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Elastic modulus of single-crystal GaN nanowires

Published online by Cambridge University Press:  03 March 2011

Hai Ni ,
Xiaodong Li ,
Guosheng Cheng  and
Robert Klie
Hai Ni
Affiliation:
Department of Mechanical Engineering, University of South Carolina, Columbia, South Carolina 29208
Xiaodong Li*
Affiliation:
Department of Mechanical Engineering, University of South Carolina, Columbia, South Carolina 29208
Guosheng Cheng
Affiliation:
Departments of Electrical Engineering and Applied Physics, Yale University, New Haven, Connecticut 06520
Robert Klie
Affiliation:
Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973
*
a) Address all correspondence to this author. e-mail: [email protected]
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Abstract

The deformation behavior of single-crystal GaN nanowires was studied by directly performing three-point bending tests on each individual nanowire in an atomic force microscope. The elastic modulus calculated from the load–displacement response of the nanowires was 43.9 ± 2.2 GPa. Single-crystal GaN nanowires investigated in this study were synthesized by chemical vapor deposition techniques based on the vapor–liquid–solid growth mechanism and had a diameter range from 60 to 110 nm. Crystalline GaN nanowires did not show obvious plastic deformation in bending and usually failed in a brittle manner.

Keywords

Chemical vapor deposition (CVD)Elastic propertiesElectron energy loss spectroscopy (EELS)
Type
Articles
Information
Journal of Materials Research , Volume 21 , Issue 11 , November 2006 , pp. 2882 - 2887
Copyright
Copyright © Materials Research Society 2006

