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Luminescence of SrY2O4:Eu3+ associated with defects

Published online by Cambridge University Press:  31 January 2011

Jia Zhang  and
Yuhua Wang
Jia Zhang
Affiliation:
Department of Material Science, School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, People's Republic of China
Yuhua Wang*
Affiliation:
Department of Material Science, School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, People's Republic of China
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

SrY2O4:Eu3+ phosphors were synthesized by both the solid-state reaction method and the sol-gel method, and their photoluminescence in vacuum ultraviolet (VUV) and the ultraviolet (UV) region were evaluated. The excitation spectra of SrY2O4:Eu3+ phosphors prepared by solid-state reaction show another excitation band centered at 324 nm except for the charge-transfer bands (CTB) of Eu3+ when monitored at 610 nm, and a blue emission band around 406 nm is observed when excited at 324 nm, which could be associated with defects. Both the excitation and emission bands mentioned above disappear when the samples were prepared by the sol-gel method. SrY1.98O4:0.02Eu3+ phosphors synthesized by the sol-gel method exhibit a higher emission intensity under 147 nm excitation compared with solid-state reaction technology. The main reason could be that the samples prepared by the solution-based route have more regular and uniform morphologies.

Keywords

LuminescenceDefectsEu
Type
Articles
Information
Journal of Materials Research , Volume 25 , Issue 11 , November 2010 , pp. 2120 - 2124
Copyright
Copyright © Materials Research Society 2010

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References

REFERENCES

1.Im, W.B., Yoo, H.S., Vaidyanathan, S., Kwon, K.H., Park, H.J., Kim, Y., Jeon, D.Y.: A novel blue-emitting silica-coated KBaPO4:Eu2+ phosphor under vacuum ultraviolet and ultraviolet excitation. Mater. Chem. Phys. 115, 161 (2009)Google Scholar
2.Kubota, S., Shimada, M.: Sr3Al10SiO20:Eu2+ as a blue luminescent material for plasma displays. Appl. Phys. Lett. 81, 2749 (2002)Google Scholar
3.Jiang, Y.D., Zhang, F., Summers, C.J., Wang, Z.L.: Synthesis and properties of Sr2CeO4 blue emission powder phosphor for field emission displays. Appl. Phys. Lett. 74, 1677 (1999)Google Scholar
4.Park, S.J., Park, C.H., Yu, B.Y., Bae, H.S., Kim, C.H., Pyun, C.H.: Structure and luminescence of SrY2O4:Eu. J. Electrochem. Soc. 146, 3903 (1999)Google Scholar
5.Fu, Z.L., Zhou, S.Y., Yu, Y.N., Zhang, S.Y.: Photoluminescence properties and analysis of spectral structure of Eu3+-doped SrY2O4. J. Phys. Chem. B 109, 23320 (2005)CrossRefGoogle ScholarPubMed
6.Atkins, R., Diaz, A.L.: Investigation of host-to-activator energy transfer and surface losses in SrY2O4:Eu3+ under VUV excitation. J. Lumin. 128, 1463 (2008)Google Scholar
7.Xu, W.L., Jia, W.Y., Revira, I., Monge, K., Liu, H.M.: Optical properties of multiple sites of Eu3+ in SrY2O4 single-crystal fibers. J. Electrochem. Soc. 148, H176 (2001)Google Scholar
8.Fu, Z.L., Zhou, S.H., Zhang, S.Y.: Preparation and optical properties of trivalent europium-doped bulk and nanocrystalline SrY2O4. J. Opt. Soc. Am. B: Opt. Phys. 23, 1852 (2006)Google Scholar
9.Wang, D.Y., Wang, Y.H., Wang, L.L.: Photoluminescence properties of Sr(Y, Gd)2O4:Eu3+ under VUV excitation. J. Lumin. 126, 135 (2007)Google Scholar
10.Babin, V., Fabeni, P., Krasnikov, A., Nejezchleb, K., Nikl, M., Pazzi, G.P., Savikhina, T., Zazubovich, S.: Irregular Ce3+ and defect-related luminescence in YAlO3 single crystal. J. Lumin. 124, 273 (2007)Google Scholar
11.Bode, J.H.G., Oosterhout, A.B.V.: Defect luminescence of ordered perovskites A2BWO6. J. Lumin. 10, 237 (1975)Google Scholar
12.Mao, Z.Y., Wang, D.J., Lu, Q.F., Yu, W.H., Yuan, Z.H.: Tunable single-doped single-host full-color-emitting LaAlO3:Eu phosphor via valence state-controlled means. Chem. Commun. 40, 346 (2009)Google Scholar
13.Chen, L., Jiang, Y., Chen, S.F., Zhang, G.B., Wang, C., Li, G.H.: The intermediate role of Gd3+ in energy transfer to produce light under VUV excitation. J. Lumin. 128, 2048 (2008)Google Scholar
14.Zhang, Q.Y., Huang, X.Y.: Recent progress in quantum cutting phosphors. Prog. Mater. Sci. 55, 353 (2010)CrossRefGoogle Scholar
15.Di, W.H., Wang, X.J., Chen, B.J., Lai, H.S., Zhao, X.X.: Preparation, characterization and VUV luminescence property of YPO4:Tb phosphor for a PDP. Opt. Mater. 27, 1386 (2005)CrossRefGoogle Scholar
16.Moine, B., Mugnier, J., Boyer, D., Mahiou, R., Schamm, S., Zanchi, G.: VUV absorption coefficient measurements of borate matrices. J. Alloys Compd 323/324, 816 (2001)Google Scholar