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Nonuniform distribution of second phase particles in melt-textured Y–Ba–Cu–O oxide with metal oxide (CeO2, SnO2, and ZrO2) addition

Published online by Cambridge University Press:  03 March 2011

Chan-Joong Kim ,
Ki-Baik Kim ,
Gye-Won Hong  and
Ho-Yong Lee
Chan-Joong Kim
Affiliation:
Superconductivity Research Laboratory, Korea Atomic Energy Research Institute, P.O. Box 105, Yusung, Taejon, 305-600, Korea
Ki-Baik Kim
Affiliation:
Superconductivity Research Laboratory, Korea Atomic Energy Research Institute, P.O. Box 105, Yusung, Taejon, 305-600, Korea
Gye-Won Hong
Affiliation:
Superconductivity Research Laboratory, Korea Atomic Energy Research Institute, P.O. Box 105, Yusung, Taejon, 305-600, Korea
Ho-Yong Lee
Affiliation:
Department of Material Science and Engineering, Sungwha University, Choongnam, 337-840, Korea
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Abstract

Segregation of second-phase particles within Y1Ba2Cu3O7−y domain was investigated in melt-textured Y-Ba-Cu-O with metal oxide (CeO2, SnO2, and ZrO2) addition. It is found that coarse particles (Y2Ba1Cu1O5) are trapped with a special pattern in the interior of Y1Ba2Cu3O7−y domain, while fine BaCeO3 and BaSnO3 particles are present within the remnant liquid-phase region. During the growth of Y1Ba2Cu3O7−y domain, fine particles appear to be pushed out of the advancing Y1Ba2Cu3O7−y /liquid interface toward the liquid phase. The particle segregation that occurred during peritectic growth of the Y1Ba2Cu3O7−y domain was explained in terms of the Uhlmann-Chalmers-Jackson theory based on the particle interaction at solid/liquid interface.

Type
Articles
Information
Journal of Materials Research , Volume 10 , Issue 7 , July 1995 , pp. 1605 - 1610
Copyright
Copyright © Materials Research Society 1995

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References

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