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Manganese-doped MnSe/CdSe core/shell nanocrystals: Preparation, characterization, and study of growth mechanism

Published online by Cambridge University Press:  21 September 2011

Kangwei Zhu
Affiliation:
Key Laboratory for Magnetism and Magnetic Materials of Ministry of Education, Lanzhou University, Lanzhou 730000, People’s Republic of China; and School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, People’s Republic of China
Xin Zhang*
Affiliation:
Key Laboratory for Magnetism and Magnetic Materials of Ministry of Education, Lanzhou University, Lanzhou 730000, People’s Republic of China; and School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, People’s Republic of China
Lei Wang
Affiliation:
Key Laboratory for Magnetism and Magnetic Materials of Ministry of Education, Lanzhou University, Lanzhou 730000, People’s Republic of China; and School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, People’s Republic of China
Haibin Zhang
Affiliation:
Key Laboratory for Magnetism and Magnetic Materials of Ministry of Education, Lanzhou University, Lanzhou 730000, People’s Republic of China; and School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, People’s Republic of China
Jumeng Wei
Affiliation:
Key Laboratory for Magnetism and Magnetic Materials of Ministry of Education, Lanzhou University, Lanzhou 730000, People’s Republic of China; and School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, People’s Republic of China
Long Wang
Affiliation:
Key Laboratory for Magnetism and Magnetic Materials of Ministry of Education, Lanzhou University, Lanzhou 730000, People’s Republic of China; and School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, People’s Republic of China
Min Zhou
Affiliation:
Key Laboratory for Magnetism and Magnetic Materials of Ministry of Education, Lanzhou University, Lanzhou 730000, People’s Republic of China; and School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, People’s Republic of China
Boxue Feng
Affiliation:
Key Laboratory for Magnetism and Magnetic Materials of Ministry of Education, Lanzhou University, Lanzhou 730000, People’s Republic of China; and School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, People’s Republic of China
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

Nucleation doping strategy is an effective doping method; herein the synthesis of MnSe/CdSe nanocrystals using this strategy with different anion precursors was demonstrated. The resulted nanocrystals were characterized by various test technology to confirm the composition and structure. Wurtzite CdSe shell was achieved without using alkylphosphine, this is meaningful for the development of green chemistry. It is argued that the shell growth is more like a second nucleation process, rather than the epitaxial growth; this conclusion is believed to shed some light on the nucleation doping process.

