Hostname: page-component-586b7cd67f-dsjbd Total loading time: 0 Render date: 2024-11-23T04:26:38.272Z Has data issue: false hasContentIssue false
  • English
  • Français

Plasmon resonance absorption in sulfide-coated gold nanorods

Published online by Cambridge University Press:  01 January 2006

K. Chatterjee ,
S. Basu  and
D. Chakravorty
K. Chatterjee
Affiliation:
Indian Association for the Cultivation of Science, Kolkata 700 032, India
S. Basu
Affiliation:
Indian Association for the Cultivation of Science, Kolkata 700 032, India
D. Chakravorty*
Affiliation:
Indian Association for the Cultivation of Science, Kolkata 700 032, India
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

Gold nanorods 100 nm in diameter were grown within polycarbonate membranes as templates by the electrodeposition technique. A low-temperature sulfidation process was used to make gold sulfide nanoshells around the nanorods with a thickness of ∼7 nm. Optical absorption measurements were carried out on sulfide-coated gold nanorods obtained by dissolving the polycarbonate membrane. Several peaks were observed. These were analyzed on the basis of longitudinal and transverse modes of gold nanorods, the core–shell structure of gold–gold sulfide, and the presence of nanoparticles of gold. Theoretical analysis was carried out using a modified Mie scattering formalism. Satisfactory agreement between experimental results and theoretical fits were obtained.

Keywords

ElectrodepositionNanoscaleOptical properties
Type
Articles
Information
Journal of Materials Research , Volume 21 , Issue 1 , January 2006 , pp. 34 - 40
Copyright
Copyright © Materials Research Society 2006

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Weissman, J.M., Sunkara, H.B., Tse, A.S. and Asher, S.A.: Thermally switchable periodicities and diffraction from mesoscopically ordered materials. Science 274, 959 (1996).CrossRefGoogle ScholarPubMed
2.Elghanian, R., Storhoff, J.J., Mucic, R.C., Letsinger, R.L. and Mirkin, C.A.: Selective colorimetric detection of polynucleotides based on the distance-dependent optical properties of gold nanoparticles. Science 277, 1078 (1997).CrossRefGoogle ScholarPubMed
3.Mirkin, C.A., Letsinger, R.L., Mucic, R.C. and Storhoff, J.J.: A DNA-based method for rationally assembling nanoparticles into macroscopic materials. Nature (London) 382, 607 (1996).CrossRefGoogle ScholarPubMed
4.Haynes, C.L. and Van Duyne, R.P.: Nanosphere lithography: A versatile nanofabrication tool for studies of size-dependent nanoparticle optic. J. Phys. Chem. B 105, 5599 (2001).CrossRefGoogle Scholar
5.Schubert, E.F., Hunt, N.E.J., Micovic, M., Malik, R.J., Sivco, D.L., Cho, A.Y. and Zydzik, G.J.: Highly efficient light-emitting diodes with microcavities. Science 265, 943 (1994).CrossRefGoogle ScholarPubMed
6.Wanke, M.C., Lehmann, O., Muller, K., Wen, Q. and Stuke, M.: Laser rapid prototyping of photonic band-gap microstructures Science 275, 1284 (1997).CrossRefGoogle ScholarPubMed
7.Joannopoulous, J.D., Villeneuve, P.R. and Fan, S.: Photonic crystals: Putting a new twist on light. Nature (London) 386, 143 (1997).CrossRefGoogle Scholar
8.Hache, F., Ricard, D. and Flytzanis, C.: Optical nonlinearities of small metal particles: Surface-mediated resonance and quantum-size effects. J. Opt. Soc. Am. B 3, 1647 (1986).CrossRefGoogle Scholar
9.Wang, D.S. and Kerker, M.: Enhanced Raman scattering by molecules adsorbed at the surface of colloidal spheroids. Phys. Rev. B 24, 1777 (1981).CrossRefGoogle Scholar
10.Li, Z.S., Kan, C.X. and Cai, W.P.: Tunable optical properties of nanostructured-gold/mesoporous-silica assembly. Appl. Phys. Lett. 82, 1392 (2003).CrossRefGoogle Scholar
11.Mie, G.: Contribution to the optics of turbid media specifically colloidal metal particles. Ann. Phys. (Leipzig) 25, 377 (1908).CrossRefGoogle Scholar
12.Granqvist, C.G., Clander, N. and Hunderi, O.: Optical properties of ultrafine silver particles. Solid State Commun. 31, 249 (1979).CrossRefGoogle Scholar
13.Sonnichsen, C., Franzl, T., Wilk, T., Von Plessen, G., Feldmann, J., Wilson, O. and Mulvaney, P.: Drastic reduction of plasmon damping in gold nanorods phys. Rev. Lett. 88, 077402 (2002).CrossRefGoogle Scholar
14.Neeves, A.E. and Birnboim, M.H.: Composite structures for the enhancement of nonlinear optical materials. Opt. Lett. 134, 1087 (1988).CrossRefGoogle Scholar
15.Haus, J.W., Zhou, H.S., Honma, I. and Komiyama, H.: Enhanced optical properties of metal-coated nanoparticles. J. Appl. Phys. 73, 1043 (1993).CrossRefGoogle Scholar
16.Chatterjee, K., Banerjee, S. and Chakravorty, D.: Plasmon resonance shifts in oxide-coated silver nanoparticles. Phys. Rev. B66, 085421 (2002).CrossRefGoogle Scholar
17.Banerjee, S., Banerjee, S., Datta, A. and Chakravorty, D.: Nanocomposite gel-derived films by fractal growth of silver. Europhys. Lett. 46, 346 (1999).CrossRefGoogle Scholar
18.Bhattacharyya, S., Saha, S.K. and Chakravorty, D.: Silver nanowires grown in the pores of a silica gel. Appl. Phys. Lett. 77, 3770 (2000).CrossRefGoogle Scholar
19.Dan, A., Satpati, B., Satyam, P.V. and Chakravorty, D.: Diodelike behavior in glass-metal nanocomposites. J. Appl. Phys. 93, 4794 (2003).CrossRefGoogle Scholar
20.Handbook of Chemistry and Physics, edited by Hodgman, C.D. (The Chemical Rubber Publishing Co., Cleveland, OH, 1962), p. 2672.Google Scholar
21.Gans, R.: Form of ultramicroscopic particles of silver. Ann. Physik. 47, 270 (1915).CrossRefGoogle Scholar
22.Papavassiliou, G.C.: Optical properties of small inorganic and organic metal particles. Prog. Solid State Chem. 12, 185 (1980).CrossRefGoogle Scholar
23.Johnson, P.B. and Christy, R.W.: Optical constants of the noble metals. Phys. Rev. B 6, 4370 (1972).CrossRefGoogle Scholar
24.Link, S., Mohamed, M.B. and El-Sayed, M.A.: Simulation of the optical absorption spectra of gold nanorods as a function of their aspect ratio and the effect of the medium dielectric constant. J. Phys. Chem. B 103, 3073 (1999).CrossRefGoogle Scholar
25.Zhou, H.S., Honma, I., Komiyama, H. and Hous, J.W.: Controlled synthesis and quantum-size effect in gold-coated nanoparticles. Phys. Rev. B 50, 12052 (1994).CrossRefGoogle ScholarPubMed
26.Kreibig, U.: Electronic properties of small silver particles: The optical constants and their temperature dependence. J. Phys. F: Met. Phys. 4, 999 (1974).CrossRefGoogle Scholar
27.Kittel, C.: Introduction to Solid State Physics (Wiley, New York, London, 1961), p. 374.Google Scholar