Hostname: page-component-78c5997874-8bhkd Total loading time: 0 Render date: 2024-11-19T02:58:08.375Z Has data issue: false hasContentIssue false
  • English
  • Français

Preparation and Characterization of Pb(Zr0.52Ti0.48)O3 Powders and Thin Films by a Sol-gel Route

Published online by Cambridge University Press:  31 January 2011

Dage Liu ,
Hongxi Zhang ,
Zhong Wang  and
Liancheng Zhao
Dage Liu*
Affiliation:
School of Materials Science and Engineering, Harbin Institute of Technology, P.O. Box 433, Harbin 150001, People's Republic of China, and Institute of Chemistry, Chinese Academy of Sciences, P.O. Box 2709, Beijing 100080, People's Republic of China
Hongxi Zhang
Affiliation:
School of Science, Harbin Institute of Technology, P.O. Box 408, Harbin 150001, People's Republic of China
Zhong Wang
Affiliation:
School of Materials Science and Engineering, Harbin Institute of Technology, P.O. Box 433, Harbin 150001, People's Republic of China
Liancheng Zhao
Affiliation:
School of Materials Science and Engineering, Harbin Institute of Technology, P.O. Box 433, Harbin 150001, People's Republic of China
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

Lead zirconate titanate [Pb(ZrxTi1−x)O3 (PZT)] powders and ferroelectric thin films with a composition near the morphotropic phase boundary [Pb(Zr0.52Ti0.48)O3] were prepared by a modified sol-gel process using zirconium oxynitrate-2-hydrate as the zirconium source and ethylene glycol as solvent. The precursor solution was prepared from lead acetate-3-hydrate, tetrabutyl titanate, and zirconium oxynitrate-2-hydrate. Perovskite PZT powders were obtained after sintering at 450 °C for 2 h. Films rapid-thermally annealed at 650 °C for 1 min formed well-crystallized perovskite.Microstructures of these films indicated the presence of nano-sized grains (∼50 nm). The remnant polarization was 28.5 μC/cm2, and the coercive field was 39.8 kV/cm. Ferroelectric polarization fatigue test of In/PZT/Pt/Ti/SiO2/Si showed a high fatigue resistance up to 3 × 1010 cycles before Pr decreased by 50%.

Type
Articles
Information
Journal of Materials Research , Volume 15 , Issue 6 , June 2000 , pp. 1336 - 1341
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Schwartz, R.W., Voigt, J.A., Tuttle, B.A., Payne, D.A., Reichert, T.L., and Dasalla, R.S., J. Mater. Res. 12, 444 (1997).CrossRefGoogle Scholar
2.Chen, S.Y. and Chen, I.W., J. Am. Ceram. Soc. 81, 97 (1998).CrossRefGoogle Scholar
3.Lakeman, C.D.E and Payne, D.A., J. Am. Ceram. Soc. 75, 3091 (1992).Google Scholar
4.Roy, R., Science 238, 1664 (1987).CrossRefGoogle Scholar
5.Xu, Y. and Mackenzie, J.D., Integr. Ferroelectr. 1, 17 (1992).CrossRefGoogle Scholar
6.Cross, L.E., Am. Ceram. Soc. Bull. 67, 578 (1988).Google Scholar
7.Hwang, C.S. and Kim, H.J., J. Am. Ceram. Soc. 78, 329 (1995).CrossRefGoogle Scholar
8.Selvaraj, U., Brooks, K., Prasadarao, A.V., Kamarneni, S., Roy, R., and Cross, L.E., J. Am. Ceram. Soc. 76, 1441 (1993).CrossRefGoogle Scholar
9.Kim, S.H., Chios, Y.S., Chios, C.E., Kim, C.E., and Oh, Y.J., J. Mater. Res. 12, 1576 (1997).CrossRefGoogle Scholar
10.Calzada, M.L. and Olmo, L.D., J. Non-Cryst. Solids 121, 413 (1990).CrossRefGoogle Scholar
11.Budd, K.D., Dey, S.K., and Payne, D.A. Br, Ceram. Proc. 36, 107 (1985).Google Scholar
12.Tu, Y.L., Calzada, M.L., Phillips, N.J., and Milne, S.J., J. Am. Ceram. Soc. 79, 441 (1996).CrossRefGoogle Scholar
13.Huglin, M.B., Light Scattering From Polymer Solutions (Academic Press, New York, 1972).Google Scholar
14.Nakamoto, K., Infrared and Raman Spectra of Inorganic Coordination Components (Wiley, New York, 1986).Google Scholar
15.Barton, D. and Ollis, W.D., Comprehensive Organic Chemistry: The Synthesis and Reactions of Organic Compounds, Vol. 2 (Pergamon, United Kingdom, 1979).Google Scholar
16.Ramamuthi, S.D. and Payne, D.A., J. Am. Ceram. Soc. 73, 2547 (1990).CrossRefGoogle Scholar
17.Li, S., Condrate, R.A. Sr, and Spriggs, R.M., Spectrosc. Lett. 21, 969 (1988).Google Scholar
18.Lakeman, C.E.D, Campion, J-F., and Payne, D.A., in Ceramic Transaction 25, edited by Bhalla, A.S. and Nair, K.M. (The American Ceramic Society, Columbus, OH 1992), p. 413.Google Scholar
19.Chen, K.C. and Mackenzie, J.D., in Better Ceramics Through Chemistry IV, edited by Zelinski, B.J.J, Brinker, C.J., Clark, D.E., and Ulrich, D.R. (Mater. Res. Soc. Symp. Proc. 180, Pittsburgh, PA, 1990), p. 663.Google Scholar
20.Warren, W.L., Dimos, D., Al-Shareef, H.V., Raymond, M.V., Tuttle, B.A., and Pike, G.E., J. Am. Ceram. Soc. 79, 1714 (1996).CrossRefGoogle Scholar
21.Duiker, M., Beale, P.D., Scott, J.F., Paz de Araujo, C.A., Melnick, B.M., and Cuchi, J.D., J. Appl. Phys. 68, 5783 (1990).CrossRefGoogle Scholar
22.Lee, J., Thio, C.L., and Desu, S.B., J. Appl. Phys. 78, 5073 (1995).Google Scholar