Type
Articles
Copyright
Copyright © Materials Research Society 2011

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References

REFERENCES

1.Erwin, S.C., Zu, L.J., Haftel, M.I., Efros, A.L., Kennedy, T.A., and Norris, D.J.: Doping semiconductor nanocrystals. Nature 436, 91 (2005).CrossRefGoogle ScholarPubMed
2.Yu, J.H., Liu, X.Y., Kweon, K.E., Joo, J., Park, J., Ko, K.T., Lee, D., Shen, S.P., Tivakornsasithorn, K., Son, J.S., Park, J.H., Kim, Y.W., Hwang, G.S., Dobrowolska, M., Furdyna, J.K., and Hyeon, T.: Giant Zeeman splitting in nucleation-controlled doped CdSe:Mn2+ quantum nanoribbons. Nat. Mater. 9, 47 (2010).CrossRefGoogle ScholarPubMed
3.Beaulac, R., Archer, P.I., Ochsenbein, S.T., and Gamelin, D.R.: Mn2+-doped CdSe quantum dots: New inorganic materials for spin-electronics and spin-photonics. Adv. Funct. Mater. 18, 3873 (2008).CrossRefGoogle Scholar
4.Bruchez, M., Moronne, M., Gin, P., Weiss, S., and Alivisatos, A.P.: Semiconductor nanocrystals as fluorescent biological labels. Science 281, 2013 (1998).CrossRefGoogle ScholarPubMed
5.Htoon, H., Hollingworth, J.A., Malko, A.V., Dickerson, R., and Klimov, V.I.: Light amplification in semiconductor nanocrystals: Quantum rods versus quantum dots. Appl. Phys. Lett. 82, 4776 (2003).CrossRefGoogle Scholar
6.Kim, J.U., Lee, M.H., and Yang, H.: Synthesis of Zn1-xCdxS:Mn/ZnS quantum dots and their application to light-emitting diodes. Nanotechnology 19, 465605 (2008).Google Scholar
7.Efros, A.L., Rashba, E.I., and Rosen, M.: Paramagnetic ion-doped nanocrystal as a voltage-controlled spin filter. Phys. Rev. Lett. 87, 206601 (2001).CrossRefGoogle ScholarPubMed
8.Beaulac, R., Archer, P.I., and Gamelin, D.R.: Luminescence in colloidal Mn2+-doped semiconductor nanocrystals. J. Solid State Chem. 181, 1582 (2008).CrossRefGoogle Scholar
9.Zuo, T., Sun, Z., Zhao, Y., Jiang, X., and Gao, X.: The big red shift of photoluminescence of Mn dopants in strained CdS: A case study of Mn-doped MnS−CdS heteronanostructures. J. Am. Chem. Soc. 132, 6618 (2010).Google Scholar
10.Pradhan, N. and Peng, X.G.: Efficient and color-tunable Mn-doped ZnSe nanocrystal emitters: Control of optical performance via greener synthetic chemistry. J. Am. Chem. Soc. 129, 3339 (2007).CrossRefGoogle ScholarPubMed
11.Zheng, J.J., Yuan, X., Ikezawa, M., Jing, P.T., Liu, X.Y., Zheng, Z.H., Kong, X.G., Zhao, J.L., and Masumoto, Y.: Efficient photoluminescence of Mn2+ ions in MnS/ZnS core/shell quantum dots. J. Phys. Chem. C 113, 16969 (2009).CrossRefGoogle Scholar
12.Zeng, R., Rutherford, M., Xie, R., Zou, B., and Peng, X.: Synthesis of highly emissive Mn-doped ZnSe nanocrystals without pyrophoric reagents. Chem. Mater. 22, 2107 (2010).Google Scholar
13.Al-Salim, N., Young, A.G., Tilley, R.D., McQuillan, A.J., and Xia, J.: Synthesis of CdSeS nanocrystals in coordinating and noncoordinating solvents: Solvent’s role in evolution of the optical and structural properties. Chem. Mater. 19, 5185 (2007).Google Scholar
14.Murray, C.B., Noms, D.J., and Bawendi, M.G.: Synthesis and characterization of nearly monodisperse CdE(E = S, Se, Te) semiconductor nanocrystallites. J. Am. Chem. Soc. 115, 8706 (1993).Google Scholar
15.Jasieniak, J., Bullen, C., van Embden, J., and Mulvaney, P.: Phosphine-free synthesis of CdSe nanocrystals. J. Phys. Chem. B 109, 20665 (2005).Google Scholar
16.Bullen, C., van Embden, J., Jasieniak, J., Cosgriff, J.E., Mulder, R.J., Rizzardo, E., Gu, M., and Raston, C.L.: High activity phosphine-free selenium precursor solution for semiconductor nanocrystal growth. Chem. Mater. 22, 4135 (2010).Google Scholar
17.Pradhan, N., Goorskey, D., Thessing, J., and Peng, X.G.: An alternative of CdSe nanocrystal emitters: Pure and tunable impurity emissions in ZnSe nanocrystals. J. Am. Chem. Soc. 127, 17586 (2005).CrossRefGoogle ScholarPubMed
18.Qin, T., Lu, J., Wei, S., Qi, P., Peng, Y., Yang, Z., and Qian, Y.: [alpha]-MnSe crystallites through solvothermal reaction in ethylenediamine. Inorg. Chem. Commun. 5, 369 (2002).Google Scholar
19.Sines, I.T., Misra, R., Schiffer, P., and Schaak, R.E.: Colloidal synthesis of non-equilibrium wurtzite-type MnSe. Angew. Chem. Int. Ed. 49, 4638 (2010).CrossRefGoogle ScholarPubMed
20.Heimbrodt, W., Goede, O., Tschentscher, I., Weinhold, V., Klimakow, A., Pohl, U., Jacobs, K., and Hoffmann, N.: Optical study of octahedrally and tetrahedrally coordinated MnSe. Physica B 185, 357 (1993).CrossRefGoogle Scholar
21.Kwak, W.C., Sung, Y.M., Kim, T.G., and Chae, W.S.: Synthesis of Mn-doped zinc blende CdSe nanocrystals. Appl. Phys. Lett. 90, 173111 (2007).Google Scholar
22.Bryan, J.D. and Gamelin, D.R.: Doped semiconductor nanocrystals: Synthesis, characterization, physical properties, and applications. Prog. Inorg. Chem. 54, 47 (2005).Google Scholar
23.Yu, W.W., Qu, L.H., Guo, W.Z., and Peng, X.G.: Experimental determination of the extinction coefficient of CdTe, CdSe, and CdS nanocrystals. Chem. Mater. 15, 2854 (2003).Google Scholar
24.Mahler, B., Lequeux, N., and Dubertret, B.: Ligand-controlled polytypism of thick-shell CdSe/CdS nanocrystals. J. Am. Chem. Soc. 132, 953 (2010).CrossRefGoogle ScholarPubMed