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Elastic anomaly and internal friction of Ba0.5Sr0.5Co0.8Fe0.2O3-δ and La0.58Sr0.4Co0.2Fe0.8O3-δ

Published online by Cambridge University Press:  10 June 2011

Bingxin Huang
Affiliation:
Forschungszentrum Jülich GmbH, 52428 Jülich, Germany
Jürgen Malzbender*
Affiliation:
Forschungszentrum Jülich GmbH, 52428 Jülich, Germany
Rolf W. Steinbrech
Affiliation:
Forschungszentrum Jülich GmbH, 52428 Jülich, Germany
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

Elastic modulus and internal friction of Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCF) and La0.58Sr0.4Co0.2Fe0.8O3-δ (LSCF) were determined from resonance frequencies and damping behavior, respectively, using an impulse excitation method. An elastic anomaly for BSCF around 476 K, with a corresponding peak in the internal friction, is attributed to the experimentally confirmed spin transition of Co3+. LSCF is in a ferromagnetic state below ∼220 K and in a paramagnetic state above ∼250 K. The elastic modulus of LSCF exhibits an anomaly between 473 and 1113 K, which is attributed to a transition from rhombohedral to cubic symmetry.

Type
Materials Communications
Copyright
Copyright © Materials Research Society 2011

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References

REFERENCES

1.Sunarso, J., Baumann, S., Serra, J.M., Meulenberg, W.A., Liu, S., Lin, Y.S., and Diniz da Costa, J.C.: Mixed ionic-electronic conducting (MIEC) ceramic-based membranes for oxygen separation. J. Membr. Sci. 320, 13 (2008).CrossRefGoogle Scholar
2.Cheng, J.H., Navrotsky, A., Zhou, X.D., and Anderson, H.U.: Thermochemistry of La1-xSrxFeO3-δ solid solutions (0.0 <= x <= 1.0, 0.0 <= δ <= 0.5). Chem. Mater. 17, 2197 (2005).CrossRefGoogle Scholar
3.Buchler, O., Serra, J.M., Meulenberg, W.A., Sebold, D., and Buchkremer, H.P.: Preparation and properties of thin La1-xSrxCo1-yFeyO3-δ perovskitic membranes supported on tailored ceramic substrates. Solid State Ion 178, 91 (2007).CrossRefGoogle Scholar
4.Huang, B.X., Malzbender, J., Steinbrech, R.W., Grychtol, P., Schneider, C.M., and Singheiser, L.: Anomalies in the thermomechanical behavior of Ba0.5Sr0.5Co0.8Fe0.2O3-δ ceramic oxygen conductive membranes at intermediate temperatures. Appl. Phys. Lett. 95, 051901 (2009).CrossRefGoogle Scholar
5.Huang, B.X., Malzbender, J., Steinbrech, R.W., and Singheiser, L.: Mechanical properties of La0.58Sr0.4Co0.2Fe0.8O3-δ membranes. Solid State Ion 180, 241 (2009).CrossRefGoogle Scholar
6.Zheng, R.K., Tang, A.N., Yang, Y., Wang, W., Li, G., Li, X.G., and Ku Transport, H.C.: magnetic, specific heat, internal friction, and shear modulus in the charge ordered La0.25Ca0.75MnO3 manganite. J. Appl. Phys. 94, 514 (2003).CrossRefGoogle Scholar
7.Bhalla, A.S., Guo, R.Y., and Roy, R.: The perovskite structure—a review of its role in ceramic science and technology. Mater. Res. Innovations 4, 3 (2000).CrossRefGoogle Scholar
8.Radaelli, P.G. and Cheong, S.W.: Structural phenomena associated with the spin-state transition in LaCoO3. Phys. Rev. B 66, 094408 (2002).CrossRefGoogle Scholar
9.Ravindran, P., Korzhavyi, P.A., Fjellvag, H., and Kjekshus, A.: Electronic structure, phase stability, and magnetic properties of La1-xSrxCoO3 from first-principles full-potential calculations. Phys. Rev. B 60, 16423 (1999).CrossRefGoogle Scholar
10.Wu, X.S., Zuo, Y.B., Li, J.H., Chen, C.S., and Liu, W.: Low-frequency internal friction study of phase transitions in La1/3Sr2/3FeO3-δ ceramics. J. Alloy. Comp. 462, 432 (2008).CrossRefGoogle Scholar
11.Yamaguchi, S., Okimoto, Y., Taniguchi, H., and Tokura, Y.: Spin-state transition and high-spin polarons in LaCoO3. Phys. Rev. B 53, R2926 (1996).CrossRefGoogle ScholarPubMed
12.Swarnakar, A.K., Gimenez, S., Salehi, S., Vleugels, J., and Van der Biest, O.: Recent advances in material characterization using the impulse excitation technique (IET). Key Eng. Mater. 333, 235 (2007).CrossRefGoogle Scholar
13.Du, J., Sun, Y., Jiang, J., Zeng, F., and Yin, H.: Internal friction and Youngs modulus in the Bi(Pb)-Sr-Ca-Cu-O superconductor. Phys. Rev. B 41, 6679 (1990).Google Scholar
14.Giraud, S. and Canel, J.: Young’s modulus of some SOFCs materials as a function of temperature. J. Eur. Ceram. Soc. 28, 77 (2008).CrossRefGoogle Scholar