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LiMn2O4 microspheres secondary structure of nanoparticles/plates as cathodes for Li-ion batteries

Published online by Cambridge University Press:  23 April 2013

Cheng-Yue Sun ,
Yun-Guang Zhu ,
Tie-Jun Zhu ,
Jian Xie ,
Gao-Shao Cao ,
Xin-Bing Zhao  and
Shi-Chao Zhang
Cheng-Yue Sun
Affiliation:
State Key Laboratory of Silicon Materials; Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province; and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
Yun-Guang Zhu*
Affiliation:
State Key Laboratory of Silicon Materials; Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province; and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
Tie-Jun Zhu*
Affiliation:
State Key Laboratory of Silicon Materials; Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province; and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
Jian Xie
Affiliation:
State Key Laboratory of Silicon Materials; Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province; and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
Gao-Shao Cao
Affiliation:
State Key Laboratory of Silicon Materials; Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province; and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
Xin-Bing Zhao
Affiliation:
State Key Laboratory of Silicon Materials; Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province; and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
Shi-Chao Zhang
Affiliation:
School of Materials Science and Engineering, Beijing University of Aeronautics and Astronautics, Beijing 100191, China
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

In this work, we succeeded in synthesis of spinel LiMn2O4 via a facile self-template method. The product displays a micro-/nanohybrid structure. Nanoparticles/plates act as the primary nanoblocks to build the secondary microarchitecture. There is the open space between the nanoblocks and the void space between the secondary structures. Electrochemical tests demonstrate that the as-synthesized sample exhibits superior rate capability and high-rate cycleability when contrasted with its solid counterpart. The initial discharge capacity is 126 mAh/g at 0.1 C, 110 mAh/g at 10 C, and 84 mAh/g at 20 C. The discharge capacity retention of about 80% is obtained after 800 cycles at 10 C. The high capacity and excellent cycling life of the material shows its potential for application as high-power batteries. The improved rate capability and cycleability can be attributed to its secondary structure that can facilitate fast Li-insertion/extraction and buffer the volume expansion/contraction upon cycling.

Type
Articles
Information
Journal of Materials Research , Volume 28 , Issue 10 , 28 May 2013 , pp. 1343 - 1348
Copyright
Copyright © Materials Research Society 2013 

