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Nitrogen-doped zinc/cobalt mixed oxide micro-/nanospheres for high-rate lithium-ion battery anode

Published online by Cambridge University Press:  03 September 2019

Xiaotao Deng ,
Sirui Li ,
Jiaqi Wang ,
Ding Nan ,
Junhui Dong  and
Jun Liu
Xiaotao Deng
Affiliation:
Pipeline Design Department, Zhuhai Branch of China Petroleum Pipeline Engineering Co., Ltd., Zhuhai 519015, People’s Republic of China
Sirui Li
Affiliation:
School of Materials Science and Engineering, Inner Mongolia University of Technology, Hohhot 010051, China; and Inner Mongolia Key Laboratory of Graphite and Graphene for Energy Storage and Coating, Hohhot 010051, China
Jiaqi Wang
Affiliation:
School of Materials Science and Engineering, Inner Mongolia University of Technology, Hohhot 010051, China; and Inner Mongolia Key Laboratory of Graphite and Graphene for Energy Storage and Coating, Hohhot 010051, China
Ding Nan*
Affiliation:
School of Materials Science and Engineering, Inner Mongolia University of Technology, Hohhot 010051, China; and Inner Mongolia Key Laboratory of Graphite and Graphene for Energy Storage and Coating, Hohhot 010051, China
Junhui Dong
Affiliation:
School of Materials Science and Engineering, Inner Mongolia University of Technology, Hohhot 010051, China; and Inner Mongolia Key Laboratory of Graphite and Graphene for Energy Storage and Coating, Hohhot 010051, China
Jun Liu*
Affiliation:
School of Materials Science and Engineering, Inner Mongolia University of Technology, Hohhot 010051, China; and Inner Mongolia Key Laboratory of Graphite and Graphene for Energy Storage and Coating, Hohhot 010051, China
*
a)Address all correspondence to these authors. e-mail: [email protected]
b)e-mail: [email protected]
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Abstract

Metal oxides are promising candidates as the anodes of next-generation lithium ion batteries. However, the low electronic conductivities hinder their practical applications. Herein, through a facile calcination process using ammonium bicarbonate (NH4HCO3) as the N source, the nitrogen heteroelement was introduced into the ZnO/CoO micro-/nanospheres, which greatly improves the conductivity of the composites. As the lithium-ion battery anode, the N-doped ZnO/CoO micro-/nanosphere demonstrates much enhanced electrochemical performance. It displays a high initial capacity of 911.8 mA h/g at a current density of 0.2 A/g and long-term cycling stability, with a reversible capacity of 977.8 mA h/g remained after 500 cycles at a current density of 1 A/g. Furthermore, the N-doped ZnO/CoO composite presents an outstanding rate performance, with 605 mA h/g remained even at 5 A/g. The excellent electrochemical properties make N-doped ZnO/CoO micro-/nanospheres a promising candidate as high-performance anodes for next-generation rechargeable LIBs.

Keywords

nitrogen dopingzinc/cobalt mixed oxidemicro-/nanosphereslithium-ion batterieshigh rate capability
Type
Article
Information
Journal of Materials Research , Volume 34 , Issue 18 , 30 September 2019 , pp. 3204 - 3211
Copyright
Copyright © Materials Research Society 2019 

