Hostname: page-component-586b7cd67f-rdxmf Total loading time: 0 Render date: 2024-11-27T05:33:38.088Z Has data issue: false hasContentIssue false
  • English
  • Français

Metal coatings on semiconductor particles in glass

Published online by Cambridge University Press:  03 March 2011

Vijay Sukumar ,
Shou-Chen Kao ,
Pratima G.N. Rao  and
Robert H. Doremus
Vijay Sukumar
Affiliation:
Materials Engineering Department, Rensselaer Polytechnic Institute, Troy, New York 12180-3590
Shou-Chen Kao
Affiliation:
Materials Engineering Department, Rensselaer Polytechnic Institute, Troy, New York 12180-3590
Pratima G.N. Rao
Affiliation:
Materials Engineering Department, Rensselaer Polytechnic Institute, Troy, New York 12180-3590
Robert H. Doremus
Affiliation:
Materials Engineering Department, Rensselaer Polytechnic Institute, Troy, New York 12180-3590
Get access

Abstract

Glasses containing semiconductor particles coated with metal were synthesized and studied. Glasses containing CdS and silver were heated to grow the CdS particles first, followed by the growth of metal on them. The solubility of silver in the CdS glass was increased by changing the base glass composition. Optical absorption and transmission electron microscopy results showed that silver coated the CdS particles in these glasses. The CdS particles had to be a critical size before silver grew on them. This critical size was calculated from nucleation theory and was found to be in good agreement with the experimental results. Glasses containing CuCl particles were partially reduced in hydrogen to obtain copper-coated CuCl particles. Absorption spectroscopy and TEM indicated a copper coating on the particles.

Type
Articles
Information
Journal of Materials Research , Volume 8 , Issue 10 , October 1993 , pp. 2686 - 2693
Copyright
Copyright © Materials Research Society 1993

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1Rowell, J. M., Sci. Am. 255 (4), 147 (1986).Google Scholar
2Jain, R. K. and Lind, R. C., J. Opt. Soc. Am. 73, 647 (1983).Google Scholar
3Ekimov, A. I. and Efros, A. L., Phys. Status Solidi B 150, 627 (1988).Google Scholar
4Warnock, J. and Awschalom, D. D., Phys. Rev. B 32 (8), 5529 (1985).Google Scholar
5Remillard, J. T. and Steel, D. G., Opt. Lett. 13 (1), 30 (1988).Google Scholar
6Luong, J. C., Superlattices Microstruct. 4 (3), 385 (1988).Google Scholar
7Ricard, D., Hache, F., Roussignol, P., and Flytzanis, C., J. Phys. Colloq. C 2, 221 (1988).Google Scholar
8Li, Y. Q., Sung, C. C., Inguva, R., and Bowden, C. M., J. Opt. Soc. Am. B 6 (4), 814 (1989).Google Scholar
9Persans, P. D., Tu, A., Wu, Y. J., and Lewis, M., J. Opt. Soc. Am. B 6 (4), 818 (1989).CrossRefGoogle Scholar
10Williams, V. S., Olbright, G. R., Fluegel, B. D., Koch, S. W., and Peyghambarian, N., J. Mod. Opt. 35 (12), 1979 (1987).Google Scholar
11Borrelli, N. F., Hall, D. W., Holland, H. J., and Smith, D. W., J. Appl. Phys. 61 (12), 5399 (1987).Google Scholar
12Liu, L. C. and Risbud, S. H., J. Appl. Phys. 68 (1), 28 (1990).Google Scholar
13Neeves, A. E. and Birnboim, M. H., J. Opt. Soc. Am. B 6 (4), 787 (1989).Google Scholar
14Birnboim, M. H. and Ma, W. P., in Materials Issues in Microcrystalline Semiconductors, edited by Fauchet, P. M., Tanaka, R., and Tsai, C. C. (Mater. Res. Soc. Symp. Proc. 164, Pittsburgh, PA, 1990), p. 277.Google Scholar
15Haus, J. W., Kalyaniwalla, N., Inguva, R., and Bowden, C. M., J. Appl. Phys. 65 (4), 1420 (1989).Google Scholar
16Haus, J. W., Kalyaniwalla, N., Inguva, R., Bloemer, M., and Bowden, C. M., J. Opt. Soc. Am. B 6 (4), 797 (1989).Google Scholar
17Ricard, D., Roussignol, P., and Flytzanis, C., Opt. Lett. 10, 511 (1985).Google Scholar
18Sukumar, V., “Metal Coatings on Semiconductor Particles in Glass for Possible Enhanced Nonlinear Optical Properties,” Ph.D. Thesis, Rensselaer Polytechnic Institute (1992).Google Scholar
19Nasu, H., Kaneko, S., Tsunetomo, K., and Kamiya, K., J. Cer. Soc. Jpn. 99 (4), 266 (1990).Google Scholar
20Doremus, R. H., J. Chem. Phys. 42, 414 (1965).Google Scholar
21Doremus, R. H., in Symposium on Nucleation and Crystallization in Glasses and Melts (The American Ceramic Society, Westerville, OH, 1962), p. 119.Google Scholar
22Weyl, W. A., Coloured Glasses (Dawson's of Pall Mall, London, 1959).Google Scholar
23Aden, A. L. and Kerker, M. L., J. Appl. Phys. 22, 1242 (1951).Google Scholar
24Guttler, A., Ann. Phys. 11, 65 (1952).CrossRefGoogle Scholar
25Samara, G. A., Phys. Rev. B 27 (6), 3494 (1983).Google Scholar
26Otter, W., Z. Phys. 161 (2), 163 (1961).Google Scholar
27Doremus, R. H. (unpublished research).Google Scholar
28Haus, J. W., Zhou, H. S., Takami, S., Hirasawa, M., Homma, I., and Komiyama, H., J. Appl. Phys. (in press).Google Scholar
29Sundquist, B. E., Acta Metall. 12, 588 (1964).Google Scholar
30Doremus, R. H., Rates of Phase Transformations (Academic Press, New York, 1985), p. 63.Google Scholar
31Maurer, R. D., J. Chem. Phys. 31, 444 (1959).Google Scholar
32Doremus, R. H., Kao, S. C., and Garcia, R., Appl. Opt. 31 (27), 5773 (1992).Google Scholar
33Feldman, A. and Horowitz, D., J. Opt. Soc. Am. 59, 1406 (1969).Google Scholar