Hostname: page-component-586b7cd67f-t8hqh Total loading time: 0 Render date: 2024-11-26T21:32:09.407Z Has data issue: false hasContentIssue false
  • English
  • Français

Formation of silicate structures in Cu-containing silica xerogels

Published online by Cambridge University Press:  31 January 2011

F. Ruiz ,
J. R. Martínez  and
J. González-Hernández
F. Ruiz
Affiliation:
Instituto de Fíica “Manuel Sandoval Vallarta,” Universidad Autónoma de San Luis Potosí, 78000 San Luis Potosí, S.L.P., Mexico
J. R. Martínez
Affiliation:
Facultad de Ciencias, Universidad Autónoma de San Luis Potosí, 78000 San Luis Potosí, S.L.P., Mexico
J. González-Hernández
Affiliation:
Centro de Investigación y de Estudios Avanzados del IPN, Unidad Querétaro, Apdo. Postal 1–1010, C.P. 76010, Querétaro, Qro., Mexico
Get access

Abstract

Using infrared absorption and Raman spectroscopy, the structure of SiO2 sol-gel samples containing copper were analyzed as a function of air heat treatments. The weight composition of the samples was 70(SiO2)–30(CuO) and the thermal treatments were carried out in air at various temperatures in the range of 100–600 °C. It was found that the Cu might be incorporated into the SiO2 matrix at least in two ways: forming oxide particles and forming metasilicatelike structures. The copper metasilicate found had the chemical formula, Cu6 [Si6O18] · 6H2O, which is known as dioptase with a thermal stability at temperatures up to 600 °C.

