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Molecular composite films of MoS2 and styrene

Published online by Cambridge University Press:  31 January 2011

W.M.R. Divigalpitiya ,
R.F. Frindt  and
S.R. Morrison
W.M.R. Divigalpitiya
Affiliation:
Physics Department, Simon Fraser University, Burnaby, British Columbia, Canada, V5A 1S6
R.F. Frindt
Affiliation:
Physics Department, Simon Fraser University, Burnaby, British Columbia, Canada, V5A 1S6
S.R. Morrison
Affiliation:
Physics Department, Simon Fraser University, Burnaby, British Columbia, Canada, V5A 1S6
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Abstract

Novel composite films with a monolayer of organic molecules included between single molecular layers of MoS2 can be prepared with a recently described technique. Styrene-included MoS2, before and after polymerization, is discussed as an example that exhibits interesting properties. The sensitivity to humidity of the styrene-included MoS2 system is monitored in situ with x-ray diffraction where reversible incorporation and removal of water molecules are observed. Films with an anisotropy of electrical conductivity of about 108 are obtained by polymerizing the monomer between the layers.

Type
Articles
Information
Journal of Materials Research , Volume 6 , Issue 5 , May 1991 , pp. 1103 - 1107
Copyright
Copyright © Materials Research Society 1991

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References

1Friend, R. H. and Yoffe, A. F., Adv. in Phys. 36, 1 (1987).CrossRefGoogle Scholar
2Lee, P. A., Physics and Chemistry of Materials with Layered Structure, Vol. 4, Optical and Electrical Properties, edited by Lee, P. A. (D. Reidel, Boston, MA, 1976).Google Scholar
3Thompson, A. H. and Di Salvo, F. J., Intercalation Chemistry, edited by Whittingham, M. S. and Jacobson, A. J. (Academic Press, New York, 1982), p. 573.CrossRefGoogle Scholar
4Divigalpitiya, W. M. R., Frindt, R. F., and Morrison, S. R., Science 246, 369 (1989).CrossRefGoogle Scholar
5Divigalpitiya, W. M. R., Morrison, S. R., and Frindt, R. F., Thin Solid Films 186, 177 (1990).CrossRefGoogle Scholar
6Divigalpitiya, W. M. R., Frindt, R. F., and Morrison, S. R., J. of Physics D: Applied Physics 23, 966 (1990).CrossRefGoogle Scholar
7Pauling, L., The Nature of the Chemical Bond (Cornell University Press, Ithaca, NY, 1948), pp. 187–193.Google Scholar
8Cullity, B. D., Elements of X-ray Diffraction (Addison-Wesley, New York, 1956).Google Scholar
9Lerf, A. and Schöllhorn, R., Inorg. Chem. 16, 2950 (1977).CrossRefGoogle Scholar
10The X-ray Identification and Crystal Structures of Clay Minerals, edited by Brown, G. (Mineralogical Society, London, 1961), pp. 169–175.Google Scholar
11Souder, S. and Brodie, D. E., Can. J. Phys. 49, 2565 (1971).CrossRefGoogle Scholar
12Thompson, A. H., Gamble, F. R., and Koehler, R. F., Jr., Phys. Rev. B 5, 2811 (1972).CrossRefGoogle Scholar