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Elastic to elastic–plastic transition of Al2O3/TiC ceramics studied by nanoindentation

Published online by Cambridge University Press:  31 January 2011

Gerold A. Schneider*
Affiliation:
Institute of Advanced Ceramics, Hamburg University of Technology, Hamburg 21073, Germany
*
a) Address all correspondence to this author. e-mail: [email protected]
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Abstract

In this work load–penetration curves obtained by nanoindentation were analyzed, using a spherical tip approximation and applying the stress/strain concept by Tabor. Nanoindentation experiments were done on sapphire, pure TiC, and a mixed ceramic with in situ formed TiCx layer, using a sharp cube-corner indenter at very low loads and penetration depths. With the implemented method it is possible to display the elastic to elastic–plastic transition of each investigated phase, and much more information can be extracted than by conventional analysis. Regarding the mixed ceramic, it was found that the present TiC phases exhibit slightly lower hardness than the alumina phase, but they can sustain much higher stresses during the transition from the elastic to the elastic–plastic regime. This is considered to be beneficial for the application as cutting material. No correlation was found between the nanomechanical behavior of the model materials sapphire and TiC and the corresponding phases of the mixed ceramic.

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Articles
Copyright
Copyright © Materials Research Society 2009

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References

1Whitney, E.D. and Vaidyanathan, P.N.: Microstructural engineering of ceramic cutting tools. Ceram. Bull. 6, 1010 (1988)Google Scholar
2Cutler, R. and Rigtrup, K.M.: Synthesis, sintering, microstructure and mechanical properties of ceramics made by exothermic reactions. J. Am. Ceram. Soc. 1, 36 (1992)CrossRefGoogle Scholar
3Adachi, S., Wada, T., Mihara, T., Miyamoto, Y., and Koizumi, M.: High-pressure self-combustion sintering of alumina-titanium car-bide ceramic composite. J. Am. Ceram. Soc. 5, 1451 (1990)Google Scholar
4Bruhn, J.: Low-Cost Composites Prepared by Aluminothermic Reaction for Cutting and Wear Applications (VDI Verlag, Düsseldorf, Germany 2001).Google Scholar
5Zimmermann, K., Schneider, G.A., Bhattacharya, A.K., and Hintze, W.: Surface modification of Al2O3/TiC cutting ceramics. J. Am. Ceram. Soc. 12, 3773 (2007)CrossRefGoogle Scholar
6Bhattacharya, A.K., Zimmermann, K., Schneider, G.A., and Hintze, W.: Influence of surface modification on the cutting performance of reaction-sintered Al2O3—TiOC ceramics. J. Am. Ceram. Soc. 9, 2982 (2008)CrossRefGoogle Scholar
7Oliver, W.C. and Pharr, G.M.: An improved technique for determining hardness and elastic modulus using load and displacement sensing nanoindentation experiments. J. Mater. Res. 7, 1564 (1992)Google Scholar
8Bradby, J.E., Williams, J.S., and Swain, M.V.: Pop-in events induced by spherical indentation in compound semiconductors. J. Mater. Res. 19, 380 (2004)Google Scholar
9Scholz, T., McLaughlin, K.K., Giuliani, F., Clegg, W.J., Espinoza-Beltran, F.J., Swain, M.V., and Schneider, G.A.: Nanoindentation initiated dislocations in barium titanate (BaTiO3). Appl. Phys. Lett. 91, 062903 (2007)CrossRefGoogle Scholar
10Tymiak, N.I., Daugela, A., Wyrobek, T.J., and Warren, O.L.: Acoustic emission monitoring of the earliest stages of contact-induced plasticity in sapphire. Acta Mater. 52, 553 (2004)Google Scholar
