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Enhancement of glass-forming ability and plasticity of Cu-rich Cu–Zr–Al bulk metallic glasses by minor addition of Dy

Published online by Cambridge University Press:  04 July 2014

B.W. Zhou ,
L. Deng ,
X.G. Zhang ,
W. Zhang ,
H. Kimura  and
A. Makino
B.W. Zhou
Affiliation:
School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, People's Republic of China
L. Deng
Affiliation:
School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, People's Republic of China
X.G. Zhang*
Affiliation:
School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, People's Republic of China
W. Zhang
Affiliation:
School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, People's Republic of China
H. Kimura
Affiliation:
Institute of Materials Research, Tohoku University, Sendai 980-8577, Japan
A. Makino
Affiliation:
Institute of Materials Research, Tohoku University, Sendai 980-8577, Japan
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

(Cu0.47Zr0.45Al0.08)100–xDyx (x = 0, 1, 2, 3, 4; at.%) metallic glasses with greatly enhanced glass-forming ability (GFA) and plasticity were synthesized based on microalloying technique. The structure, thermal stability, and elastic properties of the BMG samples were studied by x-ray diffraction (XRD), differential scanning calorimetry (DSC), and ultrasonic measurements, respectively. With addition of minor dysprosium (Dy), fully metallic glassy rods with diameters exceeding 20 mm could be successfully fabricated by copper mold casting. In addition, the Cu–Zr–Al–Dy BMGs exhibit good mechanical properties under a compressive deformation mode, i.e., high yield strength of 1735–1906 MPa, Young's modulus of 85–100 GPa, and distinct plastic strain up to 4.02%. The strength and plasticity show remarkable correlations with glass transition temperature and Poisson's ratio, respectively. The role of minor Dy addition in enhancement in GFA and mechanical property of the Cu-rich BMGs is also discussed.

Keywords

bulk metallic glasscopper-rich alloysmicroalloying techniqueglass-forming abilitymechanical property
Type
Articles
Information
Journal of Materials Research , Volume 29 , Issue 12 , 28 June 2014 , pp. 1362 - 1368
Copyright
Copyright © Materials Research Society 2014 

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References

REFERENCES

Inoue, A.: Stabilization of metallic supercooled liquid and bulk amorphous alloys. Acta Mater. 48, 279 (2000).CrossRefGoogle Scholar
Wang, W.H., Dong, C., and Shek, C.H.: Bulk metallic glasses. Mater. Sci. Eng., R 44, 45 (2004).Google Scholar
Chen, H.S.: Thermodynamic considerations on the formation and stability of metallic glasses. Acta Metall. 22, e1505 (1974).Google Scholar
Johnson, W.L.: Bulk glass-forming metallic alloys: Science and technology. MRS Bull. 24, 42 (1999).Google Scholar
Peker, A. and Johnson, W.: A highly processable metallic glass: Zr41.2Ti13.8Cu12.5Ni10.0Be22.5. Appl. Phys. Lett. 63, 2342 (1993).Google Scholar
Zhang, Q., Zhang, W., and Inoue, A.: Preparation of Cu36Zr48Ag8Al8 bulk metallic glass with a diameter of 25 mm by copper mold casting. Scr. Mater. 55, 711 (2006).CrossRefGoogle Scholar
Inoue, A., Nishiyama, N., and Kimura, H.: Preparation and thermal stability of bulk amorphous Pd40Cu30Ni10P20 alloy cylinder of 72 mm in diameter. Mater. Trans., JIM 38, 179 (1997).CrossRefGoogle Scholar
Zhou, B.W., Zhang, X.G., Zhang, W., Kimura, H., Zhang, T., Makino, A., and Inoue, A.: Synthesis and mechanical properties of new Cu-based Cu-Zr-Al glassy alloys with critical diameters up to centimeter order. Mater. Trans. 51, 826 (2010).CrossRefGoogle Scholar
Wang, W.H., Bian, Z., Wen, P., Pan, M.X., and Zhao, D.Q.: Role of addition in formation and properties of Zr-based bulk metallic glasses. Intermetallics 10, 1249 (2002).Google Scholar
Lu, Z.P. and Liu, C.T.: Role of minor alloying additions in formation of bulk metallic glasses: A review. J. Mater. Sci. 39, 3965 (2004).CrossRefGoogle Scholar
Wang, J.F., Li, R., Hua, N.B., and Zhang, T.: Co-based ternary bulk metallic glasses with ultrahigh strength and plasticity. J. Mater. Res. 26, 2072 (2011).Google Scholar
Zhang, L., Cheng, Y.Q., Cao, A.J., Xu, J., and Ma, E.: Bulk metallic glasses with large plasticity: Composition design from the structural perspective. Acta Mater. 57, 1154 (2009).Google Scholar
Xu, X., Chen, L.Y., Zhang, G.Q., Wang, L.N, and Jiang, J.Z.: Formation of bulk metallic glasses in Cu45Zr48−xAl7REx (RE=La, Ce, Nd, Gd and 0≤x≤5at.%). Intermetallics 15, 1066 (2007).Google Scholar
Park, E.S., Kyeong, J.S., and Kim, D.H.: Role of minor addition of metallic alloying elements in formation and properties of Cu-Ti-rich bulk metallic glasses. Scr. Mater. 57, 49 (2007).Google Scholar
Park, E.S. and Kim, D.H.: Phase separation and enhancement of plasticity in Cu–Zr–Al–Y bulk metallic glasses. Acta Mater. 54, 2597 (2005).CrossRefGoogle Scholar
Turnbull, D.: Under what conditions can a glass be formed?. Contemp. Phys. 10, 473 (1969).CrossRefGoogle Scholar
Lu, Z. P. and Liu, C. T.: A new glass-forming ability criterion for bulk metallic glasses. Acta. Mater. 50, 35013512 (2002).Google Scholar
Lewandowski, J.J., Wang, W.H., and Greer, A.L.: Intrinsic plasticity or brittleness of metallic glasses. Philos. Mag. Lett. 85, 77 (2005).Google Scholar
Papadakis, E.P.: Ultrasonic phase velocity by the pulse echo overlap method incorporating diffraction phase corrections. J. Acoust. Soc. Am. 42, 1045 (1967).CrossRefGoogle Scholar
Scheriber, D.: Elastic Constants and their Measurement (McGraw-Hill, NewYork, 1973).Google Scholar
Inoue, A., Zhang, W., Zhang, T., and Kurosaka, K.: High-strength Cu-based bulk glassy alloys in Cu–Zr–Ti and Cu–Hf–Ti ternary systems. Acta Mater. 49, 2645 (2001).Google Scholar
Zhang, W. and Inoue, A.: Formation and mechanical properties of Ni-based Ni–Nb–Ti–Hf bulk glassy alloys. Scr. Mater. 48, 641 (2003).Google Scholar
Wang, W.H.: Bulk metallic glasses with functional physical properties. Prog. Mater. Sci. 52, 540 (2007).Google Scholar
Zhang, Y., Chen, J., Chen, G. L., and Liu, X. J.: Glass formation mechanism of minor yttrium addition in CuZrAl alloys. Appl. Phys. Lett. 89, 131904 (2006).Google Scholar
Schroers, J. and Johnson, W.L.: Ductile bulk metallic glass. Phys. Rev. Lett. 93, 255506 (2004).Google Scholar
Chen, H.S., Krause, J.T., and Coleman, E.: Elastic constants, hardness and their implications to flow properties of metallic glasses. J. Non-Cryst. Solids 18, 157 (1975).Google Scholar