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References

Manthiram, A.: Materials challenges and opportunities of lithium ion batteries. J. Phys. Chem. Lett. 2, 373 (2011).CrossRefGoogle Scholar
Lu, L., Han, X., Li, J., Hua, J., and Ouyang, M.: A review on the key issues for lithium-ion battery management in electric vehicles. J. Power Sources 226, 272 (2013).CrossRefGoogle Scholar
Scrosati, B., Hassoun, J., and Sun, Y-K.: Lithium-ion batteries. A look into the future. Energy Environ. Sci. 4, 3287 (2011).CrossRefGoogle Scholar
Shen, L., Chen, S., Maier, J., and Yu, Y.: Carbon-coated Li3VO4 spheres as constituents of an advanced anode material for high-rate long-life lithium-ion batteries. Adv. Mater. 29, 1701571–1701577 (2017).CrossRefGoogle ScholarPubMed
Xu, X., Zhao, R., Ai, W., Chen, B., Du, H., Wu, L., Zhang, H., Huang, W., and Yu, T.: Controllable design of MoS2 nanosheets anchored on nitrogen-doped graphene: Toward fast sodium storage by tunable pseudocapacitance. Adv. Mater. 30, 1800658–1800664 (2018).CrossRefGoogle ScholarPubMed
Lukatskaya, M.R., Dunn, B., and Gogotsi, Y.: Multidimensional materials and device architectures for future hybrid energy storage. Nat. Commun. 7, 12647–12659 (2016).CrossRefGoogle ScholarPubMed
Poizot, P., Laruelle, S., Grugeon, S., Dupont, L., and Tarascon, J.M.: Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries. Nature 407, 496 (2000).CrossRefGoogle ScholarPubMed
Ji, L., Lin, Z., Alcoutlabi, M., and Zhang, X.: Recent developments in nanostructured anode materials for rechargeable lithium-ion batteries. Energy Environ. Sci. 4, 2682 (2011).CrossRefGoogle Scholar
Jiaojiao, D., Xiaoliang, Y., Yanbing, H., Baohua, L., Quan-Hong, Y., and Feiyu, K.: A sliced orange-shaped ZnCo2O4 material as anode for high-performance lithium ion battery. Energy Storage Mater. 6, 61 (2017).Google Scholar
Sharma, Y., Sharma, N., Rao, G.V.S., and Chowdari, B.V.R.: Nanophase ZnCo2O4 as a high performance anode material for Li-ion batteries. Adv. Funct. Mater. 17, 2855 (2007).CrossRefGoogle Scholar
Du, N., Xu, Y., Zhang, H., Yu, J., Zhai, C., and Yang, D.: Porous ZnCo2O4 nanowires synthesis via sacrificial templates: High-performance anode materials of Li-ion batteries. Inorg. Chem. 50, 3320 (2011).CrossRefGoogle ScholarPubMed
Liu, H. and Wang, J.: One-pot synthesis of ZnCo2O4 nanorod anodes for high power lithium ions batteries. Electrochim. Acta 92, 371 (2013).CrossRefGoogle Scholar
Luo, W., Hu, X., Sun, Y., and Huang, Y.: Electrospun porous ZnCo2O4 nanotubes as a high-performance anode material for lithium-ion batteries. J. Mater. Chem. 22, 8916 (2012).CrossRefGoogle Scholar
Wang, Z., Zhou, L., and Lou, X.W.: Metal oxide hollow nanostructures for lithium-ion batteries. Adv. Mater. 24, 1903 (2012).CrossRefGoogle ScholarPubMed
Zhu, Y., Cao, C., Zhang, J., and Xu, X.: Two-dimensional ultrathin ZnCo2O4 nanosheets: General formation and lithium storage application. J. Mater. Chem. A 3, 9556 (2015).CrossRefGoogle Scholar
Zhao, Y., Li, X., Yan, B., Xiong, D., Li, D., Lawes, S., and Sun, X.: Recent developments and understanding of novel mixed transition-metal oxides as anodes in lithium ion batteries. Adv. Energy Mater. 6, 1502175 (2016).CrossRefGoogle Scholar
Mei, J., Liao, T., Kou, L., and Sun, Z.: Two-Dimensional metal oxide nanomaterials for next-generation rechargeable batteries. Adv. Mater. 29, 1700176 (2017).CrossRefGoogle ScholarPubMed
Mei, J., Liao, T., Spratt, H., Ayoko, G.A., Zhao, X., and Sun, Z.: Honeycomb-inspired heterogeneous bimetallic Co–Mo oxide nanoarchitectures for high-rate electrochemical lithium storage. Small Methods 3, 1900055 (2019).CrossRefGoogle Scholar
Rai, A.K., Trang Vu, T., Paul, B.J., and Kim, J.: Synthesis of nano-sized ZnCo2O4 anchored with graphene nanosheets as an anode material for secondary lithium ion batteries. Electrochim. Acta 146, 577 (2014).CrossRefGoogle Scholar
Liu, B., Wang, X., Liu, B., Wang, Q., Tan, D., Song, W., Hou, X., Chen, D., and Shen, G.: Advanced rechargeable lithium-ion batteries based on bendable ZnCo2O4-urchins-on-carbon-fibers electrodes. Nano Res. 6, 525 (2013).CrossRefGoogle Scholar
