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Preparation of Bi based high-Tc superconductors containing Pb and Sb by the sol-gel method

Published online by Cambridge University Press:  31 January 2011

Y. Masuda
Affiliation:
Superconducting and Cryogenic Technology Center, Kobe Steel Ltd., 1-5-5, Takatsukadai Nishi-ku, Kobe 651-22, Japan
R. Ogawa
Affiliation:
Superconducting and Cryogenic Technology Center, Kobe Steel Ltd., 1-5-5, Takatsukadai Nishi-ku, Kobe 651-22, Japan
Y. Kawate
Affiliation:
Kobelco Institute Co., Wakinohama Chuo-ku, Kobe 651, Japan
T. Tateishi
Affiliation:
Kobelco Institute Co., Wakinohama Chuo-ku, Kobe 651, Japan
N. Hara
Affiliation:
Kobelco Institute Co., Wakinohama Chuo-ku, Kobe 651, Japan
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Abstract

Preparation of Bi based high-Tc superconductors having Pb and Sb elements has been attempted using the sol-gel method. Production of the high-Tc phase was promoted by doping a little Sb (0.05 mol) together with Pb. The nominal composition of the system is Bi0.96Pb0.19Sb0.05Sr1.0Ca1.1Cu1.6Oy. It has been found that the reaction scheme of Sb doped samples is different from that of Sb nondoped samples.

Type
Articles
Copyright
Copyright © Materials Research Society 1992

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