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Preparation of a solid amine adsorbent based on polypropylene fiber and its performance for CO2 capture

Published online by Cambridge University Press:  16 October 2013

Linzhou Zhuang ,
Shuixia Chen ,
Rijia Lin  and
Xiuzhu Xu
Linzhou Zhuang
Affiliation:
PCFM Lab, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, People’s Republic of China
Shuixia Chen*
Affiliation:
PCFM Lab, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, People’s Republic of China; and DSAPM Lab, Materials Science Institute, Sun Yat-Sen University, Guangzhou 510275, People’s Republic of China
Rijia Lin
Affiliation:
PCFM Lab, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, People’s Republic of China
Xiuzhu Xu
Affiliation:
PCFM Lab, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, People’s Republic of China
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

A novel kind of solid amine-containing fibrous adsorbent (PP-GMA-TETA) was prepared through irradiation grafting copolymerization with glycidyl methacrylate (GMA) onto polypropylene (PP) fiber, followed by reacting with triethylenetetramine (TETA) to introduce primary and secondary amine groups on its surface. The effects of the reaction conditions, such as the TETA concentration, temperature, and reaction time on amination degree of PP-GMA-TETA, were investigated. Adsorption capacity of PP-GMA-TETA with 77.7% amination degree could reach 4.72 mmol/g. After adsorption, the spent fiber could be completely regenerated at 100 °C by steam for 20 min and its adsorption behavior kept almost constant within six recycles. The comparison of adsorption capacities of amine fibers aminated with various aminating agents also demonstrated that fibers with higher content of primary amine would obtain faster adsorption rates and higher adsorption capacities.

Keywords

polypropyleneaminecarbon dioxide
Type
Articles
Information
Journal of Materials Research , Volume 28 , Issue 20 , 28 October 2013 , pp. 2881 - 2889
Copyright
Copyright © Materials Research Society 2013 

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References

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