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Polyol-mediated preparation of disklike (ZnSe)2·EN precursor and its conversion to ZnSe crystals with quasi-network structure

Published online by Cambridge University Press:  03 March 2011

Guozhen Shen ,
Di Chen ,
Kaibin Tang  and
Yitai Qian
Guozhen Shen*
Affiliation:
Department of Chemistry and Structure Research Laboratory, University of Science and Technology of China, Hefei 230026, People’s Republic of China
Di Chen
Affiliation:
Department of Chemistry and Structure Research Laboratory, University of Science and Technology of China, Hefei 230026, People’s Republic of China
Kaibin Tang
Affiliation:
Department of Chemistry and Structure Research Laboratory, University of Science and Technology of China, Hefei 230026, People’s Republic of China
Yitai Qian
Affiliation:
Department of Chemistry and Structure Research Laboratory, University of Science and Technology of China, Hefei 230026, People’s Republic of China
*
a) Address all correspondence to this author. e-mail: [email protected]
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Abstract

In this paper, we reported the rapid synthesis of disklike (ZnSe)2·EN precursor via a simple and convenient polyol method. Annealing the precursor in argon stream at 500 °C resulted in the formation of ZnSe crystals with unique quasi-network structure. The obtained samples were characterized by powder x-ray diffraction, field-emission scanning electron microscopy, transmission electron microscopy, infrared absorbance spectra, and thermogravimetric analysis. The influence of PEG200 on the final products in the system was also discussed.

Keywords

Chemical synthesisNanoscaleScanning electron microscopy (SEM)
Type
Articles
Information
Journal of Materials Research , Volume 19 , Issue 5 , May 2004 , pp. 1369 - 1373
Copyright
Copyright © Materials Research Society 2004

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