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References

REFERENCES

Scrosati, B.: Challenge of portable power. Nature 373, 557 (1995).CrossRefGoogle Scholar
Marier, J.: Nanoionics: Ion transport and electrochemical storage in confined systems. Nat. Mater. 4, 805 (2005).CrossRefGoogle Scholar
Chung, S.Y., Bloking, J.T., and Chiang, Y.M.: Electronically conductive phospho-olivines as lithium storage electrodes. Nat. Mater. 1, 123 (2002).CrossRefGoogle ScholarPubMed
Li, W., Dahn, J.R., and Wainwright, D.S.: Rechargeable lithium batteries with aqueous electrolytes. Science 264, 1117 (1994).CrossRefGoogle ScholarPubMed
Whittingham, M.S.: Materials challenges facing electrical energy storage. Mater. Res. Bull. 33, 411 (2008).CrossRefGoogle Scholar
Thackeray, M.M., Johnson, P.J., Depicciotto, L.A., Bruce, P.G., and Goodenough, J.B.: Electrochemical extraction of lithium from LiMn2O4. Mater. Res. Bull. 19, 179 (1984).CrossRefGoogle Scholar
Thackeray, M.M.: Structural considerations of layered and spinel lithium ion batteries. J Electrochem. Soc. 142, 2558 (1995).CrossRefGoogle Scholar
Jiao, F., Shaju, K.M., and Bruce, P.G.: Synthesis of nanowire and mesoporous low-temperature LiCoO2 by a post-templating reaction. Angew. Chem. Int. Ed. 44, 6550 (2005).CrossRefGoogle ScholarPubMed
Tang, W., Tian, S., Liu, L.L., Li, L., Zhang, H.P., Yue, Y.B., Bai, Y., Wu, Y.P., and Zhu, K.: Nano-LiCoO2 as cathode material of large capacity and high rate capability for aqueous rechargeable lithium batteries. Electrochem. Commun. 12, 1524 (2010).CrossRefGoogle Scholar
Wang, Y. and Cao, G.: Developments in nanostructured cathode materials for high-performance lithium-ion batteries. Adv. Mater. 20, 2251 (2008).CrossRefGoogle Scholar
Guo, Y.G., Hu, Y.S., Sigle, W., and Marier, J.: Superior electrode performance of nanostructured mesoporous TiO2 (Anatase) through efficient hierarchical mixed conducting networks. Adv. Mater. 19, 2087 (2007).CrossRefGoogle Scholar
Ding, Y.L., Xie, J., Cao, G.S., Zhu, T.J., Yu, H.M., and Zhao, X.B.: Enhanced elevated-temperature performance of Al-doped single-crystalline LiMn2O4 nanotubes as cathodes for lithium ion batteries. J. Phys. Chem. C 115, 9821 (2011).CrossRefGoogle Scholar
Fu, L.J., Zhang, T., Cao, Q., Zhang, H.P., and Wu, Y.P.: Preparation and characterization of three-dimensionally ordered mesoporous titania microparticles as anode material for lithium ion battery. Electrochem. Commun. 9, 2143 (2007).CrossRefGoogle Scholar
Lytle, J.C., Yan, H., Ergang, N.S., Smyrl, W.H., and Stein, A.: Structural and electrochemical properties of three-dimensionally ordered macroporous tin(IV) oxide films. J. Mater. Chem. 14, 1621 (2004).CrossRefGoogle Scholar
Hosono, E., Kudo, T., Honma, I., Matsuda, H., and Zhou, H.: Synthesis of single crystalline spinel LiMn2O4 nanowires for a lithium ion battery with high power density. Nano Lett. 9, 1045 (2009).CrossRefGoogle ScholarPubMed
Ding, Y.L., Xie, J., Cao, G.S., Zhu, T.J., Yu, H.M., and Zhao, X.B.: Single-crystalline LiMn2O4 nanotubes synthesized via template-engaged reaction as cathodes for high-power lithium ion batteries. Adv. Funct. Mater. 21, 348 (2011).CrossRefGoogle Scholar
Hu, L., Zhong, H., Zheng, X., Huang, Y., Zhang, P., and Chen, Q.: CoMn2O4 spinel hierarchical microspheres assembled with porous nanosheets as stable anodes for lithium-ion batteries. Sci. Rep. 2, 986 (2012).CrossRefGoogle ScholarPubMed
Zhang, W.M., Hu, J.S., Guo, Y.G., Zheng, S.F., Zhong, L.S., Song, W.G., and Wan, L.J.: Tin-nanoparticles encapsulated in elastic hollow carbon spheres for high-performance anode material in lithium-ion batteries. Adv. Mater. 20, 1160 (2008).CrossRefGoogle Scholar
Lee, M.H., Kim, J.Y., and Song, H.K.: A hollow sphere secondary structure of LiFePO4 nanoparticles. Chem. Mater. 46, 6795 (2010).Google ScholarPubMed
Deng, D. and Lee, J.Y.: Hollow core-shell mesospheres of crystalline SnO2 nanoparticle aggregates for high capacity Li+ ion storage. Chem. Mater. 20, 1841 (2008).CrossRefGoogle Scholar
Fei, J., Cui, Y., Yan, X., Qi, W., Yang, Y., Wang, K., He, Q., and Li, J.: Controlled preparation of MnO2 hierarchical hollow nanostructures and their application in water treatment. Adv. Mater. 20, 452 (2008).CrossRefGoogle Scholar
Cao, J., Zhu, Y., Shi, L., Zhu, L., Bao, K., Liu, S., and Qian, Y.: Double-shelled Mn2O3 hollow spheres and their application in water treatment. Eur. J. Inorg. Chem. 2010, 1172 (2010).CrossRefGoogle Scholar
Xia, Y. and Yoshio, M.: An investigation of lithium ion insertion into spinel structure Li-Mn-O compounds. J. Electrochem. Soc. 143, 825 (1996).CrossRefGoogle Scholar
Xiao, X., Lu, J., and Li, Y.: LiMn2O4 microspheres: Synthesis, characterization and use as a cathode in lithium ion batteries. Nano Res. 3, 733 (2010).CrossRefGoogle Scholar
Naghash, A.R. and Lee, J.Y.: Preparation of spinel lithium manganese oxide by aqueous co-precipitation. J. Power Sources 85, 284 (2000).CrossRefGoogle Scholar
Kovacheva, D., Gadjov, H., Petrov, K., Mandal, S., Lazarraga, M.G., Pascual, L., Amarilla, J.M., Rojas, R.M., Herrero, P., and Rojo, J.M.: Synthesizing nanocrystalline LiMn2O4 by a combustion route. J. Mater. Chem. 12, 1184 (2002).CrossRefGoogle Scholar
Wu, H.M., Tu, J.P., Yuan, Y.F., Chen, X.T., Xiang, J.Y., Zhao, X.B., and Cao, G.S.: One-step synthesis LiMn2O4 cathode by a hydrothermal method. J. Power Sources 161, 1260 (2006).CrossRefGoogle Scholar
Zhou, L., Wu, H.B., Zhu, T., and Lou, X.W.: Facile preparation of ZnMn2O4 hollow microspheres as high-capacity anodes for lithium-ion batteries. J. Mater. Chem. 22, 827 (2012).CrossRefGoogle Scholar