11Nix, W.D. and Gao, H.: Indentation size effects in crystalline materials: A law for strain gradient plasticity. J. Mech. Phys. Solids 46, 411 (1998)Google Scholar
12Swadener, J.G., George, E.P., and Pharr, G.M.: The correlation of the indentation size effect measured with indenters of various shapes. J. Mech. Phys. Solids 50, 681 (2002)CrossRefGoogle Scholar
13Scholz, T., Munoz-Saldana, J., Swain, M., and Schneider, G.A.: Indentation size effect in barium titanate with spherical tipped nanoindenters. Appl. Phys. Lett. 88, 091908 (2006)CrossRefGoogle Scholar
14Lu, C., Mai, Y.W., Tam, P.L., and Shen, Y.G.: Nanoindentation-induced elastic-plastic transition and size effect in alpha-Al2O3 (0001). Philos. Mag. Lett. 6, 409 (2007)Google Scholar
15Hurtado-Macias, A., Munoz, J.-Saldana, Espinoza-Beltran, F.J., Scholz, T., Swain, M.V., and Schneider, G.A.: Indentation size effect in soft PZT ceramics with tetragonal structure close to the MPB. J. Phys. D: Appl. Phys. 41, 035407 (2008)Google Scholar
16Tabor, D.: The Hardness of Metals (Clarendon Press, Oxford, England, 1951).Google Scholar
17Johnson, K.L.: Contact Mechanics (Cambridge University Press, Cambridge, England, 1985).Google Scholar
18Fischer-Cripps, A.C.: Nanoindentation (Springer, New York, 2002).Google Scholar
19Waynant, R.W. and Ediger, M.N.: Electro-Optics Handbook (McGraw-Hill, New York, 2000).Google Scholar
20Pierson, H.O.: Handbook of Refractory Carbides and Nitrides: Properties, Characteristics, Processing and Applications (Noyes Publications, Westwood, NJ, 1996).Google Scholar
21Sneddon, I.N.: The relation between load and penetration in the axisymmetric boussinesq problem for a punch of arbitrary profile. Int. J. Eng. Sci. 1, 47 (1965)Google Scholar
22Field, J.S. and Swain, M.: Determining the mechanical properties of small volumes of material from submicrometer spherical indentations. J. Mater. Res. 10, 101 (1995)CrossRefGoogle Scholar
23Bushby, A.J. and Dunstan, D.J.: Plasticity size effects in nano-indentation. J. Mater. Res. 19, 137 (2004)Google Scholar
24Fischer-Cripps, A.C.: Introduction to Contact Mechanics (Springer, New York, 2007).Google Scholar
25Scholz, T., Schneider, G.A., Munoz-Saldana, J., and Swain, M.V.: Fracture toughness from submicron derived indentation cracks. Appl. Phys. Lett. 84(16), 3055 (2004).Google Scholar
26Field, J.S., Swain, M.V., and Dukino, R.D.: Determination of fracture toughness from the extra penetration produced by indentation-induced pop-in. J. Mater. Res. 18(6), 1412 (2003).Google Scholar
27Toeroe, E., Perry, A.J., Chollet, L., and Sproul, W.D.: Young's modulus of TiN, TiC, ZrN and HfN. Thin Solid Films 1–3, 37 (1987)Google Scholar
28Guemmaz, M., Mosser, A., Boudoukha, L., Grob, J.J., Raiser, D., and Sens, J.C.: Ion beam synthesis of non-stoichiometric titanium carbide: Composition structure and nanoindentation studies. Nucl. Instrum. Methods Phys. Res., Sect. B 3, 263 (1996)Google Scholar
29Fernandes, A.C., Carvalho, P., Vaz, F., Parreira, N.M.G., Goudeau, P., Bourhis, E. Le, and Riviëre, J.P.: Correlation between processing and properties of titanium oxycarbide, TiCxOy. Plasma Processes Polym. S1, 83 (2007)Google Scholar
30Kucheyev, S.O., Bradby, J.E., Williams, J.S., Jagadish, C., and Swain, M.V.: Mechanical deformation of single-crystal ZnO. Appl. Phys. Lett. 80, 956 (2002)Google Scholar
31Page, T.F., Oliver, W.C., and McHargue, C.J.: The deformation behavior of ceramic crystals subjected to very low load (nano) indentations. J. Mater. Res. 7, 450 (1992)CrossRefGoogle Scholar