Hostname: page-component-78c5997874-v9fdk Total loading time: 0 Render date: 2024-11-09T08:09:22.737Z Has data issue: false hasContentIssue false
  • English
  • Français

Low temperature chemical synthesis of nanocrystalline Pb(Mg1/3Nb2/3)O3 and (1–x)Pb(Mg1/3Nb2/3)O3–xPb(Fe1/2Nb1/2)O3 (x = 0.1, 0.2, and 1) ceramics

Published online by Cambridge University Press:  31 January 2011

R. N. Das ,
J. C. Ray  and
P. Pramanik
R. N. Das*
Affiliation:
Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology, Bombay, Powai, Mumbai-400076, India
J. C. Ray
Affiliation:
Department of Chemistry, Indian Institute of Technology, Kharagpur-721–302, West-Bengal, India
P. Pramanik
Affiliation:
Department of Chemistry, Indian Institute of Technology, Kharagpur-721–302, West-Bengal, India
*
a)Address all correspondence to this address. e-mail: [email protected]
Get access

Abstract

Nanocrystalline (20 nm) lead magnesium niobate (PMN) powders were prepared via a chemical process. This process involved the addition of aqueous niobium tartrate, lead-ethylenediaminetetraacetic acid, and magnesium-polyvinyl alcohol complex to produce a homogeneous solution. After the complete evaporation of the resulting homogeneous solution, the complexes decomposed and produced a black, fluffy precursor material. The precursor material on calcination up to 850 °C/2 h produced nanocrystalline PMN powders with the corresponding average particle size 20 nm. PMN powders modified with lead iron niobate (PFN) (1 – x)PMN–xPFN (x = 0.1, 0.2, and 1) were also prepared using this route and investigated through x-ray diffraction studies.

Type
Articles
Information
Journal of Materials Research , Volume 15 , Issue 11 , November 2000 , pp. 2273 - 2275
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Piezoelectricity, edited by Taylor, G.W., Gagnepain, J.J., Nakamura, T., and Shuvlaov, L. (Gordon and Breach Science Publishers, United Kingdom, 1992), Vol. 4.Google Scholar
2.Sekar, M.M. and Halliyal, A., J. Am. Ceram. Soc. 81, 380 (1998).CrossRefGoogle Scholar
3.Randall, C.A., Kim, N., Kucera, J-P., Cao, W., and Shrout, T.R., J. Am. Ceram. Soc. 81, 677 (1998).CrossRefGoogle Scholar
4.Das, R.N., Pathak, A., and Pramanik, P., J. Am. Ceram. Soc. 81, 3353 (1998).CrossRefGoogle Scholar
5.Das, R.N. and Pramanik, P., Nanostruct. Mater. 10, 1371 (1998).CrossRefGoogle Scholar
6.Lejeune, M. and Boilot, J.P., Ceram. Int. 8, 99 (1992).CrossRefGoogle Scholar
7.Chaput, F., Boilot, J.P., Lejeune, M., Papiernik, R., and Hubert Pfalzgraf, L.G., J. Am. Ceram. Soc. 72, 1355 (1989).CrossRefGoogle Scholar
8.Choy, J-H., Woo, J-S., Kang, S-G., Hong, S-T., and Kim, D-G., Mater. Res. Bull. 25, 283 (1990).CrossRefGoogle Scholar