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Microcolumn development on titanium by multipulse laser irradiation in nitrogen

Published online by Cambridge University Press:  31 January 2011

E. György ,
A. Pérez del Pino ,
P. Serra  and
J. L. Morenza
E. György
Affiliation:
Universitat de Barcelona, Departament de Física Aplicada i Òptica, Avda. Diagonal 647, E-08028 Barcelona, Spain
A. Pérez del Pino
Affiliation:
Universitat de Barcelona, Departament de Física Aplicada i Òptica, Avda. Diagonal 647, E-08028 Barcelona, Spain
P. Serra
Affiliation:
Universitat de Barcelona, Departament de Física Aplicada i Òptica, Avda. Diagonal 647, E-08028 Barcelona, Spain
J. L. Morenza*
Affiliation:
Universitat de Barcelona, Departament de Física Aplicada i Òptica, Avda. Diagonal 647, E-08028 Barcelona, Spain
*
b) Address all correspondence to this author. e-mail: [email protected]
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Abstract

We report the growth of titanium nitride microcolumns under multipulse Nd:yttrium aluminum garnet (λ = 1.064 μm, τ ∼ 300 ns, ν = 30 kHz) laser irradiation of titanium targets in nitrogen atmosphere. The laser intensity value was chosen below the single-pulse melting threshold of titanium. The evolution with the number of laser pulses of the target morphology, crystalline state, and chemical composition at the surface as well as in depth were investigated by scanning electron microscopy, x-ray diffractometry, Raman spectroscopy, and wavelength dispersive x-ray spectroscopy. Under the action of the laser pulses, during progressive surface nitridation, an initial rippled morphology developed, which evolved with further irradiation to TiN microcolumns. In-depth investigations showed a granular zone beneath the surface consisting of rutile and anatase phase TiO2, followed by a compact needlelike layer of titanium until the interface with the unaffected target material.

Type
Articles
Information
Journal of Materials Research , Volume 18 , Issue 9 , September 2003 , pp. 2228 - 2234
Copyright
Copyright © Materials Research Society 2003

