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Formation and properties of Pr-based bulk metallic glasses

Published online by Cambridge University Press:  01 February 2006

Z.F. Zhao
Affiliation:
Institute of Physics, Chinese Academy of Sciences, Beijing 100080, People’s Republic of China
P. Wen
Affiliation:
Institute of Physics, Chinese Academy of Sciences, Beijing 100080, People’s Republic of China
R.J. Wang
Affiliation:
Institute of Physics, Chinese Academy of Sciences, Beijing 100080, People’s Republic of China
D.Q. Zhao
Affiliation:
Institute of Physics, Chinese Academy of Sciences, Beijing 100080, People’s Republic of China
M.X. Pan
Affiliation:
Institute of Physics, Chinese Academy of Sciences, Beijing 100080, People’s Republic of China
W.H. Wang*
Affiliation:
Institute of Physics, Chinese Academy of Sciences, Beijing 100080, People’s Republic of China
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

The data on the compositional dependence of glass-forming ability, glass transition, and properties of bulk metallic glasses (BMGs) are important for understanding the nature and glass-forming ability of metallic glasses and for their application. In this paper, we report the formation of rare-earth-based Pr–(Cu,Ni)–Al pseudo-ternary BMGs with a large bulk glass-forming composition range and distinct glass transition. The compositional dependence of glass-forming ability, glass transition, and properties were systematically studied. The contrasting effects of Al and Pr on glass formation and glass transition, unique elastic properties, and phonon softening of the BMGs are discussed from the structural point of view.

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Articles
Copyright
Copyright © Materials Research Society 2006

