Hostname: page-component-586b7cd67f-2plfb Total loading time: 0 Render date: 2024-11-27T03:37:28.187Z Has data issue: false hasContentIssue false

Major phase transformations and magnetic property changes caused by electromagnetic fields at microwave frequencies

Published online by Cambridge University Press:  31 January 2011

Rustum Roy*
Affiliation:
Materials Research Institute, The Pennsylvania State University, University Park, Pennsylvania 16802
Ramesh Peelamedu
Affiliation:
Materials Research Institute, The Pennsylvania State University, University Park, Pennsylvania 16802
Craig Grimes
Affiliation:
Materials Research Institute, The Pennsylvania State University, University Park, Pennsylvania 16802
Jiping Cheng
Affiliation:
Materials Research Institute, The Pennsylvania State University, University Park, Pennsylvania 16802
Dinesh Agrawal
Affiliation:
Materials Research Institute, The Pennsylvania State University, University Park, Pennsylvania 16802
*
a)Address all correspondence to this author.102A Materials Research Laboratory, The Pennsylvania State University, University Park, Pennsylvania 16802.[email protected]
Get access

Abstract

We demonstrate in this paper that common crystalline phases can be made noncrystalline and hard magnets can be converted to soft magnets in the solid state in several seconds at temperatures far below the melting points. New crystal structures and magnetic structures of ferromagnetic oxides (ferrites such as BaFe12O19, CoFe2O4, Fe3O4, and ZnFe2O4, etc.) are formed by reacting either the stoichiometric mixture of oxides or the preformed phase-pure crystalline material in a pure H field (or E field) at microwave (2.45 GHz) frequencies. These major changes in the magnetic properties as well as major structural phase changes are caused by the magnetic field.

Type
Rapid Communications
Copyright
Copyright © Materials Research Society 2002

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1.Sutton, W.H., Am. Ceram. Soc. Bull. 68, 376 (1989).Google Scholar
2.Roy, R., Komarneni, S., and Yang, L.J., J. Am. Ceram. Soc. 68, 392 (1985).CrossRefGoogle Scholar
3.Roy, R., “New First Principles of Microwave-Material Interaction. Discovering the Role of the H Field and Anisothermal Reactions,” presented at the Second International Congress Microwave and RF Heating (Orlando, FL, April 2000).Google Scholar
4.Cheng, J., Roy, R., and Agrawal, D.. J. Mater. Sci. Lett. 20, 1561 (2001).CrossRefGoogle Scholar
5.Cheng, J., Roy, R., and Agrawal, D., U.S. Patent No. 6 365885 (2 April 2002).Google Scholar
6.Miskovsky, N. and Cutler, P. (private communication, 2001).Google Scholar
7.Kimura, T., Takizawa, K., Uheda, K., Endo, T., and Shimada, M., J. Am. Ceram. Soc. 81, 2961 (1998).CrossRefGoogle Scholar
8.Endo, T., “Synthesis of Inorganic Materials by 28 GHz MW Radiation,” in Proc. Symp. on MW Effects and Application(Kokushikau Univ. of Tokyo, 2001).Google Scholar
9.Roy, R., Peelamedu, R.D., Hurtt, L., Cheng, J.P., and Agrawal, D.K., Mater. Res. Innov. 6, 128 (2002).CrossRefGoogle Scholar
10.Kreisel, J., Lucazeau, G., and Vincent, H., J. Solid State Chem. 137, 127 (1998).CrossRefGoogle Scholar
11.Kreisel, J., Pignard, S., Vincent, H., and Senateur, J.P., and Lucazeau, G., Appl. Phys. Lett. 73, 1194 (1998).CrossRefGoogle Scholar
12.Chen, M.S., Shen, Z.X., Liu, X.Y., and Wang, J., J. Mater. Res. 15, 483 (2000).CrossRefGoogle Scholar
13.Grimes, C.A., IEEE Trans. Magn. 27, 4310 (1991).CrossRefGoogle Scholar
14.Grimes, C.A., J. Appl. Phys. 80, 4548 (1996).CrossRefGoogle Scholar