Hostname: page-component-78c5997874-m6dg7 Total loading time: 0 Render date: 2024-11-06T11:57:09.722Z Has data issue: false hasContentIssue false
  • English
  • Français

Microstructure and mechanical properties of Ti/AlTiN/Ti-diamondlike carbon composite coatings on steel

Published online by Cambridge University Press:  31 January 2011

Xiaolu Pang ,
Huisheng Yang ,
Shijian Shi ,
Kewei Gao ,
Yanbin Wang  and
Alex A. Volinsky
Xiaolu Pang
Affiliation:
Department of Materials Physics and Chemistry, University of Science and Technology Beijing, Beijing 100083, China
Huisheng Yang*
Affiliation:
Department of Materials Physics and Chemistry, University of Science and Technology Beijing, Beijing 100083, China
Shijian Shi
Affiliation:
Department of Materials Physics and Chemistry, University of Science and Technology Beijing, Beijing 100083, China
Kewei Gao
Affiliation:
Department of Materials Physics and Chemistry, University of Science and Technology Beijing, Beijing 100083, China
Yanbin Wang
Affiliation:
Department of Materials Physics and Chemistry, University of Science and Technology Beijing, Beijing 100083, China
Alex A. Volinsky
Affiliation:
Department of Mechanical Engineering, University of South Florida, Tampa, Florida 33620
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

Ti/AlTiN/Ti-diamondlike carbon (DLC) composite coatings were deposited by mid-frequency magnetron sputtering and Hall ion source-assisted deposition on high-speed steel W18Cr4V substrates. The coating microstructure and mechanical properties, including hardness, elastic modulus, coefficient of friction, and wear properties were investigated by scanning electron microscopy, Raman spectroscopy, scratch and ball-on-disk friction tests, respectively. Fairly smooth composite coating with strong interfacial adhesion and good mechanical properties was produced. The substrate bias increases sp3 bonds contents in the DLC layer, thus coating hardness increased from 14 to 24 GPa and elastic modulus from 190 to 230 GPa with the increased substrate bias. Adhesion of interfaces between Ti-DLC and AlTiN layer, AlTiN and the steel substrate decreased with the substrate bias. The coefficient of friction is between 0.10 and 0.15, except when the substrate bias is 500 V, it is 0.2. Composite coating wear resistance increased with the substrate bias.

Keywords

AdhesionTribologyHardness
Type
Articles
Information
Journal of Materials Research , Volume 25 , Issue 11 , November 2010 , pp. 2159 - 2165
Copyright
Copyright © Materials Research Society 2010

