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Functionalized activated carbon prepared form petroleum coke with high-rate supercapacitive performance

Published online by Cambridge University Press:  08 November 2016

Yan Zhang ,
Tonghui Cai ,
Jufeng Huang ,
Wei Xing  and
Zifeng Yan
Yan Zhang
Affiliation:
School of Chemical Engineering, State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Qingdao 266580, People's Republic of China
Tonghui Cai
Affiliation:
School of Chemical Engineering, State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Qingdao 266580, People's Republic of China
Jufeng Huang
Affiliation:
School of Science, State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Qingdao 266580, People's Republic of China
Wei Xing*
Affiliation:
School of Science, State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Qingdao 266580, People's Republic of China
Zifeng Yan*
Affiliation:
School of Chemical Engineering, State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Qingdao 266580, People's Republic of China
*
a) Address all correspondence to this author. e-mail: [email protected]
a) Address all correspondence to this author. e-mail: [email protected]
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Abstract

Petroleum coke (PC) is a low-cost and potential carbon source for electrochemical energy storage. To expand the utilization of PC in supercapacitor, PC-based activated carbons (PCACs) with heteroatoms-doped were prepared from PC by KOH chemical activation. The as-prepared carbon exhibited a high surface area (2326.4 m2/g) and hierarchical micro-mesoporous structure, resulting in a high specific capacitance (421 F/g at 1 A/g) and excellent rate performance in KOH electrolyte (217 F/g at 50 A/g). Meanwhile, to improve the high-rate capacitive performance of PCACs in H2SO4 electrolyte, functionalized activated carbon (HQ/PCAC-4) was prepared by physically adsorbing the hydroquinone (HQ) on PCACs. The HQ/PCAC-4 showed an unprecedented capacitance value of 300.2 F/g even at an ultrahigh current density of 50 A/g. In addition, the energy density of HQ/PCAC-4 in H2SO4 electrolyte reached 19.5 W h/kg. The high energy density and excellent rate performance ensured their prosperous application in high-power energy storage system.

Keywords

electrical propertiesenergy storagenanostructure
Type
Articles
Information
Journal of Materials Research , Volume 31 , Issue 23 , 14 December 2016 , pp. 3723 - 3730
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Copyright
Copyright © Materials Research Society 2016 

