture of potassium dihydrogen phosphate (KDP). J. Am. Ceram. Soc. 85, 174178 (2002).CrossRefGoogle Scholar
Rao, K.K. and Sirdeshmukh, D.B.: Microhardness of some crystals with potassium dihydrogen phosphate structure. Indian J. Pure Appl. Phys. 16, 860861 (1978).Google Scholar
Shaskol'skaya, M.P., Hai-kuin, C., and Katrich, M.D.: Mechanical-properties and plastic-deformation of KDP, DKDP, ADP, and RDP crystals. Inorg. Mater. 14, 558561 (1978).Google Scholar
Wang, H.X., Wang, J.H., and Dong, S.: Nanoindentation size effect of KDP crystal by instrumented indentation testing. Key Eng. Mater. 364, 188192 (2008).CrossRefGoogle Scholar
Lu, C.P., Gao, H., Wang, J.H., Teng, X.J., and Wang, B.L.: Mechanical properties of potassium dihydrogen phosphate single crystal by the nanoindentation technique. Mater. Manuf. Processes 25, 740748 (2010).CrossRefGoogle Scholar
Wang, J.H., Chen, M.J., Dong, S., Wang, H.X., Zhang, J.H., and Zong, W.J.: Critical cutting condition for brittle-ductile transition of KDP crystals in ultra-precision machining. Key Eng. Mater. 329, 409414 (2007).CrossRefGoogle Scholar
Kucheyev, S.O., Siekhaus, W.J., Land, T.A., and Demos, S.G.: Mechanical response KD2XH2(1−X)PO4 crystals during nanoindentation. Appl. Phys. Lett. 84, 22742276 (2004).CrossRefGoogle Scholar
Guin, C.H., Katrich, M.D., Savinkov, A.I., and Shaskol'skaya, M.P.: Plastic strain and dislocation structure of the KDP Group crystals. Krist. Tech. 15, 479488 (1980).CrossRefGoogle Scholar
Fu, Y.J., Gao, Z.S., Sun, X., Wang, S.L., Li, Y.P., Zeng, H., Luo, J.P., Duan, A.D., and Wang, J.Y.: Effects of anions on rapid growth and growth habit of KDP crystals. Prog. Cryst. Growth Charact. Mater. 40, 211220 (2000).CrossRefGoogle Scholar
Bei, H., George, E.P., Hay, J.L., and Pharr, G.M.: Influence of indenter tip geometry on elastic deformation during nanoindentation. Phys. Rev. Lett. 95, 045501 (2005).CrossRefGoogle ScholarPubMed
Kim, J.Y., Kang, S.K., and Lee, J.J.: Influence of surface-roughness on indentation size effect. Acta Mater. 35, 35553563 (2005).Google Scholar
Kiely, J.D., Hwang, R.Q., and Houston, J.E.: Effect of surface steps on the plastic threshold in nanoindentation. Phys. Rev. Lett. 81, 44244427 (1998).CrossRefGoogle Scholar
Goken, M. and Kempf, M.: Pop-ins in nanoindentations—The initial yield point. Z. Metallkunde 92, 10611067 (2001).Google Scholar
Wang, Z.G., Bei, H., George, E.P., and Pharr, G.M.: Influences of surface preparation on nanoindentation pop-in in single-crystal Mo. Scr. Mater. 65, 469472 (2011).CrossRefGoogle Scholar
Wu, D.J., Chao, X.S., Wang, Q.G., Wang, B., Gao, H., and Kang, R.K.: Damage detection and analysis of machined KDP crystal subsurface. Opt. Precis. Eng. 15, 17221726 (2007).Google Scholar
Liu, C., Liua, P., Zhao, Z.B., and Northwood, D.O.: Room temperature creep of a high strength steel. Mater. Des. 22, 325328 (2001).CrossRefGoogle Scholar
Yang, S., Zhang, Y.W., and Zeng, K.Y.: Analysis of nanoindentation creep for polymeric materials. J. Appl. Phys. 95, 36553667 (2004).CrossRefGoogle Scholar
González-Doncell, G. and Sherby, O.D.: High temperature creep behavior of metal matrix aluminum-SiC composites. Acta Metall. Mater. 41, 27972805 (1993).CrossRefGoogle Scholar
Wang, S.H. and Chen, W.X.: Room temperature creep deformation and its effect on yielding behavior of a line pipe steel with discontinuous yielding. Mater. Sci. Eng., A 301, 147153 (2001).CrossRefGoogle Scholar
Li, W.B., Henshall, J.L., Hooper, R.M., and Easterling, K.E.: The mechanisms of indentation creep. Acta Metall. Mater. 39, 30993110 (1991).CrossRefGoogle Scholar
Alden, T.H.: Theory of mobile dislocation density: Application to the deformation of 304 stainless steel. Metall. Trans. A 18, 5162 (1987).CrossRefGoogle Scholar
Wang, S.H., Zhang, Y.G., and Chen, W.X.: Room temperature creep and strain-rate-dependent stress-strain behavior of pipeline steels. J. Mater. Sci. 36, 19311938 (2001).CrossRefGoogle Scholar
Mylvaganam, K., Zhang, L.C., and Zhang, Y.: Stress-induced phase and structural changes in KDP crystals. Comput. Mater. Sci. 109, 359366 (2015).CrossRefGoogle Scholar