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References

REFERENCES

1.Inoue, A., Zhang, T., Takeuchi, A. and Zhang, W.: Hard magnetic bulk amorphous Nd–Fe–Al alloys of 12 mm in diameter made by suction casting. Mater. Trans. JIM 37, 636 (1996).Google Scholar
2.Inoue, A., Zhang, T., Zhang, W. and Takeuchi, A.: Bulk Nd–Fe–Al amorphous alloys with hard magnetic properties. Mater. Trans. JIM 37, 99 (1996).CrossRefGoogle Scholar
3.Wang, W.H., Dong, C. and Shek, C.H.: Bulk metallic glasses. Mater. Sci. Eng. R 44, 45 (2004).Google Scholar
4.Wei, B.C., Wang, W.H., Pan, M.X. and Han, B.S.: Domain structure of a Nd65Al10Fe25−xCox bulk metallic glasses. Phys. Rev. B 64, 12406 (2001).CrossRefGoogle Scholar
5.Zhang, Z., Wang, R.J., Wei, B.C. and Wang, W.H.: Structural evolution and property changes in Nd60Al10Fe20Co10 bulk metallic glass during crystallization. Appl. Phys. Lett. 81, 4371 (2002).CrossRefGoogle Scholar
6.Zhao, Z.F., Zhang, Z., Wen, P. and Wang, W.H.: A highly glass-forming alloy with low glass transition temperature. Appl. Phys. Lett. 82, 4699 (2003).CrossRefGoogle Scholar
7.Zhang, B., Pan, M.X., Zhao, D.Q. and Wang, W.H.: “Soft” bulk metallic glasses based on cerium. Appl. Phys. Lett. 85, 61 (2004).Google Scholar
8.Tang, M.B., Zhao, D.Q., Pan, M.X., Wei, B.C. and Wang, W.H.: Glass-forming ability of Pr–(Cu,Ni)–Al alloys in eutectic system. J. Mater. Res. 18, 664 (2003).Google Scholar
9.Zhang, Y., Tan, H., Kong, H.Z., Yao, B. and Li, Y.: Glass-forming ability of Pr–(Cu,Ni)–Al alloys in eutectic system. J. Mater. Res. 18, 664 (2003).CrossRefGoogle Scholar
10.Greer, A.L.: Through a glass, lightly. Nature 366, 303 (1993).CrossRefGoogle Scholar
11.Turnbull, D. and Fisher, J.C.: Rate of nucleation in condensed systems. J. Chem. Phys. 17, 71 (1949).Google Scholar
12.Inoue, A., Zhang, T. and Masumoto, T.: Zr–Al–Ni amorphous alloys with high glass transition temperature and significant supercooled liquid region. Mater. Trans. JIM 31, 177 (1990).Google Scholar
13.Lu, Z.P. and Liu, C.T.: Glass formation criterion for various glass-forming systems. Phys. Rev. Lett. 91, 115505 (2003).CrossRefGoogle ScholarPubMed
14.Schroers, J., Masuhr, A., Johnson, W.L. and Busch, R.: Pronounced asymmetry in the crystallization behaviour during constant heating and cooling of a bulk metallic glass-forming liquid. Phys. Rev. B 60, 11855 (1999).Google Scholar
15.Kelton, K.F.: A new model for nucleation in bulk metallic glasses. Philos. Mag. Lett. 77, 337 (1998).Google Scholar
16.Wen, P., Wang, R.J., Pan, M.X., Zhao, D.Q. and Wang, W.H.: Characteristics of microstructure and glass transition of (Zr0.59Ti0.06Cu0.22Ni0.13)100−xAlx bulk metallic glasses. J. Appl. Phys. 93, 759 (2003).CrossRefGoogle Scholar
17.Tan, H., Zhang, Y., Ma, D., Feng, Y.P. and Li, Y.: Optimum glass formation at off-eutectic composition and its relation to skewed eutectic coupled zone in the La based La–Al–(Cu,Ni) pseudo ternary system. Acta Mater. 51, 4551 (2003).Google Scholar
18.Wang, W.H., Wang, R.J., Li, F.Y., Zhao, D.Q. and Pan, M.X.: Elastic constants and their pressure dependence of Zr41Ti14Cu12.5Ni9Be22.5C1 bulk metallic glass. Appl. Phys. Lett. 74, 1803 (1999).Google Scholar
19.Schreiber, D.: Elastic Constants and Their Measurement (McGraw-Hill, New York, 1973).Google Scholar
20.Okamoto, P.R., Lam, N.Q. and Rehn, L.E.: Solid State Physics, Vol. 52, edited by Ehrenreich, H. and Spaepen, F. (Academic Press, San Diego, CA, 1999), pp. 1135.Google Scholar
21.Wang, W.H., Wen, P., Zhao, D.Q., Pan, M.X. and Wang, R.J.: Relationship between glass transition temperature and Debye temperature in bulk metallic glasses. J. Mater. Res. 18, 2747 (2003).Google Scholar
22.Guo, F.Q., Poon, S.J. and Shiflet, J.G.: CaAl-based bulk metallic glasses with high thermal stability. Appl. Phys. Lett. 84, 37 (2004).Google Scholar
23.Schroers, J., Masuhr, A., Johnson, W.L. and Busch, R.: Pronounced asymmetry in the crystallization behavior during constant heating and cooling of a bulk metallic glass-forming liquid. Phys. Rev. B 60, 11855 (1999).CrossRefGoogle Scholar
24.Wang, W.H., Wang, Z.X., Zhao, D.Q., Tang, M.B., Utsumi, W. and Wang, X.L.: High-pressure suppression of crystallization in the metallic supercooled liquid Zr41Ti14Cu12.5Ni10Be22.5: Influence of viscosity. Phys. Rev. B 70, 092203 (2004).CrossRefGoogle Scholar
25.Angell, C.A., Ngai, K.L., McKenna, G.B., McMillan, P.F. and Martin, S.W.: Relaxation in glass forming liquids and amorphous solids. J. Appl. Phys. 88, 3113 (2000).Google Scholar
26.Verbraak, C.L.J.A., Van Dam, J. and Van Der Vegt, A.K.: High modulus of isotactic polypropylene attained by coextrusion with atactic polystyrene. Polym. Eng. Sci. 25, 431 (2004).Google Scholar
27.Golding, B., Bagley, B.G. and Hsu, F.S.L.: Soft transverse phonons in a metallic glass. Phys. Rev. Lett. 29, 68 (1972).CrossRefGoogle Scholar
28.Li, M. and Johnson, W.L.: Instability of metastable solid solutions and the crystal to glass transition. Phys. Rev. Lett. 70, 1120 (1993).Google Scholar
29.Voronel, A. and Rabinovich, S.J.: On glassification temperatures of simple metallic alloys. J. Phys. F: Met. Phys. 17, L193 (1987).CrossRefGoogle Scholar