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Mechanisms of the electron irradiation-induced amorphous transition in intermetallic compounds

Published online by Cambridge University Press:  31 January 2011

D.F. Pedraza
D.F. Pedraza
Affiliation:
Metals and Ceramics Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831
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Abstract

A buildup of radiation-induced lattice defects is proposed as the cause for lattice instability that can give rise to a crystalline-to-amorphous transition. An analysis of published experiments on intermetallic compounds suggests that, when amorphization takes place, no microstructural evolution based on the aggregation of like-point defects occurs. This observation leads us to suggest that buildup of a different type of defect, which will destabilize the crystal, should occur. We thus propose that an interstitial and a vacancy may form a complex, giving rise to a relaxed configuration exhibiting a sort of short-range order. Two mechanisms of complex formation are analyzed, one diffusionless (limited by the point defect production rate) and the other temperature dependent. The amorphization kinetics as a function of temperature, dose, and point defect sink strength are studied. Theoretical predictions on the amorphization dose as a function of temperature are made for the equiatomic TiNi alloy and compared with available experimental results.

Type
Articles
Information
Journal of Materials Research , Volume 1 , Issue 3 , June 1986 , pp. 425 - 441
Copyright
Copyright © Materials Research Society 1986

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References

REFERENCES

1Pietrokowski, P., Rev. Sci. Instrum. 34, 455 (1963).Google Scholar
2Harbur, D. R., Anderson, J. W., and Maraman, W. G., Trans. TMS-AIME 245, 1055 (1969).Google Scholar
3Thomas, G., Mori, H., Fujita, H., and Sinclair, R., Scr. Metal. 16, 589 (1982).Google Scholar
4Mori, H. and Fujita, H., Jpn. J. Appl. Phys. 21, L494 (1982).Google Scholar
5Mori, H., Fujita, H., and Fujita, M., Jpn. J. Appl. Phys. 22, L94 (1983).Google Scholar
6Pelton, A. R., Proceedings of the Seventh International Conference on High Voltage Electron Microscopy, LBL-16031, UC-25, CONF-830819 (Lawrence Berkeley Laboratory, Berkeley, CA, 1983), p. 245.Google Scholar
7Mori, H., Fujita, H., Tendo, M., and Fujita, M., Scr. Metal. 18, 783 (1984).Google Scholar
8Luzzi, D. E., Mori, H., and Fujita, H., Scr. Metal. 18, 957 (1984).Google Scholar
9Carpenter, G. J. C. and Schulson, E. M., J. Nucl. Mater. 23, 180 (1978).Google Scholar
10Howe, L. M. and Rainville, M. H., J. Nucl. Mater. 68, 215 (1977).Google Scholar
11Howe, L. M. and Rainville, M. H., Radiat. Eff. 48, 151 (1980).Google Scholar
12Rechtin, M. D., Sande, J. Vander, and Baldo, P. M., Scr. Metal. 12, 639 (1977).Google Scholar
13Elliot, R. O., Koss, D. A., and Giessen, C. B., Scr. Metal. 14, 1061 (1980).Google Scholar
14Brimhall, J. L., Kissinger, H. E., and Chariot, L. A., Metastable Materials Formation by Ion Implantation, edited by Picraux, S. T. and Choyke, W. J. (North-Holland, New York, 1982), p. 235.Google Scholar
15Brimhall, J. L., Kissinger, H. E., and Chariot, L. A., Radiat. Eff. 77, 273 (1983).Google Scholar
16Brimhall, J. L., Kissinger, H. E., and Pelton, A. R., Ion Implantation and Ion Beam Processing of Materials, edited by Hubler, G. K., Holland, O. W., Clayton, C. R., and White, C. W. (North-Holland, New York, 1984), p. 163.Google Scholar
17Moine, P., Riviere, J. P., Junqua, N., and Delafond, J., in Ref. 12, p. 243.Google Scholar
18Moine, P., Eymery, J. P., Gaboriaud, R. J., and Delafond, J., Nucl. Instrum. Methods 209/210, 267 (1983).Google Scholar
19Moine, P., Riviere, J. P., Rouault, M. O., Chaumont, J., Pelton, A., and Sinclair, R., Nucl. Instrum. Methods B 7/8, 20 (1985).Google Scholar
20Woo, O. T., J. Nucl. Mater. 125, 120 (1984).Google Scholar
21Brimhall, J. L., Chariot, L. A., and Wang, R., Scr. Metal. 13, 217 (1979).Google Scholar
22Grant, W. A., J. Vac. Sci. Technol. 15, 1644 (1978).Google Scholar
23Wollenberger, H. J., Physical Metallurgy, edited by Cahn, R. W. and Haasen, P. (Elsevier, New York, 1983), 3rd ed., Chap. 17, p. 1140.Google Scholar
24Halbwachs, M. and Hillairet, J., Phys. Rev. B 18, 4927 (1978).Google Scholar
25Halbwachs, M., Stanley, J. T., and Hillairet, J., Phys. Rev. B 18, 4938 (1978).Google Scholar
26Dimitrov, C., Belo, M. Da Cunha, and Dimitrqv, O., in the Proceedings of the Yamada Conference, edited by Takamura, J. I., Doyama, M., and Kiritani, M. (University of Tokyo, Tokyo, 1982), p. 660.Google Scholar
27Riviere, J. P., Rouault, M. O., Schack, M., and Chaumont, J., Radiat. Eff, 79, 275 (1983).CrossRefGoogle Scholar
28Swanson, M. L., Parson, J. R., and Hoelke, C. W., Radiat. Eff. 9, 249 (1971).Google Scholar
29Ansara, I., Pasturel, A., and Buschow, K. H. J., Phys. Status Solidi (A) 69, 447 (1982).CrossRefGoogle Scholar
30Henaff, M. R., Colinet, C., Pasturel, A., and Buschow, K. H. J., J. Appl. Phys. 56, 307 (1984).CrossRefGoogle Scholar
31Marshall, A. F., Lee, Y. S., and Stevenson, D . A., Acta Metall. 31, 1225 (1984).Google Scholar
32Sadocand, J. F.Wagner, C. N. J., Glossy Metals II, Topics in Applied Physics, edited by Beck, H. and Guntherodt, H. J. (Springer, Berlin, 1983), Vol. 53, p. 51.Google Scholar
33Pedraza, D. Fainstein, Savino, E. J., and Pedraza, A. J., J. Nucl. Mater. 73, 151 (1978).Google Scholar
34Mansur, L. K., Nucl. Technol. 40, 5 (1978).Google Scholar
35Mukoi, T., Kinoshita, C., and Kitajuina, S., Philos. Mag. A 47, 255 (1983).Google Scholar
36Adda, Y. and Phillibert, J., La Diffusion dans les Solides (Presses Universitaires de France, Paris, 1966), Tome I.Google Scholar
37Pedraza, D. F. and Mansur, L. K., “The Effect of Point Defects on the Amorphization of Metallic Alloys During Ion Implantation,” in the Proceedings of the Symposium on Irradiation Effects Associated with Ion Implantation, Toronto, Ontario, Canada, October 1985 (to be published).Google Scholar
38Luzzi, D. E., Mori, H., Fujita, H., and Meshii, M., Scr. Metal. 19, 897 (1985).CrossRefGoogle Scholar