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References

REFERENCES

Stoller, M.D. and Ruoff, R.S.: Best practice methods for determining an electrode material's performance for ultracapacitors. Energy Environ. Sci. 3(9), 1294 (2010).Google Scholar
Zhang, L.L. and Zhao, X.: Carbon-based materials as supercapacitor electrodes. Chem. Soc. Rev. 38(9), 2520 (2009).Google Scholar
Yan, J., Wang, Q., Wei, T., and Fan, Z.: Recent advances in design and fabrication of electrochemical supercapacitors with high energy densities. Adv. Energy Mater. 4(4), 1300816 (2014).Google Scholar
Simon, P. and Gogotsi, Y.: Materials for electrochemical capacitors. Nat. Mater. 7(11), 845 (2008).Google Scholar
Chen, S-M., Ramachandran, R., Mani, V., and Saraswathi, R.: Recent advancements in electrode materials for the high performance electrochemical supercapacitors: A review. Int. J. Electrochem. Sci. 9, 4072 (2014).Google Scholar
Jiang, H., Lee, P.S., and Li, C.: 3D carbon based nanostructures for advanced supercapacitors. Energy Environ. Sci. 6(1), 41 (2013).CrossRefGoogle Scholar
Chmiola, J., Yushin, G., Gogotsi, Y., Portet, C., Simon, P., and Taberna, P-L.: Anomalous increase in carbon capacitance at pore sizes less than 1 nanometer. Science 313(5794), 1760 (2006).Google Scholar
Largeot, C., Portet, C., Chmiola, J., Taberna, P-L., Gogotsi, Y., and Simon, P.: Relation between the ion size and pore size for an electric double-layer capacitor. J. Am. Chem. Soc. 130(9), 2730 (2008).CrossRefGoogle ScholarPubMed
Zhong, M., Kim, E.K., McGann, J.P., Chun, S-E., Whitacre, J.F., Jaroniec, M., Matyjaszewski, K., and Kowalewski, T.: Electrochemically active nitrogen-enriched nanocarbons with well-defined morphology synthesized by pyrolysis of self-assembled block copolymer. J. Am. Chem. Soc. 134(36), 14846 (2012).Google Scholar
Liu, F. and Xue, D.: An electrochemical route to quantitative oxidation of graphene frameworks with controllable C/O ratios and added pseudocapacitances. Chem. –Eur. J. 19(32), 10716 (2013).Google Scholar
Singh, C. and Paul, A.: Physisorbed hydroquinone on activated charcoal as a supercapacitor: An application of proton-coupled electron transfer. J. Phys. Chem. C 119(21), 11382 (2015).Google Scholar
Wu, Z-S., Sun, Y., Tan, Y-Z., Yang, S., Feng, X., and Müllen, K.: Three-dimensional graphene-based macro-and mesoporous frameworks for high-performance electrochemical capacitive energy storage. J. Am. Chem. Soc. 134(48), 19532 (2012).CrossRefGoogle ScholarPubMed
Xing, W., Huang, C., Zhuo, S., Yuan, X., Wang, G., Hulicova-Jurcakova, D., Yan, Z., and Lu, G.: Hierarchical porous carbons with high performance for supercapacitor electrodes. Carbon 47(7), 1715 (2009).Google Scholar
Puthusseri, D., Aravindan, V., Madhavi, S., and Ogale, S.: 3D micro-porous conducting carbon beehive by single step polymer carbonization for high performance supercapacitors: The magic of in situ porogen formation. Energy Environ. Sci. 7(2), 728 (2014).Google Scholar
Gao, Y., Zhou, Y.S., Qian, M., He, X.N., Redepenning, J., Goodman, P., Li, H.M., Jiang, L., and Lu, Y.F.: Chemical activation of carbon nano-onions for high-rate supercapacitor electrodes. Carbon 51, 52 (2013).Google Scholar
Pittman, C. Jr, He, G-R., Wu, B., and Gardner, S.: Chemical modification of carbon fiber surfaces by nitric acid oxidation followed by reaction with tetraethylenepentamine. Carbon 35(3), 317 (1997).Google Scholar
Andreas, H.A. and Conway, B.E.: Examination of the double-layer capacitance of an high specific-area C-cloth electrode as titrated from acidic to alkaline pHs. Electrochim. Acta 51(28), 6510 (2006).Google Scholar
Okajima, K., Ohta, K., and Sudoh, M.: Capacitance behavior of activated carbon fibers with oxygen-plasma treatment. Electrochim. Acta 50(11), 2227 (2005).Google Scholar
Hulicova-Jurcakova, D., Seredych, M., Lu, G.Q., and Bandosz, T.J.: Combined effect of nitrogen-and oxygen-containing functional groups of microporous activated carbon on its electrochemical performance in supercapacitors. Adv. Funct. Mater. 19(3), 438 (2009).Google Scholar
Cai, T., Xing, W., Liu, Z., Zeng, J., Xue, Q., Qiao, S., and Yan, Z.: Superhigh-rate capacitive performance of heteroatoms-doped double shell hollow carbon spheres. Carbon 86, 235 (2015).Google Scholar
Lin, T., Chen, I-W., Liu, F., Yang, C., Bi, H., Xu, F., and Huang, F.: Nitrogen-doped mesoporous carbon of extraordinary capacitance for electrochemical energy storage. Science 350(6267), 1508 (2015).Google Scholar
Simon, P. and Gogotsi, Y.: Capacitive energy storage in nanostructured carbon–electrolyte systems. Acc. Chem. Res. 46(5), 1094 (2012).Google Scholar
Raymundo-Pinero, E., Kierzek, K., Machnikowski, J., and Béguin, F.: Relationship between the nanoporous texture of activated carbons and their capacitance properties in different electrolytes. Carbon 44(12), 2498 (2006).Google Scholar
Wang, D.W., Li, F., Liu, M., Lu, G.Q., and Cheng, H.M.: 3D aperiodic hierarchical porous graphitic carbon material for high-rate electrochemical capacitive energy storage. Angew. Chem. 120(2), 379 (2008).Google Scholar
Lei, Z., Liu, Z., Wang, H., Sun, X., Lu, L., and Zhao, X.: A high-energy-density supercapacitor with graphene–CMK-5 as the electrode and ionic liquid as the electrolyte. J. Mater. Chem. A 1(6), 2313 (2013).CrossRefGoogle Scholar
Lei, Z., Christov, N., and Zhao, X.: Intercalation of mesoporous carbon spheres between reduced graphene oxide sheets for preparing high-rate supercapacitor electrodes. Energy Environ. Sci. 4(5), 1866 (2011).Google Scholar
Zhi, J., Zhao, W., Liu, X., Chen, A., Liu, Z., and Huang, F.: Highly conductive ordered mesoporous carbon based electrodes decorated by 3D graphene and 1D silver nanowire for flexible supercapacitor. Adv. Funct. Mater., 24(14), 2013 (2013).Google Scholar
Hou, Y., Guo, L-p., and Wang, G.: Synthesis and electrochemical performance of ordered mesoporous carbons with different pore characteristics for electrocatalytic oxidation of hydroquinone. J. Electroanal. Chem. 617(2), 211 (2008).Google Scholar
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