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References

REFERENCES

1.Stach, E.A., Pauzauskie, P.J., Kuykendall, T., Goldberger, J., He, R.R., Yang, P.D.: Watching GaN nanowires grow. Nano Lett. 3, 867 (2003).CrossRefGoogle Scholar
2.Cheng, G.S., Kolmakov, A., Zhang, Y.X., Moskovits, M., Munden, R., Reed, M.A., Wang, G.M., Moses, D., Zhang, J.P.: Current rectification in a single GaN nanowire with a well-defined p-n junction. Appl. Phys. Lett. 83, 1578 (2003).CrossRefGoogle Scholar
3.Gradečak, S., Qian, F., Li, Y., Park, H.G., Lieber, C.M.: GaN nanowire lasers with low lasing thresholds. Appl. Phys. Lett. 87, 173111 (2005).CrossRefGoogle Scholar
4.Hu, J.Q., Jiang, Y., Meng, X.M., Lee, C.S., Lee, S.T.: A simple large-scale synthesis of very long aligned silica nanowires. Chem. Phys. Lett. 367, 339 (2003).CrossRefGoogle Scholar
5.Liu, Z.Q., Xie, S.S., Sun, L.F., Tang, D.S., Zhou, W.Y., Wang, C.Y., Liu, W., Li, Y.B., Zou, X.P., Wang, G.: Synthesis of alpha-SiO2 nanowires using Au nanoparticle catalysts on a silicon substrate. J. Mater. Res. 16, 683 (2001).CrossRefGoogle Scholar
6.Yu, D.P., Hang, Q.L., Ding, Y., Zhang, H.Z., Bai, Z.G., Wang, J.J., Zou, Y.H., Qian, W., Xiong, G.C., Feng, S.Q.: Amorphous silica nanowires: Intensive blue light emitters. Appl. Phys. Lett. 73, 3076 (1998).CrossRefGoogle Scholar
7.Zhang, M., Bando, Y., Wada, K., Kurashima, K.: Synthesis of nanotubes and nanowires of silicon oxide. J. Mater. Sci. Lett. 18, 1999 (1911).Google Scholar
8.Liang, C.H., Zhang, L.D., Meng, G.W., Wang, Y.W., Chu, Z.Q.: Preparation and characterization of amorphous SiOx nanowires. J. Non-Cryst. Solids 277, 63 (2000).CrossRefGoogle Scholar
9.Iijima, S.: Helical microtubules of graphitic carbon. Nature 354, 56 (1991).CrossRefGoogle Scholar
10.Martin, C.R.: Nanomaterials—A membrane-based synthetic approach. Science 266, 1961 (1994).CrossRefGoogle Scholar
11.Niu, J.J., Sha, J., Ma, X.Y., Xu, J., Yang, D.: Array-orderly single crystalline silicon nano-wires. Chem. Phys. Lett. 367, 528 (2003).CrossRefGoogle Scholar
12.Shi, W.S., Peng, H.Y., Zheng, Y.F., Wang, N., Shang, N.G., Pan, Z.W., Lee, C.S., Lee, S.T.: Synthesis of large areas of highly oriented, very long silicon nanowires. Adv. Mater. 12, 1343 (2000).3.0.CO;2-Q>CrossRefGoogle Scholar
13.Zheng, B., Wu, Y.Y., Yang, P., Liu, J.: Synthesis of ultra-long and highly oriented silicon oxide nanowires from liquid alloys. Adv. Mater. 14, 122 (2002).3.0.CO;2-V>CrossRefGoogle Scholar
14.Cheng, G.S., Zhang, L.D., Zhu, Y., Fei, G.T., Li, L., Mo, C.M., Mao, Y.Q.: Large-scale synthesis of single crystalline gallium nitride nanowires. Appl. Phys. Lett. 75, 2455 (1999).CrossRefGoogle Scholar
15.Fasol, G.: Room-temperature blue gallium nitride laser diode. Science 272, 1751 (1996).CrossRefGoogle Scholar
16.Gao, P.X., Ding, Y., Wang, Z.L.: Crystallographic orientation-aligned ZnO nanorods grown by a tin catalyst. Nano Lett. 3, 1315 (2003).CrossRefGoogle Scholar
17.Yi, G.C., Wang, C.R., Park, W.I.: ZnO nanorods: Synthesis, characterization and applications. Semicond. Sci. Technol. 20 S22(2005).CrossRefGoogle Scholar
18.Chen, Y.F., Wang, R.M., Zhang, H.Z., Sun, X.C., Zhang, Z.S., Xing, Y.J., Yu, D.P.: TEM investigations on ZnO nanobelts synthesized via a vapor phase growth. Micron. 35, 481 (2004).CrossRefGoogle Scholar
19.Hughes, W.L., Wang, Z.L.: Controlled synthesis and manipulation of ZnO nanorings and nanobows. Appl. Phys. Lett. 86, 043106 (2005).CrossRefGoogle Scholar
20.Morkoc, H., Mohammad, S.N.: High-luminousity blue and blue-green gallium nitride light-emitting diodes. Science 267, 51 (1995).CrossRefGoogle ScholarPubMed
21.Ponce, F.A., Bour, D.P.: Nitride-based semiconductors for blue and green light-emitting devices. Nature 386, 351 (1997).CrossRefGoogle Scholar
22.Stern, E., Cheng, G., Cimpoiasu, E., Klie, R., Guthrie, S., Klemic, J., Kretzschmar, I., Steinlauf, E., Turner-Evans, D., Broomfield, E., Hyland, J., Koudelka, R., Boone, T., Young, M., Sanders, A., Munden, R., Lee, T., Routenberg, D., Reed, M.A.: Electrical characterization of single GaN nanowires. Nanotech. 16, 2941 (2005).CrossRefGoogle Scholar
23.Huang, Y., Duan, X.F., Cui, Y., Lieber, C.M.: Gallium nitride nanowire nanodevices. Nano Lett. 2, 101 (2002).CrossRefGoogle Scholar
24.Kim, J.R., So, H.M., Park, J.W., Kim, J.J., Kim, J., Lee, C.J., Lyu, S.C.: Electrical transport properties of individual gallium nitride nanowires synthesized by chemical-vapor-deposition. Appl. Phys. Lett. 80, 3548 (2002).CrossRefGoogle Scholar
25.Kim, H.M., Kim, D.S., Park, Y.S., Kim, D.Y., Kang, T.W., Chang, K.S.: Growth of GaN nanorods by a hydride vapor-phase epitaxy method. Adv. Mater. 14, 991 (2002).3.0.CO;2-L>CrossRefGoogle Scholar
26.Huang, Y., Duan, X.F., Cui, Y., Lauhon, L.J., Kim, K.H., Lieber, C.M.: Logic gates and computation from assembled nanowire building blocks. Science 294, 1313 (2001).CrossRefGoogle ScholarPubMed
27.Huang, Y., Duan, X.F., Wei, Q.Q., Lieber, M.: Directed assembly of one-dimensional nanostructures into functional networks. Science 291, 630 (2001).CrossRefGoogle ScholarPubMed
28.Johnson, J.C., Choi, H.J., Knutsen, K.P., Schaller, R.D., Yang, P.D., Saykally, R.J.: Single gallium nitride nanowire lasers. Nat. Mater. 1, 106 (2002).CrossRefGoogle ScholarPubMed
29.Nakamura, S., Pearton, S., Fasol, G.: The Blue Laser Diode: The Complete Story (Springer, Berlin, Germany, 2000), p. 103.CrossRefGoogle Scholar
30.Ding, W., Dikin, D.A., Chen, X., Piner, R.D., Ruoff, R.S., Zussman, E., Wang, X., Li, X.: Mechanics of hydrogenated amorphous carbon deposits from electron-beam-induced deposition of a paraffin precursor. J. Appl. Phys. 98, 014905 (2005).CrossRefGoogle Scholar
31.Ni, H., Li, X.D., Gao, H.S.: Elastic modulus of amorphous SiO2 nanowires. Appl. Phys. Lett. 88, 043108 (2006).CrossRefGoogle Scholar
32.Li, X.D., Wang, X.N., Xiong, Q.H., Eklund, P.C.: Mechanical properties of ZnS nanobelts. Nano Lett. 5, 2005 (1982).Google Scholar
33.Ni, H., Li, X.D.Young’s modulus of ZnO nanobelts measured using atomic force microscopy and nanoindentation techniques. Nanotech. 17, 3591 (2006).CrossRefGoogle ScholarPubMed
34.Li, X.D., Bhushan, B.: Fatigue studies of nanoscale structures for MEMS/NEMS applications using nanoindentation techniques. Surf. Coat. Technol. 163, 521 (2003).CrossRefGoogle Scholar
35.Namazu, T., Isono, Y., Tanka, T.: Evaluation of size effect on mechanical properties of single crystal silicon by nanoscale bending test using AFM. J. Microelectromech. Syst. 9, 450 (2000).CrossRefGoogle Scholar
36.Wu, B., Heidelberg, A., Boland, J.J.: Mechanical properties of ultrahigh-strength gold nanowires. Nat. Mater. 4, 525 (2005).CrossRefGoogle ScholarPubMed
37.Nowak, R., Pessa, M., Suganuma, M., Leszczynski, M., Grzegory, I., Porowski, S., Yoshida, F.: Elastic and plastic properties of GaN determined by nano-indentation of bulk crystal. Appl. Phys. Lett. 75, 2070 (1999).CrossRefGoogle Scholar
38.Schwarz, R.B., Khachaturyan, K., Weber, E.R.: Elastic moduli of gallium nitride. Appl. Phys. Lett. 70, 1122 (1997).CrossRefGoogle Scholar