Type
Articles
Information
Journal of Materials Research , Volume 15 , Issue 12 , December 2000 , pp. 2875 - 2880
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Brinker, C.J. and Scherer, G.W., Sol-Gel: The Physics and Chemistry of Sol Gel Processing (Academic Press, New York, 1990).Google Scholar
2.Orgaz, F. and Rawson, H., J. Non-Cryst. Solids 82, 390 (1986).Google Scholar
3.Nogami, M., in Sol-Gel Optics, Processing and Applications, edited by Klein, L.C. (Kluwer Academic, Hingham, MA, 1994). p. 329.Google Scholar
4.Gwak, J-H., Kim, S-J., and Lee, M., J. Phys. Chem. B 102, 7699 (1998).CrossRefGoogle Scholar
5.Iwamoto, M., Stud. Surf. Sci. Catal. 54, 121 (1990).CrossRefGoogle Scholar
6.Shimokawage, M., Takezawa, N., and Kobayashi, H., Appl. Catal. 2, 379 (1982).CrossRefGoogle Scholar
7.Yan, J., Buckley, A.M., and Greenblatt, M., J. Non-Cryst. Solids 180, 180 (1995).CrossRefGoogle Scholar
8.da Silva, M.G.F. and Fernandez Navarro, J.M., J. Non-Cryst. Solids 100, 447 (1988).CrossRefGoogle Scholar
9.Pérez-Robles, J.F., García-Rodríguez, F.J., Yañez-Limón, J.M., Espinoza-Beltrán, F.J., Vorobiev, Y.V., and González-Hernández, J., J. Phys. Chem. Solids 60, 1729 (1999).CrossRefGoogle Scholar
10.Ogale, S.B., Bilukar, P.G., Mate, N., Kanetkar, S.M., Parikh, N., and Patnaik, B., J. Appl. Phys. 72, 3765 (1992).CrossRefGoogle Scholar
11.Cordoba, G., Arroyo, R., Fierro, J.L.G, and Viniegra, M., J. Solid State Chem. 123, 93 (1994).CrossRefGoogle Scholar
12.Wells, A.F., Structural Inorganic Chemistry (Clarendon Press, Oxford, 1978).Google Scholar
13.Belov, N.V., Maksirnov, B.A., Noskik, Yu. Z., and Muradyan, L.A., Sov. Phys. Dokl. 23, 215 (1978).Google Scholar
14.Rino, J.P., Ebbsjö, I., Kalia, R.K., Nakana, A., and Vashishta, P., Phys. Rev. B 47, 3053 (1993).CrossRefGoogle Scholar
15.Pérez-Robles, J.F., García-Cerda, L.A., Espinoza-Beltrán, F.J., Yánez-Limón, M., González-Hernández, J., Vorobiev, Y.V., and Parga-Torres, J.R., Ruiz, F., and Méndez-Nonell, J., Phys. Status Solidi 172, 49 (1999).3.0.CO;2-I>CrossRefGoogle Scholar
16.Sen, P. and Thorpe, M.F., Phys. Rev. B 15, 4030 (1979).CrossRefGoogle Scholar
17.Galeener, F.L., Phys. Rev. B 15, 4292 (1979).CrossRefGoogle Scholar
18.Duran, A., Serna, C., Fornes, V., and Fernández-Navarro, J.M., J. Non-Cryst. Solids 63, 45 (1984).Google Scholar
19.Colthup, N.B., Daly, L.H., and Wiberly, S.E., Introduction to Infrared and Raman Spectroscopy, 2nd ed. (Academic Press, New York, 1975).Google Scholar
20.Martínez, J.R., Ruiz, F., Vorobiev, Y.V., Pérez-Robles, F., and González-Hernández, J., J. Chem. Phys. 109, 7511 (1998).CrossRefGoogle Scholar
21.Martínez, J.R., Ruiz, F., de la Cruz-Mendoza, J.A., Villaseñor-González, P., González-Hernández, J., González-Chávez, M.M., and Valle-Aguilera, L., Rev. Mex. Fís. 44, 575 (1998).Google Scholar
22.Lange, P., J. Appl. Phys. 66, 201 (1989).CrossRefGoogle Scholar
23.Ogale, S.B., Bilukar, P.G., Mate, N., Kanetkar, S.M., Parikh, N., and Patnaik, B., J. Appl. Phys. 72, 3765 (1992).CrossRefGoogle Scholar
24.Kirk, C.T., Phys. Rev. B 38, 1255 (1988).CrossRefGoogle Scholar
25.Seifert, F.A., Mysen, B.O., and Virgo, D., Am. Mineral. 67, 696 (1982).Google Scholar
26.Vukcetich, M.R., J. Non-Cryst. Solids 48, 31 (1982).Google Scholar
27.Iler, R.K., The Chemistry of Silica (Wiley, New York, 1979).Google Scholar
28.Lucovsky, G. and Manitini, M.J., J. Vac. Sci. Technol. B 5, 530 (1987).CrossRefGoogle Scholar
29.Galeener, F.L., Solid State Commun. 44, 1037 (1982).CrossRefGoogle Scholar
30.Pasquarello, and Car, R., Phys. Rev. Lett. 80, 5145 (1998).CrossRefGoogle Scholar
31.Dean, P., Nature, 210, 257 (1966).CrossRefGoogle Scholar
32.Galeener, F., Barrio, RA., Martínez, E., and Elliot, R.J., Phys. Rev. Lett. 53, 2429 (1984).CrossRefGoogle Scholar
33.Zuñiga, A., Ruiz, F., Vázquez, C., González-Hernández, J., Torres, G., and Tsu, DV., J. Vac. Sci. Technol. A 12, 1445 (1994).Google Scholar
34.Krol, D.M. and van Lierop, J.G., J. Non-Cryst. Solids 63, 131 (1984).CrossRefGoogle Scholar
35.Armitage, D.A., Inorganic Rings and Cages (Edward Arnold, London, 1972).Google Scholar
36.Barrio, R.A., Galeener, F.L., Martinez, E., and Elliott, R.J., Phys. Rev. B 48, 15672 (1993).CrossRefGoogle Scholar
37.Riegel, B., Hartmann, I., Kiefer, W., Groβ, J., Fricke, J., J. Non-Cryst. Solids 211, 294 (1997).CrossRefGoogle Scholar
38.Pérez-Robles, F., García-Rodríguez, F.J., Jimenez-Sandoval, S., and González-Hernández, J., J. Raman Spectrosc. 30, 1099 (1999).3.0.CO;2-0>CrossRefGoogle Scholar
39.Nakamoto, K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, 5th ed. (John Wiley, New York, 1997).Google Scholar
40.Chrzanowski, J. and Irwin, J.C., Solid State Phys. 70, 11 (1989).Google Scholar
41.International Center for Diffraction Data, Inorganic Phases (Joint Committee on Powder Diffraction Standards, Swarthmore, PA, 1995), Powder Diffraction File, Card No. 41–0254.Google Scholar
42.McMillan, P. and Piriou, B., Bull. Mineral 106, 57 (1983).Google Scholar
43.Furukawa, T., Fox, T., and White, W.B., J. Chem. Phys. 75, 3226 (1981).CrossRefGoogle Scholar
44.McMillan, P. and Piriou, B., J. Non-Cryst. Solids, 53, 279 (1982).CrossRefGoogle Scholar
45.Virgo, D., Mysen, O.B., and Kushiro, I., Science 208, 1371 (1980).CrossRefGoogle Scholar