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Highly conductive ink made of silver nanopolyhedrons through an ecofriendly solution process

Published online by Cambridge University Press:  18 February 2011

Hua Zheng ,
Junxuan Yuan ,
Lei Wang ,
Junbiao Peng ,
Yong Cao ,
Hai-Bo Chen ,
Jian Wang  and
Jian Pei
Hua Zheng
Affiliation:
Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Key Laboratories of Specially Functional Materials, Ministry of Education, Guangzhou 510640, China
Junxuan Yuan
Affiliation:
Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Key Laboratories of Specially Functional Materials, Ministry of Education, Guangzhou 510640, China
Lei Wang
Affiliation:
Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Key Laboratories of Specially Functional Materials, Ministry of Education, Guangzhou 510640, China
Junbiao Peng
Affiliation:
Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Key Laboratories of Specially Functional Materials, Ministry of Education, Guangzhou 510640, China
Yong Cao
Affiliation:
Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Key Laboratories of Specially Functional Materials, Ministry of Education, Guangzhou 510640, China
Hai-Bo Chen
Affiliation:
Key Laboratories of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
Jian Wang*
Affiliation:
Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Key Laboratories of Specially Functional Materials, Ministry of Education, Guangzhou 510640, China
Jian Pei*
Affiliation:
Key Laboratories of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
*
b)Address all correspondence to these authors: e-mail: [email protected]
c)e-mail: [email protected]
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Abstract

An ecofriendly process has been successfully developed to synthesize the polycrystalline silver nanopolyhedrons with a high yield at large scale. By using tannic acid in the presence of poly (vinyl pyrrolidone) (PVP), high quality silver nanopolyhedrons were obtained in an aqueous one-pot reaction without any templates or auxiliaries. The film made from the silver nanostructures exhibits an electrical conductivity higher than 104 S/cm on both rigid and flexible substrates. The supreme mechanical strength of this silver film recommends its wide application in printing and flexible electronics.

Keywords

AgNanostructureFilm
Type
Materials Communications
Information
Journal of Materials Research , Volume 26 , Issue 4 , 28 February 2011 , pp. 503 - 507
Copyright
Copyright © Materials Research Society 2011

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Footnotes

The purpose of this Materials Communications section is to provide accelerated publication of important new results in the fields regularly covered by Journal of Materials Research. Materials Communications cannot exceed four printed pages in length, including space allowed for title, figures, tables, references, and an abstract limited to about 100 words.

a)

These authors contributed equally to this work.

References

REFERENCES

1.Crawford, G.P.: Flexible flat panel display technology, in Flexible Flat Panel Display, edited by Crawford, G.P. (John Wiley & Sons, West Sussex, UK, 2005).CrossRefGoogle Scholar
2.Sirringhaus, H., Sele, C.W., von Werne, T., and Ramsdale, C.: Manufacturing of organic transistor circuits by solution-based printing, in Organic Electronics: Materials, Manufacturing, and Applications, edited by Klauk, H. (Wiley-VCH, Weinheim, Germany, 2006).Google Scholar
3.Li, Y., Wu, Y., and Ong, B.S.: A simple and efficient approach to a printable silver conductor for printed electronics. J. Am. Chem. Soc. 129, 1862 (2007).Google Scholar
4.Zheng, J., Ding, Y., Tian, B., Wang, Z.L., and Zhuang, X.: Luminescent and Raman active silver nanoparticles with polycrystalline structure. J. Am. Chem. Soc. 130, 10472 (2008).CrossRefGoogle ScholarPubMed
5.Liu, L., Wei, T., Guan, X., Zi, X., He, H., and Dai, H.: Size and morphology adjustment of PVP-stabilized silver and gold nanocrystals synthesized by hydrodynamic assisted self-assembly. J. Phys. Chem. C 113, 8595 (2009).CrossRefGoogle Scholar
6.Menard, E., Meitl, M.A., Sun, Y.G., Park, J.U., Shir, D.J.L., Nam, Y.S., Jeon, S., and Rogers, J.A.: Micro- and nanopatterning techniques for organic electronic and optoelectronic systems. Chem. Rev. 107, 1117 (2007).CrossRefGoogle ScholarPubMed
7.Tate, J., Rogers, J.A., Jones, C.D.W., Vyas, B., Murphy, D.W., Li, W.J., Bao, Z.A., Slusher, R.E., Dodabalapur, A., and Katz, H.E.: Anodization and microcontact printing on electroless silver: Solution-based fabrication procedures for low-voltage electronic systems with organic active components. Langmuir 16, 6054 (2000).CrossRefGoogle Scholar
8.Cui, S.Q., Liu, Y.C., Yang, Z.S., and Wei, X.W.: Construction of silver nanowires on DNA template by an electrochemical technique. Mater. Des. 28, 722 (2007).CrossRefGoogle Scholar
9.Pietrobon, B. and Kitaev, V.: Photochemical synthesis of monodisperse size-controlled silver decahedral nanoparticles and their remarkable optical properties. Chem. Mater. 20, 5186 (2008).CrossRefGoogle Scholar
10.Kundu, S., Wang, K., and Liang, H.: Size-controlled synthesis and self-assembly of silver nanoparticles within a minute using microwave irradiation. J. Phys. Chem. C 113, 134 (2009).CrossRefGoogle Scholar
11.Setua, P., Chakraborty, A., Seth, D., Bhatta, M.U., Satyam, P.V., and Sarkar, N.: Synthesis, optical properties, and surface enhanced Raman scattering of silver nanoparticles in nonaqueous methanol reverse micelles. J. Phys. Chem. C 111, 3901 (2007).CrossRefGoogle Scholar
12.Nooney, R.I., Stranik, O., McDonagh, C., and MacCraith, B.D.: Optimization of plasmonic enhancement of fluorescence on plastic substrates. Langmuir 24, 11261 (2008).CrossRefGoogle Scholar
13.Hu, B., Wang, S.B., Wang, K., Zhang, M., and Yu, S.H.: Microwave-assisted rapid facile “green” synthesis of uniform silver nanoparticles: Self-assembly into multilayered films and their optical properties. J. Phys. Chem. C 112, 11169 (2008).CrossRefGoogle Scholar
14.Buffat, P. and Borel, J.P.: Size effect on the melting temperature of gold particles. Phys. Rev. A 13, 2287 (1976).CrossRefGoogle Scholar
15.Wu, Y.L., Li, Y.N., and Ong, B.S.: Printed silver ohmic contacts for high-mobility organic thin-film transistors. J. Am. Chem. Soc. 128, 4202 (2006).CrossRefGoogle ScholarPubMed
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