Ru, Q., Song, X., Mo, Y., Guo, L., and Hu, S.: Carbon nanotubes modified for ZnCo2O4 with a novel porous polyhedral structure as anodes for lithium ion batteries with improved performances. J. Alloys Compd. 654, 586 (2016).CrossRefGoogle Scholar
Chunshuang, Y., Yue, Z., Yutao, L., Zhiwei, F., Lele, P., Xin, Z., Gang, C., and Guihua, Y.: Local built-in electric field enabled in carbon-doped Co3O4 nanocrystals for superior lithium-ion storage. Adv. Funct. Mater. 28, 1705951 (2018).Google Scholar
Subburaj, T., Prasanna, K., Kim, K.J., Ilango, P.R., Jo, Y.N., and Lee, C.W.: Structural and electrochemical evaluation of bismuth doped lithium titanium oxides for lithium ion batteries. J. Power Sources 280, 23 (2015).CrossRefGoogle Scholar
Xu, J., Liao, Z., Zhang, J., Gao, B., Chu, P.K., and Huo, K.: Heterogeneous phosphorus-doped WO3−x/nitrogen-doped carbon nanowires with high rate and long life for advanced lithium-ion capacitors. J. Mater. Chem. A 6, 6916 (2018).CrossRefGoogle Scholar
Wang, Y., Xue, X., Liu, P., Wang, C., Yi, X., Hu, Y., Ma, L., Zhu, G., Chen, R., and Chen, T.: Atomic substitution enabled synthesis of vacancy-rich two-dimensional black TiO2−x nanoflakes for high-performance rechargeable magnesium batteries. ACS Nano 12, 12492 (2018).CrossRefGoogle ScholarPubMed
Wu, G., Jia, Z., Cheng, Y., Zhang, H., Zhou, X., and Wu, H.: Easy synthesis of multi-shelled ZnO hollow spheres and their conversion into hedgehog-like ZnO hollow spheres with superior rate performance for lithium ion batteries. Appl. Surf. Sci. 464, 472 (2019).CrossRefGoogle Scholar
Xu, M., He, S., Chen, H., Cui, G., Zheng, L., Wang, B., and Wei, M.: TiO2−x-modified ni nanocatalyst with tunable metal–support interaction for water–gas shift reaction. ACS Catal. 7, 7600 (2017).CrossRefGoogle Scholar
Liu, S., Zhou, J., and Song, H.: 2D Zn-hexamine coordination frameworks and their derived N-rich porous carbon nanosheets for ultrafast sodium storage. Adv. Energy Mater. 8, 1800569 (2018).CrossRefGoogle Scholar
Huang, X., Xia, X., Yuan, Y., and Zhou, F.: Porous ZnO nanosheets grown on copper substrates as anodes for lithium ion batteries. Electrochim. Acta 56, 4960 (2011).CrossRefGoogle Scholar
Das, B., Reddy, M., Rao, G.S., and Chowdari, B.: Synthesis of porous-CoN nanoparticles and their application as a high capacity anode for lithium-ion batteries. J. Mater. Chem. 22, 17505 (2012).CrossRefGoogle Scholar
Das, B., Reddy, M., Malar, P., Osipowicz, T., Rao, G.S., and Chowdari, B.: Nanoflake CoN as a high capacity anode for Li-ion batteries. Solid State Ionics 180, 1061 (2009).CrossRefGoogle Scholar
Deng, J., Yu, X., Qin, X., Li, B., and Kang, F.: Carbon sphere-templated synthesis of porous yolk–shell ZnCo2O4 spheres for high-performance lithium storage. J. Alloys Compd. 780, 65 (2019).CrossRefGoogle Scholar
Deng, J., Yu, X., Qin, X., Zhou, D., Zhang, L., Duan, H., Kang, F., Li, B., and Wang, G.: Co–B nanoflakes as multifunctional bridges in ZnCo2O4 micro-/nanospheres for superior lithium storage with boosted kinetics and stability. Adv. Energy Mater. 9, 1803612 (2019).CrossRefGoogle Scholar
Deng, J., Yu, X., Qin, X., Liu, B., He, Y-B., Li, B., and Kang, F.: Controlled synthesis of anisotropic hollow ZnCo2O4 octahedrons for high-performance lithium storage. Energy Storage Mater. 11, 184 (2018).CrossRefGoogle Scholar
Deng, J., Yu, X., He, Y., Li, B., Yang, Q-H., and Kang, F.: A sliced orange-shaped ZnCo2O4 material as anode for high-performance lithium ion battery. Energy Storage Mater. 6, 61 (2017).CrossRefGoogle Scholar
Jiang, Y., Song, Y., Pan, Z., Meng, Y., Jiang, L., Wu, Z., Yang, P., Gu, Q., Sun, D., and Hu, L.: Rapid amorphization in metastable CoSeO3·H2O nanosheets for ultrafast lithiation kinetics. ACS Nano 12, 5011 (2018).CrossRefGoogle ScholarPubMed
Li, Y., Zhao, Y., Ma, C., and Zhao, Y.: Promising carbon matrix derived from willow catkins for the synthesis of SnO2/C composites with enhanced electrical performance for Li-ion batteries. Nano 13, 1850087 (2018).CrossRefGoogle Scholar