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Modeling study of effects of temperature profiling on CVI processing of woven graphite preforms with dimethyldichlorosilane
Published online by Cambridge University Press: 03 March 2011
Abstract
There is currently considerable interest in producing high temperature capability graphitic materials by first weaving graphite fiber tows (yarns) into a “preform” structure, followed by densification via cracking of precursor compounds such as dimethyldichlorosilane within the pores (macro and micro) at high temperature. The model described in this paper addresses this densification process, treating diffusion of gaseous species both within the macropores (spaces between the tows) and the micropores (spaces between individual fibers in the tows) and finite kinetics associated with the cracking of the precursor gas (treated parametrically). The resulting model is used to examine the effects of temperature distributions through cylindrical preforms on ultimate densification distribution. As might be expected (and as observed experimentally), uniform temperature through the preform leads to premature full densification of the pore structure at the periphery of the cylinder (blocking further densification in the interior), leading to severe porosity in the interior regions. Effects of externally imposed nonuniform temperature profiles (possibly via microwave heating) in alleviating this problem are examined, and it is shown that proper profiling can lead to nearly complete uniform densification throughout the preform.
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- Copyright © Materials Research Society 1994
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