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References

REFERENCES

1.Titanium in Medicine, edited by Brunette, D.M., Tengvall, P., Textor, M., and Thomsen, P. (Springer-Verlag, Berlin, Germany, 2001).CrossRefGoogle Scholar
2.Prokhorov, A.M., Ursu, I., Mihailescu, I.N., and Konov, V.I., Laser Heating of Metals (Adam Hilger, Bristol, U.K., 1990)Google Scholar
3.Bauerle, D., Laser Processing and Chemistry (Springer-Verlag, Berlin, Germany, 2000)CrossRefGoogle Scholar
4.Gyorgy, E., Perez, A. del Pino, Serra, P., and Morenza, J.L., Appl. Surf. Sci. 186, 130 (2002)CrossRefGoogle Scholar
5.Gyorgy, E., Perez, A. del Pino, Serra, P., and Morenza, J.L., Surf. Coat. Technol. 173, 265 (2003).CrossRefGoogle Scholar
6.Gyorgy, E., Mihailescu, I.N., Serra, P., Perez, A. del Pino, and Morenza, J.L., Surf. Coat. Technol. 154, 63 (2002).CrossRefGoogle Scholar
7.Gyorgy, E., Mihailescu, I.N., Serra, P., Perez, A. del Pino, and Morenza, J.L., Appl. Phys. A: Mater. Sci. Process. 74, 755 (2002).Google Scholar
8.Gyorgy, E., Pino, A. Perez del, Serra, P., and Morenza, J.L., Appl. Phys. A: Mater. Sci. Process. (in press).Google Scholar
9.Gyorgy, E., Perez, A. del Pino, Serra, P., and Morenza, J.L., Appl. Surf. Sci. 197–198, 851 (2002).CrossRefGoogle Scholar
10.Dolgaev, S.I., Lavrishev, S.V., Lyalin, A.A., Simakin, A.V., Votonov, V.V., and Shafeev, G.A., Appl. Phys. A: Mater. Sci. Process. 73, 177 (2001).CrossRefGoogle Scholar
11.Sanchez, F., Morenza, J.L., and Trtik, V., Appl. Phys. Lett. 75, 3303 (1999).CrossRefGoogle Scholar
12.Pedraza, A.J., Fowlkes, J.D., and Lowndes, D.H., Appl. Phys. Lett. 74, 2322 (1999).CrossRefGoogle Scholar
13.Mendes, M., Oliveira, V., Vilar, R., Beinhorn, F., Ihleman, J., and Conde, O., Appl. Surf. Sci. 154–155, 29 (2000).CrossRefGoogle Scholar
14.Nakamoto, M. and Fukuda, K., Appl. Surf. Sci. 202, 289 (2002).CrossRefGoogle Scholar
15.Powder Diffraction File Nos. 38–1420, 44–1095, 05–0682 (JCPDS International Centre for Diffraction Data, Swarthmore, PA, 1988).Google Scholar
16.Spengler, W., Kaiser, R., Christensen, A.N., and Muller-Vogt, G., Phys. Rev. B 17, 1095 (1978).CrossRefGoogle Scholar
17.Cheng, Y.H., Tay, B.K., Lau, S.P., Kupfer, H., and Richter, F., J. Appl. Phys. 92, 1845 (2002).CrossRefGoogle Scholar
18.Parker, J.C. and Siegel, R.W., Appl. Phys. Lett. 57, 943 (1990).CrossRefGoogle Scholar
19.Thorwarth, G., Mandl, S., and Rauschenbach, B., Surf. Coat. Technol. 136, 236 (2001).CrossRefGoogle Scholar
20.Moret, M.P., Zallen, R., Vijay, D.P., and Desu, S.B., Thin Solid Films 366, 8 (2000).CrossRefGoogle Scholar
21.Gamaly, E.G., Rode, A.V., and Luther-Davies, B., J. Appl. Phys. 85, 4213 (1999).CrossRefGoogle Scholar
22.Kelly, R. and Rothenberg, J., Nucl. Instrum. Methods B 7/8, 755 (1985).CrossRefGoogle Scholar
23.Tabuchi, S., Tabata, H., and Kawai, T., Jpn. J. Appl. Phys. 39, 1268 (2000).CrossRefGoogle Scholar
24.Nwobu, A.I., Rawlings, R.D., and West, D.R.F., Acta Mater. 47, 631 (1999).CrossRefGoogle Scholar
25.Kloosterman, A.B. and Hosson, J.Th.M. De, Scripta Metal. Mater. 33, 567 (1995).CrossRefGoogle Scholar
26.Brailovsky, A.B., Dorofeev, I.A., Ezersky, A.B., Ermakov, V.A., Luchin, V.I., and Semenov, V.E., Sov. Phys. Tech. Phys. 36, 324 (1991).Google Scholar
27.Duley, W.W., UV Lasers: Effects and Applications in Materials Science (Cambridge University Press, Cambridge, U.K., 1996).CrossRefGoogle Scholar
28.Brailovsky, A.B., Gaponov, S.V., and Luchin, V.I., Appl. Phys. A: Mater. Sci. Process. 61, 81 (1995).CrossRefGoogle Scholar
29.Willmott, P.R. and Huber, J.R., Rev. Mod. Phys. 72, 315 (2000).CrossRefGoogle Scholar
30.Jesse, S., Pedraza, A.J., Fowlkes, J.D., and Budai, J.D., J. Mater. Res. 17, 1002 (2002).CrossRefGoogle Scholar
31.Kononenko, T.V., Garnov, S.V., Pimenov, S.M., Konov, V.I., Romano, V., Borsos, B., and Weber, H.P., Appl. Phys. A: Mater. Sci. Process. 71, 627 (2000).CrossRefGoogle Scholar
32.Xin, H., Hu, C., and Baker, T.N., J. Mater. Sci. 35, 3373 (2000).CrossRefGoogle Scholar
33.Teodorescu, V.S., Mihailescu, I.N., Gyorgy, E., Luches, A., Martino, M., Nistor, L.C., Van, J. Landuyt, and Hermann, J., J. Mod. Opt. 43, 1773 (1996).CrossRefGoogle Scholar
34.Ursu, I., Mihailescu, I.N., Gutu, I., Hening, A., Julea, T., Nistor, L.C., Popescu, M., Teodorescu, V.S., Prokhorov, A.M., Konov, V.I., and Ralchenko, V.G., Appl. Opt. 25, 2720 (1986).CrossRefGoogle Scholar
35.Maksimovich, G.G., Federko, V.N., and Pogrelyuk, I.N., in Soviet Materials Science, edited by Panasyuk, V.V. (Plenum Press, New York, 1992), p. 135.Google Scholar
36.Handbook of Chemistry and Physics, edited by Lide, D.R. (CRC Press, Boca Raton, FL, 2001).Google Scholar