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High-strength binary Ti–Fe bulk alloys with enhanced ductility

Published online by Cambridge University Press:  01 December 2004

Dmitri V. Louzguine ,
Hidemi Kato ,
Larissa V. Louzguina  and
Akihisa Inoue
Dmitri V. Louzguine*
Affiliation:
Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan
Hidemi Kato
Affiliation:
Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan
Larissa V. Louzguina
Affiliation:
Research and Development Project, CREST, Japan Science and Technology Agency, Sendai 985-8577, Japan
Akihisa Inoue
Affiliation:
Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan
*
a)Address all correspondence to this author. e-mail: [email protected] Spelling of the family names.
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Abstract

The structure of hypoeutectic, hypereutectic, and eutectic Ti–Fe alloys produced in the shape of arc-melted ingots was found to consist of the ordered Pm-3m TiFe and disordered BCC Im3m β–Ti solid solution phase. The dimensions of the ingots were about 25–40 mm in diameter and 10–15 mm in height, and their structure was studied by x-ray diffractometry and scanning electron microscopy. The rectangular parallelepiped-shaped samples 2.5 × 2.5 × 5 mm in size cut from the central part of the ingots exhibit a high strength of about 2000 MPa, except for Ti60Fe40, and a certain ductility. The relatively low density of Ti (4.5 Mg/m3) implies high strength/density ratio for the studied alloys. These alloys are characterized by the low cost of the alloying element Fe and, compared to most of the high-strength non-equilibrium materials, do not require additional injection mold casting or rapid solidification procedures.

Keywords

Mechanical propertiesScanning electron microscopy (SEM)X-ray diffraction (XRD)
Type
Articles
Information
Journal of Materials Research , Volume 19 , Issue 12 , December 2004 , pp. 3600 - 3606
Copyright
Copyright © Materials Research Society 2004

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References

REFERENCES

1Smithells Metals Reference Book, 7th ed., edited by Brandes, E.A. and Brook, G.B. (Butterworth-Heinemann Ltd., Hartnolls Ltd., Bodmin, U.K., 1992), pp. 22–84.Google Scholar
2Inoue, A., Nishiyama, N., Amiya, K., Zhang, T. and Masumoto, T.: Ti-based amorphous-alloys with a wide supercooled liquid region. Mater. Lett. 19, 131 (1994).CrossRefGoogle Scholar
3Lin, X.H. and Johnson, W.L.: Formation of Ti-Zr-Cu-Ni bulk metallic glasses. J. Appl. Phys. 78, 6514 (1995).Google Scholar
4Zhang, T., Inoue, A. and Masumoto, T.: Amorphous (Ti, Zr, Hf)-Ni-Cu ternary alloys with a wide supercooled liquid region. Mater. Sci. Eng. A 181, 1423 (1994).Google Scholar
5Zhang, T. and Inoue, A.: Thermal and mechanical properties of Ti-Ni-Cu-Sn amorphous alloys with a wide supercooled liquid region before crystallization. Mater. Trans. JIM 39, 1001 (1998).Google Scholar
6Parlapanska, S. and Parlapanski, D.: Corrosion behavior of mechanically alloyed Ti-Si samples. Corros. Sci. 39, 1321 (1977).Google Scholar
7Johnson, W.L.: Bulk glass-forming metallic alloys: Science and technology. MRS Bull. 24, 42 (1999).Google Scholar
8He, G., Eckert, J., Loser, W. and Schultz, L.: Novel Ti-base nanostructure-dendrite composite with enhanced plasticity. Nat. Mater. 2, 33 (2003).CrossRefGoogle ScholarPubMed
9Hays, C.C., Kim, C.P. and Johnson, W.L.: Microstructure controlled shear band pattern formation and enhanced plasticity of bulk metallic glasses containing in situ formed ductile phase dendrite dispersions. Phys. Rev. Lett. 84, 2901 (2000).CrossRefGoogle ScholarPubMed
10Boyer, R.R. and Rosenberg, H.W. Ti-10V-2Fe-3Al properties, in Beta Titanium Alloys in the 80’s, edited by Boyer, R.R. and Rosenberg, H.W. (Metallurgical Society of AIME, Warrendale, PA, 1984), p. 41Google Scholar
11Smithells Metals Reference Book, 7th ed., edited by Brandes, E.A. and Brook, G.B. (Butterworth-Heinemann Ltd., Hartnolls Ltd., Bodmin, U.K., 1992), pp. 11–273.Google Scholar
12Smithells Metals Reference Book, 8th ed., edited by Gale, W.F. and Totemeier, T.C. (Elsevier Butterworth-Heinemann Ltd., Oxford U.K., 2004), pp. 13–30.Google Scholar
13 PDF#19-0636 Database sets 1–49 and 70–92, PCPDFWIN Version 2.2, JCPDS-International Centre for Diffraction Data, 2001.Google Scholar
14Wassermann, E.F., Rellinghaus, B., Roessel, Th. and Pepperhoff, W.: Relation between structure and magnetism of TixFe100-x alloys within the C14 Laves-phase stability range. J. Magn. Magn. Mater. 190, 289 (1998).Google Scholar
15Dwight, T.: CsCl-type equiatomic phases in binary alloys of transition elements. Trans. AIME 215, 283 (1959).Google Scholar
16Smithells Metals Reference Book, 7th ed., edited by Brandes, E.A. and Brook, G.B. (Butterworth-Heinemann Ltd., Hartnolls Ltd., Bodmin, U.K., 1992), pp. 22–84Google Scholar
17Inoue, A. and Takeuchi, A.: Recent progress in bulk glassy alloys. Mater. Trans. 43, 1892 (2002).Google Scholar
18Loffler, J.F.: Bulk metallic glasses. Intermetallics 11, 529 (2003).Google Scholar
19Wang, W.H., Dong, C. and Shek, C.H.: Bulk metallic glasses. Mater. Sci. Eng. Rep. 44, 45 (2004).Google Scholar
20Louzguine, D.V. and Inoue, A.: Nanocrystallization of Ti-Ni-Cu-Sn amorphous alloy. Scripta Mater. 43, 371 (2000).CrossRefGoogle Scholar
21Smithells Metals Reference Book, 8th ed., edited by Gale, W.F. and Totemeier, T.C. (Elsevier Butterworth-Heinemann Ltd., Oxford, U.K., 2004), pp. 11–400.Google Scholar
22 L.V. Louzguina, D.V. Louzguine, and A. Inoue: Ultra-strong and ductile hypereutectic Ti-based bulk alloys, in Proceedings of the 11th International Symposium on Metastable, Mechanically Alloyed and Nanocrystalline Materials, August 22-26, Sendai, Japan J. Metast. and Nanocr. Mater., in press, 2004.Google Scholar
23Pittinato, G.F., Kerlins, V., Phillips, A. and Russo, M.A.: SEM/TEM Fractography Handbook, MCIC-HB-06 (Metals and Ceramics Information Center, Wright-Patterson, OH, 1975), p 77Google Scholar
24Ray, R., Giessen, B.C. and Grant, N.J.: Constitution of metastable titanium-rich Ti–Fe alloys—order-disorder transition. Metall. Trans. 3, 627 (1972).Google Scholar
25Kim, Y.C., Kim, W.T. and Kim, D.H.: A development of Ti-based bulk metallic glass. Mater. Sci. Eng. A 375, 127 (2004).Google Scholar