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Weber, F-R., Fontaine, F., Scheib, M., Bock, W.: Cathodic arc evaporation of (Ti,Al)N coatings and (Ti,Al)N/TiN multilayer-coatings correlation between lifetime of coated cutting tools, structural and mechanical film properties. Surf. Coat. Technol. 177/178, 227 (2004)CrossRefGoogle Scholar
2.Dobrzański, L.A., Gołombek, K.: Structure and properties of the cutting tools made from cemented carbides and cermets with the TiN + mono-, gradient- or multi(Ti, Al, Si)N + TiN nanocrystalline coatings. J. Mater. Process. Technol. 164/165, 805 (2005)CrossRefGoogle Scholar
3.Fan, W.D., Chen, X., Jagannadham, K., Narayan, J.: Diamond-ceramic composite tool coatings. J. Mater. Res. 9, 2850 (1994)CrossRefGoogle Scholar
4.Li, X., Bhushan, B.: Development of a nanoscale fatigue measurement technique and its application to ultrathin amorphous carbon coatings. Scr. Mater. 47, 473 (2002)CrossRefGoogle Scholar
5.Takeno, T., Sugawara, T., Miki, H., Takagi, T.: Deposition of DLC film with adhesive W-DLC layer on stainless steel and its tribological properties. Diamond Relat. Mater. 18, 1023 (2009)CrossRefGoogle Scholar
6.Kano, M.: Super low friction of DLC applied to engine cam follower lubricated with ester-containing oil. Tribol. Int. 39, 1682 (2006)CrossRefGoogle Scholar
7.Noshiro, J., Watanabe, S., Sakura, T., Miyake, S.: Friction properties of co-sputtered sulfide/DLC solid lubricating films. Surf. Coat. Technol. 200, 5849 (2006)CrossRefGoogle Scholar
8.Konca, E., Cheng, Y.T., Alpas, A.T.: Dry sliding behaviour of non-hydrogenated DLC coatings against Al, Cu and Ti in ambient air and argon. Diamond Relat. Mater. 15, 939 (2006)CrossRefGoogle Scholar
9.Erdemir, A., Eryilmaz, O.L., Nilufer, I.B., Fenske, G.R.: Synthesis of superlow-friction carbon films from highly hydrogenated methane plasmas. Surf. Coat. Technol. 133/134, 448 (2000)CrossRefGoogle Scholar
10.Statuti, R.P.C.C., Radi, P.A., Santos, L.V., Trava-Airoldi, V.J.: A tribological study of the hybrid lubrication of DLC films with oil and water. Wear 267, 1208 (2009)CrossRefGoogle Scholar
11.Michler, T., Siebert, C.: Abrasive wear testing of DLC coatings deposited on plane and cylindrical parts. Surf. Coat. Technol. 163/164, 546 (2003)CrossRefGoogle Scholar
12.Pei, Y.T., Bui, X.L., Zhou, X.B., De Hosson, J.Th.M.: Tribological behavior of W-DLC coated rubber seals. Surf. Coat. Technol. 202, 1869 (2008)CrossRefGoogle Scholar
13.Harris, S.J., Weiner, A.M., Meng, W-J.: Tribology of metal-containing diamond-like carbon coatings. Wear 211, 208 (1997)CrossRefGoogle Scholar
14.Scharf, T.W., Ohlhausen, J.A., Tallant, D.R., Prasad, S.V.: Mechanisms of friction in diamondlike nanocomposite coatings. J. Appl. Phys. 101, 063521 (2007)CrossRefGoogle Scholar
15.Takadoum, J., Houmid Bennani, H., Allouard, M.: Friction and wear characteristics of TiN, TiCN and diamond-like carbon films. Surf. Coat. Technol. 88, 232 (1997)CrossRefGoogle Scholar
16.Kao, W.H., Su, Y.L., Yao, S.H.: Tribological property and drilling application of Ti–C:H and Cr–C:H coatings on high-speed steel substrates. Vacuum 80, 604 (2006)CrossRefGoogle Scholar
17.Bewilogua, K., Cooper, C.V., Specht, C., Schröder, J., Wittorf, R., Grischke, M.: Effect to target material on deposition and properties of metal-containing DLC (Me-DLC) coatings. Surf. Coat. Technol. 127, 224 (2000)CrossRefGoogle Scholar
18.Strondl, C., van der Kolk, G.J., Hurkmans, T., Fleischer, W., Trinh, T., Carvalho, N.M., de Hosson, J.Th.M.: Properties and characterization of multilayers of carbides and diamond-like carbon. Surf. Coat. Technol. 142/144, 707 (2001)CrossRefGoogle Scholar
19.Strondl, C., Carvalho, N.M., De Hosson, J.Th.M., van der Kolk, G.J.: Investigation on the formation of tungsten carbide in tungsten-containing diamond-like carbon coatings. Surf. Coat. Technol. 162, 288 (2003)CrossRefGoogle Scholar
20.Kao, W.H., Su, Y.L., Yao, S.H., Huang, H.C.: Optimizing the tribological properties and high-speed drilling performance of a-C:H coatings via nitrogen addition. Surf. Coat. Technol. 204, 1277 (2010)CrossRefGoogle Scholar
21.Arndt, M., Kacsich, T.: Performance of new AlTiN coatings in dry and high speed cutting. Surf. Coat. Technol. 163/164, 674 (2003)CrossRefGoogle Scholar
22.Pang, X., Gao, K., Volinsky, A.A.: Microstructure and mechanical properties of chromium oxide coatings. J. Mater. Res. 22, 3531 (2007)CrossRefGoogle Scholar
23.Kim, G.S., Lee, S.Y., Hahn, J.H., Lee, B.Y., Han, J.G., Lee, J.H., Lee, S.Y.: Effects of the thickness of Ti buffer layer on the mechanical properties of TiN coatings. Surf. Coat. Technol. 171, 83 (2003)CrossRefGoogle Scholar
24.Pang, X., Gao, K., Yang, H., Qiao, L., Wang, Y., Volinsky, A.A.: Interfacial microstructure of chromium oxide coatings. Adv. Eng. Mater. 9, 594 (2007)CrossRefGoogle Scholar
25.Carvalho, N.J.M., Zoestbergen, E., Kooi, B.J., De Hosson, J.Th.M.: Stress analysis and microstructure of PVD monolayer TiN and multilayerTiNy(Ti,Al)N coatings. Thin Solid Films 429, 179 (2003)CrossRefGoogle Scholar
26.Carvalho, N.J.M., De Hosson, J.Th.M.: Deformation mechanisms in TiN/(Ti,Al)N multilayers underdepth-sensing indentation. Acta Mater. 54, 1857 (2006)CrossRefGoogle Scholar
27.Landford, W.A., Rand, M.J.: The hydrogen content of plasma-deposited silicon nitride. J. Appl. Phys. 49, 2473 (1978)CrossRefGoogle Scholar
28.Casiraghi, C., Ferrari, A.C., Robertson, J.: Raman spectroscopy of hydrogenated amorphous carbons. Phys. Rev. B 72, 085401 (2005)CrossRefGoogle Scholar
29.Robertson, J.: Diamond-like amorphous carbon. Mater. Sci. Eng., R 37, 129 (2002)CrossRefGoogle Scholar
30.Jaoul, C., Jarry, O., Tristant, P., Merle-Méjean, T., Colas, M., Dublanche-Tixier, C., Jacquet, J.M.: Raman analysis of DLC coated engine components with complex shape: Understanding wear mechanisms. Thin Solid Films 518, 1475 (2009)CrossRefGoogle Scholar
31.Galvan, D., Pei, Y.T., De Hosson, J.Th.M.: Deformation and failure mechanism of nano-composite coatings under nano-indentation. Surf. Coat. Technol. 200, 6718 (2006)CrossRefGoogle Scholar
32.Leyland, A., Matthews, A.: Design criteria for wear-resistant nanostructured and glassy-metal coatings. Surf. Coat. Technol. 177/178, 317 (2004)CrossRefGoogle Scholar
33.Zoestbergen, E., Carvalho, N.J.M., De Hosson, J.Th.M.: Stress state of TiN/TiAlN PVD multilayers. Surf. Eng. 17, 29 (2001)CrossRefGoogle Scholar