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Optical Properties of Laser-dye-doped Polyvinylcarbazole Films Coated with Polycarbonate

Published online by Cambridge University Press:  31 January 2011

A. Arena
Affiliation:
Istituto Nazionale per la Fisica della Materia (INFM) and Dipartimento di Fisica della Materia e Tecnologie Fisiche Avanzate, Universitádi Messina, Salita Sperone 31, c.p.57, I-98166 Messina, Italy
F. Bonsignore
Affiliation:
Istituto Nazionale per la Fisica della Materia (INFM) and Dipartimento di Fisica della Materia e Tecnologie Fisiche Avanzate, Universitádi Messina, Salita Sperone 31, c.p.57, I-98166 Messina, Italy
S. Patanè
Affiliation:
Istituto Nazionale per la Fisica della Materia (INFM) and Dipartimento di Fisica della Materia e Tecnologie Fisiche Avanzate, Universitádi Messina, Salita Sperone 31, c.p.57, I-98166 Messina, Italy
G. Saitta
Affiliation:
Istituto Nazionale per la Fisica della Materia (INFM) and Dipartimento di Fisica della Materia e Tecnologie Fisiche Avanzate, Universitádi Messina, Salita Sperone 31, c.p.57, I-98166 Messina, Italy
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Abstract

Spectrophotometry in the ultraviolet-visible-infrared range was used to investigate the optical properties of polymer bilayers obtained by spin coating polycarbonate films about 1 μm thick on top of pyrromethene-doped polyvinylcarbazole (PVK) layers deposited on glass. Due to the light confinement in the PVK plane, the laser-dye photoluminescence collected along the polymer plane was linearly polarized and shifted from green to yellow according to the active film thickness. To laterally contain light, microstructures were imprinted on laser-dye-doped PVK films by soft lithography. The photoluminescence coming out of a microstructured film and the film topography were analyzed by scanning near-field optical microscopy.

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Articles
Copyright
Copyright © Materials Research Society 2002

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