Hostname: page-component-586b7cd67f-2plfb Total loading time: 0 Render date: 2024-11-26T19:11:03.589Z Has data issue: false hasContentIssue false
  • English
  • Français

Phase Separation of Gold Microcrystals in Glass with an Electric Field

Published online by Cambridge University Press:  03 March 2011

Guoliang Wang ,
Kaiming Liang ,
Wei Liu ,
Feng Zhou ,
Hua Shao  and
Anmin Hu
Guoliang Wang*
Affiliation:
Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, People’s Republic of China
Kaiming Liang
Affiliation:
Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, People’s Republic of China
Wei Liu
Affiliation:
Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, People’s Republic of China
Feng Zhou
Affiliation:
Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, People’s Republic of China
Hua Shao
Affiliation:
Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, People’s Republic of China
Anmin Hu
Affiliation:
Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, People’s Republic of China
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

Based on static electromagnetics theory and thermodynamics theory, a new model is proposed to describe the phase separation from the glass doped with metal particles in a static electric field. This model is proved by a heat-treatment experiment of boracic silicate glass doped with gold. The results indicate that the externally applied electric field promotes the phase separation of the glass and leads to a different size of the droplet phase just as this new model has predicted.

Keywords

Nucleation & growthGlassThermodynamic properties
Type
Articles
Information
Journal of Materials Research , Volume 19 , Issue 4 , April 2004 , pp. 1024 - 1028
Copyright
Copyright © Materials Research Society 2004

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1Recard, D., Roussignol, P. and Plytzanis, C.: Opt. Lett. 10, 511 (1985).Google Scholar
2Sasai, J. and Hirao, K.I.: Solids. 290, 49 (2001).Google Scholar
3Kineri, T., Mori, M., Kadono, K., Sakaguchi, T., Miya, M., Wakabayashi, H. and Tsuchiya, T.: J. Ceram. Soc. Jpn. 103, 117 (1995).Google Scholar
4Battaglin, G., Boscolo-Boscoletto, A., Mazzoldi, P., Meneghini, C. and Arnold, G.W.: Nucl. Instrum. and Meth. B 116, 527 (1996).Google Scholar
5Matsuoka, J., Mizutani, R., Kaneko, S., Nasu, H., Kamiya, K., Kadono, K., Sakaguchi, T. and Miya, M.: J. Ceram. Soc. Jpn. 101, 53 (1993).Google Scholar
6Selvan, S.T., Hayakawa, T., Nogami, M., Kobayashi, Y., Liz-Marzan, L.M., Hamanaka, Y. and Nakamura, A.: J. Phys. Chem. B. 106, 10157 (2002).Google Scholar
7Valentin, E., Bernas, H., Ricolleau, C. and Creuzet, F.: Phys. Rev. Lett. 86, 99 (2001).Google Scholar
8Schmelzer, J., Lembke, U. and Kranold, R.: J. Chem. Phys. 113, 1268 (2000).CrossRefGoogle Scholar
9Hopper, R.W. and Uhlmann, D.R.: Phys. Chem. Glasses. 14, 37 (1973).Google Scholar
10Liu, W., Liang, K.M., Zheng, Y.K., Gu, S.R. and Chen, H.: J. Phys. D: Appl. Phys. 30, 3366 (1997).Google Scholar
11Liu, W., Gu, X.M., Liang, K.M., Chen, H., Zheng, Y.K. and Gu, S.R.: Metall. Mater. Trans. B. 30B, 685 (1999).Google Scholar
12Liu, W., Liang, K.M., Gu, X.M., Zheng, Y.K. and Gu, S.R.: J. Mater. Sci. 34, 3455 (1999).CrossRefGoogle Scholar
13Bleaney, B.I. and Bleaney, B. in Electricity and Magnetism , 3rd ed. (Oxford University Press, Oxford, U.K., 1976), Chap. 1 and 2Google Scholar
14Pratima, R. and Robert, D.: Solids. 203, 202 (1996).Google Scholar