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The influence of Nb and Zr on glass-formation ability in the ternary Fe–Nb–B and Fe–Zr–B and quaternary Fe–(Nb,Zr)–B alloy systems

Published online by Cambridge University Press:  31 January 2011

J.H. Yao ,
H. Yang ,
J. Zhang ,
J.Q. Wang  and
Y. Li
J.H. Yao
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, People’s Republic of China
H. Yang
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, People’s Republic of China
J. Zhang
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, People’s Republic of China
J.Q. Wang*
Affiliation:
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, People’s Republic of China
Y. Li*
Affiliation:
Department of Materials Science and Engineering, National University of Singapore, Singapore 117576, Singapore
*
a)Address all correspondence to these authors. e-mail: [email protected]
b)Address all correspondence to these authors. e-mail: [email protected]
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Abstract

Glass-forming ability (GFA) in relation to microstructure evolution in the ternary Fe–Nb–B and Fe–Zr–B and quaternary Fe–(Nb,Zr)–B systems was systematically studied in a three-dimensional composition space. Through navigating, it was revealed that alloys with the optimum glass-forming ability (GFA) are coupled with composition regions surrounded by competing crystalline phases. Alloys Fe71Nb6B23, Fe77Zr4B19, and Fe71(Nb0.8Zr0.2)6B23 were illustrated to be the best glass formers in the ternary Fe–Nb–B and Fe–Zr–B systems and the quaternary Fe–(Nb,Zr)–B system, respectively, with a critical size for amorphous formation up to 2 mm. They were compared with the theoretical predictions on the basis of an efficient dense-packing model, and good agreements were obtained.

Keywords

AlloyAmorphousFe
Type
Articles
Information
Journal of Materials Research , Volume 23 , Issue 2 , February 2008 , pp. 392 - 401
Copyright
Copyright © Materials Research Society 2007

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