Hostname: page-component-cd9895bd7-gbm5v Total loading time: 0 Render date: 2024-12-23T11:19:24.397Z Has data issue: false hasContentIssue false
  • English
  • Français

Radiation-induced implantation of polymeric films in metallic substrates

Published online by Cambridge University Press:  31 January 2011

M.W. Ferralli  and
M. Luntz
M.W. Ferralli
Affiliation:
Department of Physics, Mercyhurst College, Glenwood Hills, Erie, Pennsylvania 16546
M. Luntz
Affiliation:
Department of Physics, State University of New York, College at Fredonia, Fredonia, New York 14063
Get access

Abstract

Implanted, polymeric films have been produced by accelerator-ion-beam irradiation of metallic substrates immersed in hydrocarbon gases. Typical substrates include silver, aluminum, and steel; hydrocarbon gases include 1,3 butadiene and ethylene at 6.6 Pa pressure; ion beams employed include singly ionized H, He, and Ar at 30 keV. Experimental procedures and corrosion-resistance properties of the films are reviewed (each discussed elsewhere). A theory of the film-formation process is presented. It is concluded that the films form as the result of a two-stage process: glow-discharge adhesion and polymerization followed by radiation-induced implantation resulting from collisional recoil and substrate sputtering.

Type
Articles
Information
Journal of Materials Research , Volume 1 , Issue 4 , August 1986 , pp. 577 - 582
Copyright
Copyright © Materials Research Society 1986

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1Ferralli, M. W., “Deposition of Thin Organic Coats by Ion Implantation,” U. S. Patent No. 4, 264, 642 (1981).Google Scholar
2Ferralli, M. W., “Ion Induced Thin Surface Coating,” U. S. Patent No. 4, 474, 827 (1984).Google Scholar
3Taylor, S. P., Cahen, G. L., Stoner, G. E., Moran, P. J., and Ferrall, M. W.i, “Ionized Monomer Implantation into Aluminum—A Seawater Immersion Study,” Symposium of Fundamental Aspects of Corrosion Protection by Surface Modification, Washington, D. C., 9–14 October 1983 (The Electochemical Society, Pennington, NJ, 1984), Vol. 84-3.Google Scholar
4Taylor, S. P., Cahen, G. L., Stoner, G. E., Moran, P. J., and Ferralli, M. W., “Implantation of Ionized Monomer into Aluminum 6061 for Marine Corrosion Protection,” DTNSRDC-84/046, David W. Taylor Naval Ship Research and Development Center, Bethesda, Maryland 20084, July 1984.Google Scholar
5Taylor, S. R. (private communication).Google Scholar
6Boenig, H.V., Plasma Science and Technology (Cornell U. P., Ithaca, NY, 1982).CrossRefGoogle Scholar
7Lindhard, J., Scharff, M., and Schiott, H. E., Kgl. Danske Vidensk. Selskab. Mat.Fys. Medd. 33, No. 14 (1963).Google Scholar
8Luntz, M. and Figueroa, J., Phys. Rev. B 9, 87 (1974).CrossRefGoogle Scholar